Porous composite and method of producing porous composite

Patent metadata

Field	Value
Publication number	US-12390793-B2
Application number	US-202217805497-A
Country	US
Kind code	B2
Filing date	Jun 6, 2022
Priority date	Feb 4, 2020
Publication date	Aug 19, 2025
Grant date	Aug 19, 2025

Abstract

A porous composite includes a porous base material, and a porous collection layer provided on a collection surface of the base material (e.g., on inner surfaces of first cells). The collection layer contains catalyst particles of rare-earth oxide or transition-metal oxide situated in pores of the collection surface of the base material. The collection surface has a covered region that is covered with the collection layer and whose total area is 60% or less of the total area of the collection surface.

First claim

The invention claimed is:

1. A porous composite comprising:
a porous base material; and
a porous collection layer provided on a collection surface of said base material,
wherein said collection layer contains catalyst particles of rare-earth oxide and/or transition metal oxide situated in pores of said collection surface of said base material, and
said collection surface has a covered region that is covered with said collection layer and whose total area is 60% or less of a total area of said collection surface.

2. The porous composite according to claim 1 , wherein
said catalyst particles are made of CeO 2 , lanthanum-manganese-cerium oxide, or lanthanum-praseodymium-cerium oxide.

3. The porous composite according to claim 1 , wherein
said catalyst particles have a maximum particle size less than or equal to 10 μm, and
said catalyst particles have a median diameter less than 1.0 μm.

4. The porous composite according to claim 1 , wherein
a total area of said covered region situated in a region other than the pores of said collection surface is 30% or less of the total area of said collection surface.

5. The porous composite according to claim 1 , wherein
said collection layer in the pores of said collection surface of said base material has a porosity higher than or equal to 20% and lower than or equal to 80%.

6. The porous composite according to claim 1 , wherein
said base material has a honeycomb structure whose interior is partitioned into a plurality of cells by a partition wall, and
at least some of said plurality of cells have inner surfaces serving as said collection surface.

7. The porous composite according to claim 6 , wherein the porous composite is a gasoline particulate filter that collects particulate matter in an exhaust gas emitted from a gasoline engine.

8. The porous composite according to claim 6 , wherein said plurality of cells include:
a first cell that is open at an end of a first side in a longitudinal direction and is sealed at an end of a second side in the longitudinal direction; and
a second cell that is sealed at an end of said first side in the longitudinal direction and is open at an end of said second side in the longitudinal direction, and
said first cell has an inner surface that serves as said collection surface on which said collection layer is provided, and
said second cell has an inner surface on which said collection layer is not provided.

9. A method of producing a porous composite according to claim 1 , comprising:
a) atomizing a raw material containing a rare-earth element and/or a transition metal element into raw mist;
b) generating catalyst particles of rare-earth oxide and/or transition metal oxide by heating said raw mist; and
c) forming a porous collection layer by adding said catalyst particles together with a carrier gas to a porous base material so as to deposit said catalyst particles in pores of a collection surface of said base material,
wherein in said operation b), a temperature of heating said raw mist is lower than 1000° C., and
said collection surface after said operation c) has a covered region that is covered with said collection layer and whose total area is 60% or less of a total area of said collection surface.

10. The method of producing a porous composite according to claim 9 , wherein
in said operation c), said catalyst particles are added to said base material for a period of time longer than or equal to 0.5 minutes and shorter than or equal to 60 minutes.

Assignees

• Ngk Insulators Ltd

Inventors

• Kuboyama Masashi
• Hidaka Kenichi
• Nakashima Takuya
• Izumi Yunie

Classifications

• B01J35/50

  characterised by their shape or configuration · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title