Methods for preparing ceramic fiber filter tubes with high air permeability

Patent metadata

Field	Value
Publication number	US-12397265-B2
Application number	US-202519026585-A
Country	US
Kind code	B2
Filing date	Jan 17, 2025
Priority date	Oct 11, 2022
Publication date	Aug 26, 2025
Grant date	Aug 26, 2025

Abstract

A method for preparing a ceramic fiber filter tube with high air permeability, including: using mullite short fibers as aggregates, adding glass fibers and silica sol as sintering aids, obtaining a ceramic fiber filter tube green body by using a filterer-pressing forming process, and obtaining the ceramic fiber filter tube with high air permeability by freeze-drying and heat treatment in turn. The combination of two sintering aids with different properties can effectively improve the performance of ceramic fiber filter tube prepared by a wet forming technology. At the same time, the freeze-drying treatment can block the migration path of nanoparticles in the silica sol to the surface of the ceramic fiber filter tube due to the capillary force, so that the properties of the prepared ceramic fiber filter tube are more uniform, providing a reference for the preparation of a ceramic fiber membrane with high flux.

First claim

What is claimed is:

1. A method for preparing a ceramic fiber filter tube with an air permeability, wherein the method comprises: mixing silica sol with water to obtain a mixed solution, and adding mullite fibers and glass fibers into the mixed solution; wherein a mass ratio of the silica sol, the mullite fibers, and the glass fibers is (30-45):(1.5-9):1, adding an organic forming aid into the mixed solution and stirring, and obtaining a ceramic fiber filter tube green body by a filter-pressing forming process; wherein an aspect ratio of the mullite fibers is within a range of (50:1)-(200:1); and placing a demolded green body in a refrigerator for freezing for 12 h-24 h, drying a frozen green body at a temperature of (−60° C.)−(−20° C.) for 12 h-24 h, and obtaining the ceramic fiber filter tube by a calcination process, wherein the calcination process includes calcining the frozen green body at a temperature of 800° C.-1400° C., and holding for 1 h-3 h, wherein a heating rate and a cooling rate are controlled at 0.5° C./min-3° C./min.

2. The method of claim 1 , wherein a mass fraction of the silica sol is within a range of 20 wt %-40 wt %, and a volume ratio of the silica sol to the water is 1:(1.5-9).

3. The method of claim 1 , wherein the organic forming aid is an aqueous polyvinyl alcohol (PVA) solution that has a concentration of 8 wt %-12 wt %, and adding an amount of the PVA solution that is 60%-80% of a total mass of the mullite short fibers and the glass fibers to the mixed solution.

4. The method of claim 1 , wherein a time of the stirring is within a range of 3 min-10 min.

5. The method of claim 1 , wherein a pressure in the filter-pressing forming process is within a range of 2 MPa-4 MPa.

Assignees

• Nanjing University Of Technology

Inventors

• Zhong Zhaoxiang
• Ni Shiying
• ZOU Dong
• Gong Yanmin
• Xing Weihong

Classifications

• B01D71/00

  Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor · CPC title

• C04B35/00

  Shaped ceramic products characterised by their composition {(porous ceramic products C04B38/00; ceramic articles characterised by particular shape, see the relevant classes, e.g. linings for casting ladles, tundishes, cups or the like B22D41/02; ceramic substrates for microelectronic semi-conductors H10W70/692)}; Ceramics compositions ({shaping of ceramics B28B;} containing free metal bonded to carbides, diamond, oxides, borides, nitrides, silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides or sulfides other than as macroscopic reinforcing agents C22C); Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products {(infiltration of sintered ceramic preforms with molten metal C04B41/51; chemical preparation of powders of inorganic compounds C01)} · CPC title

• C04B2235/6567

  Treatment time · CPC title

• C04B2235/6565

  Cooling rate · CPC title

• C04B2235/6562

  Heating rate · CPC title