Composite material having an aluminosilicate matrix in particular made from barium aluminosilicate (BAS) reinforced with metal oxide reinforcements, and method for preparing same

Patent metadata

Field	Value
Publication number	US-12391617-B2
Application number	US-202117492864-A
Country	US
Kind code	B2
Filing date	Oct 4, 2021
Priority date	Nov 20, 2012
Publication date	Aug 19, 2025
Grant date	Aug 19, 2025

Abstract

A composite material consisting of a matrix made of at least one aluminosilicate notably selected from barium aluminosilicate BAS, barium and strontium aluminosilicate BSAS, strontium aluminosilicate SAS, and mixtures thereof, reinforced by reinforcements made of at least one metal or metalloid oxide, the expansion coefficient of which is close to that of said at least one aluminosilicate.
A method for preparing said composite material.
A composite material according to the invention notably finding its application in the aeronautical or aerospace field, for example for the manufacture of radomes.

First claim

The invention claimed is:

1. A method for preparing a composite material consisting of a matrix made of at least one aluminosilicate, reinforced by reinforcements made of at least one metal oxide or metalloid oxide, the at least one metal oxide or metalloid oxide having a thermal expansion coefficient with a value that is within 30% of the thermal expansion coefficient of said at least one aluminosilicate, the method comprising the following successive steps a) to d):
a) placing into contact a powder of at least one aluminosilicate selected from barium aluminosilicate BAS, barium and strontium aluminosilicate BSAS, strontium aluminosilicate SAS, and mixtures thereof, with reinforcements made of at least one metal oxide or metalloid oxide having a thermal expansion coefficient with a value that is within 30% of the thermal expansion coefficient of said at least one aluminosilicate;
b) sintering the powder of at least one aluminosilicate and the reinforcements made of at least one metal oxide or metalloid oxide by a hot sintering method using a pulsed electric field;
c) cooling the sintered powder and reinforcements; and
d) recovering the composite material.

2. The method according to claim 1 , wherein the powder of at least one aluminosilicate is barium aluminosilicate BAS powder.

3. The method according to claim 2 , wherein the BAS in majority by mass comprises BAS of hexagonal structure.

4. The method according to claim 3 , wherein the BAS powder, wherein in majority by mass comprises BAS of hexagonal structure, is prepared by carrying out the following successive steps:
mixing BaCO 3 powder and SiO 2 powder in a molar ratio of 1 BaCO 3 for 2 SiO 2 ;
drying and then sintering the mixture of the BaCO 3 powder and of the SiO 2 powder to obtain a compound in majority consisting of the compound BaSi 2 O 5 ;
milling the compound in majority consisting of BaSi 2 O 5 to obtain a powder of said compound in majority consisting of BaSi 2 O 5 ;
mixing the powder of the compound in majority consisting of BaSi 2 O 5 , and Al 2 O 3 powder, in a molar ratio of 1 BaSi 2 O 5 for 1 Al 2 O 3 ;
drying and then sintering the mixture of the powder of the compound in majority consisting of BaSi 2 O 5 , and of the Al 2 O 3 powder; and
milling the sintered mixture to obtain the BAS powder which in majority by mass comprises BAS of hexagonal structure.

5. The method according to claim 3 , wherein the reinforcements are made of alumina.

6. The method according to claim 2 , wherein the BAS in majority by mass comprises BAS of monoclinic structure.

7. The method according to claim 6 , wherein the reinforcements are made of silica and/or made of mullite.

8. The method according to claim 1 , wherein the reinforcements made of at least one metal oxide or metalloid oxide appear in one or more form(s) selected from particles and fabrics of fibers.

9. The method according to claim 8 , wherein the at least one metal oxide or metalloid oxide is in the form of particles and the particles are selected from long fibers having a length of from 100 μm to 10 mm and short fibers (whiskers) having a length of from 0.5 μm to 100 μm.

10. The method according to claim 8 , wherein the step a) further comprises preparing a mixture of a powder of the at least one aluminosilicate and of particles of the at least one metal oxide or metalloid oxide.

11. The method according to claim 10 , wherein the at least one aluminosilicate is barium aluminosilicate powder.

12. The method according to claim 8 , wherein the step a) further comprises impregnating a fabric of fibers comprising the at least one metal oxide or metalloid oxide with a slurry of the powder of at least one aluminosilicate.

13. The method according to claim 12 , wherein the at least one aluminosilicate is barium aluminosilicate powder.

14. The method according to claim 1 , wherein the matrix represents 99 to 50% by mass of the material, and the reinforcements represent 1 to 50% by mass of the material.

15. The method according to claim 1 , wherein the composite material is a dense material with a density from 80% to 100% of the theoretical density.

Assignees

• Commissariat Energie Atomique
• Centre Nat Rech Scient

Inventors

• Allemand Alexandre
• Billard Romain
• Le Petitcorps Yann

Classifications

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B2235/5264

  characterised by the diameter of the fibers · CPC title

• C04B2235/5232

  Silica or silicates other than aluminosilicates, e.g. quartz · CPC title

• C04B2235/666

  Applying a current during sintering, e.g. plasma sintering [SPS], electrical resistance heating or pulse electric current sintering [PECS] · CPC title