Catalyst for hydrogen evolution reaction and preparing method of the same

Patent metadata

Field	Value
Publication number	US-12392046-B2
Application number	US-202217585021-A
Country	US
Kind code	B2
Filing date	Jan 26, 2022
Priority date	Feb 2, 2021
Publication date	Aug 19, 2025
Grant date	Aug 19, 2025

Abstract

The present application relates to a catalyst for hydrogen evolution reaction (HER) including a transition metal matrix and noble metal atoms formed in the transition metal matrix, in which the noble metal atoms have oxygen adsorbed thereto, and oxygen is derived from the transition metal matrix.

First claim

What is claimed is:

1. A catalyst for hydrogen evolution reaction (HER) comprising a transition metal matrix and noble metal atoms formed in the transition metal matrix, wherein the noble metal atoms have oxygen physisorbed thereto, and the oxygen is derived from the transition metal matrix.

2. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the transition metal matrix is produced by reducing a transition metal oxide, and oxygen is physisorbed on the noble metal atoms in the reduction process.

3. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the noble metal atoms have hydrogen spillover occurring on the hetero-interface thereof.

4. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the transition metal matrix has a lattice structure, and the noble metal atoms are introduced into the lattice structure.

5. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the transition metal matrix includes a metal oxide selected from the group consisting of Cu 2 O, CuO, SnO 2 , SnO, Fe 2 O, Fe 2 O 3 , Fe 3 O 4 , FeO(OH), Al 2 O 3 , NiO, TiO, TiO 2 , WO 3 , PbO, PbO 2 , Pb 3 O 4 , ZnO, Sb 2 O 3 , Sb 2 O 4 , Sb 2 O 5 , Bi 2 O 3 , V 2 O 3 , V 2 O 4 , V 2 O 5 , MnO, Mn 3 O 4 , Mn 2 O 3 , MnO 2 , CrO 2 , Cr 2 O 3 , CrO 3 , CoO, Co 3 O, ZrO 2 , Ga 2 O 3 , In 2 O 3 , and combinations thereof.

6. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the transition metal matrix includes a nanostructure selected from the group consisting of nanowires, nanorods, nanoplates, nanotubes, nanowires, and combinations thereof.

7. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the noble metal includes one selected from the group consisting of ruthenium (Ru), gold (Au), silver (Ag), platinum (Pt), palladium (Pd), iridium (Ir), rhodium (Rh), osmium (Os), and combinations thereof.

8. A water splitting system including the catalyst for hydrogen evolution reaction (HER) according to claim 1 .

9. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the noble metal includes ruthenium (Ru).

10. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the transition metal matrix includes copper.

11. The catalyst for hydrogen evolution reaction (HER) of claim 1 , wherein the noble metal has an oxidation state of less than +2.

12. A method for preparing a catalyst for hydrogen evolution reaction (HER), the method comprising the steps of:
immersing a transition metal matrix in a noble metal chloride solution;
preparing an intermediate by exchanging noble metal cations of the noble metal chloride solution with a portion of metal cations of the transition metal matrix;
immersing the intermediate in a solution containing a reducing agent; and
forming noble metal atoms to which oxygen is physisorbed on the transition metal matrix by moving oxygen of the transition metal matrix to noble metal atoms by the reducing agent.

13. The method of claim 12 , wherein the reducing agent includes one selected from the group consisting of NaBH 4 , LiAlH 4 , hydrazine, KBH 4 , hydroiodic acid, and combinations thereof.

14. The method of claim 12 , wherein the transition metal matrix is one which is produced by reducing a transition metal oxide, and in which oxygen is physisorbed on the noble metal atoms in the reduction process.

15. The method of claim 12 , wherein the noble metal atoms have hydrogen spillover occurring on the hetero-interface thereof.

16. The method of claim 12 , wherein the transition metal matrix has a lattice structure, and the noble metal atoms are introduced into the lattice structure.

17. The method of claim 12 , wherein the transition metal matrix includes a metal oxide selected from the group consisting of Cu 2 O, CuO, SnO 2 , SnO, Fe 2 O, Fe 2 O 3 , Fe 3 O 4 , FeO (OH), Al 2 O 3 , NiO, TIO, TiO 2 , WO 3 , PbO, PbO 2 , Pb 3 O 4 , ZnO, Sb 2 O 3 , Sb 2 O 4 , Sb 2 O 5 , Bi 2 O 3 , V 2 O 3 , V 2 O 4 , V 2 O 5 , MnO, Mn 3 O 4 , Mn 2 O 3 , MnO 2 , CrO 2 , Cr 2 O 3 , CrO 3 , CoO, Co 3 O, ZrO 2 , Ga 2 O 3 , In 2 O 3 , and combinations thereof.

18. The method of claim 12 , wherein the transition metal matrix includes a nanostructure selected from the group consisting of nanowires, nanorods, nanoplates, nanotubes, nanowires, and combinations thereof.

19. The method of claim 12 , wherein the noble metal includes one selected from the group consisting of ruthenium (Ru), gold (Au), silver (Ag), platinum (Pt), palladium (Pd), iridium (Ir), rhodium (Rh), osmium (Os), and combinations thereof.

Assignees

• Research & Business Found Sungkyunkwan Univ
• Inst Basic Science

Inventors

• Lee Hyoyoung
• Liu Yang

Classifications

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/45

  Nanoparticles · CPC title