Light-emitting device, display device, light-emitting apparatus, electronic device, and lighting device

Patent metadata

Field	Value
Publication number	US-12389739-B2
Application number	US-202217672799-A
Country	US
Kind code	B2
Filing date	Feb 16, 2022
Priority date	Feb 25, 2021
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

A light-emitting device with high emission efficiency is provided. The light-emitting device includes a first electrode, a second electrode, and an EL layer positioned between the first electrode and the second electrode. The EL layer includes at least a light-emitting layer, a first layer, a second layer, and a third layer. The first layer is positioned between the first electrode and the light-emitting layer. The third layer is positioned between the first layer and the light-emitting layer. The second layer is positioned between the first layer and the third layer. The first layer includes a first organic compound. The second layer includes a second organic compound. The third layer includes a third organic compound. The ordinary refractive index of the second organic compound is higher than the ordinary refractive indices of the first organic compound and the third organic compound.

First claim

What is claimed is:

1. A light-emitting device comprising:
a first electrode;
a second electrode; and
an Electro-Luminescent (EL) layer positioned between the first electrode and the second electrode,
wherein the EL layer comprises at least a light-emitting layer, a first layer, a second layer, and a third layer,
wherein the first layer is positioned between the first electrode and the light-emitting layer,
wherein the third layer is positioned between the first layer and the light-emitting layer,
wherein the second layer is positioned between the first layer and the third layer,
wherein the first layer comprises a first organic compound,
wherein the second layer comprises a second organic compound,
wherein the third layer comprises a third organic compound,
wherein an ordinary refractive index of the second organic compound with respect to light with any of wavelengths greater than or equal to 450 nm and less than or equal to 650 nm is higher than an ordinary refractive index of the first organic compound with respect to light with any of the wavelengths and an ordinary refractive index of the third organic compound with respect to light with any of the wavelengths, and
wherein a value obtained by subtracting a Giant Surface Potential (GSP) (mV/nm) of the third layer from a GSP (mV/nm) of the first layer is less than or equal to 10 (mV/nm).

2. The light-emitting device according to claim 1 , wherein an ordinary refractive index of the second organic compound with respect to light with a wavelength of 633 nm is higher than an ordinary refractive index of the first organic compound with respect to light with the wavelength of 633 nm and an ordinary refractive index of the third organic compound with respect to light with the wavelength of 633 nm.

3. The light-emitting device according to claim 1 ,
wherein a difference between a Highest Occupied Molecular Orbit (HOMO) level of the first organic compound and a HOMO level of the third organic compound is less than or equal to 0.2 eV.

4. The light-emitting device according to claim 1 , wherein the first organic compound and the third organic compound are the same organic compound.

5. The light-emitting device according to claim 1 ,
wherein a difference between a Highest Occupied Molecular Orbit (HOMO) level of the first organic compound and a HOMO level of the second organic compound is less than or equal to 0.2 eV.

6. The light-emitting device according to claim 1 , wherein the third layer does not comprise fluorine.

7. The light-emitting device according to claim 1 , wherein the first layer to the third layer each have a thickness larger than or equal to 25 nm and smaller than or equal to 70 nm.

8. The light-emitting device according to claim 1 , wherein the thickness of the second layer is larger than a thickness of the first layer and the thickness of the third layer.

9. The light-emitting device according to claim 1 ,
wherein the first layer is in contact with the second layer, and
wherein the second layer is in contact with the third layer.

10. The light-emitting device according to claim 1 , wherein the first electrode comprises a reflective electrode.

11. The light-emitting device according to claim 1 , wherein a value obtained by subtracting the GSP (mV/nm) of the third layer from a GSP (mV/nm) of the second layer is less than or equal to 10 (mV/nm).

12. The light-emitting device according to claim 1 , wherein the value obtained by subtracting the GSP (mV/nm) of the third layer from the GSP (mV/nm) of the first layer is less than or equal to 0 (mV/nm).

13. The light-emitting device according to claim 1 , wherein the GSP (mV/nm) of the third layer is larger than a GSP (mV/nm) of the second layer.

14. The light-emitting device according to claim 1 , wherein the GSP (mV/nm) of the third layer is larger than the GSP (mV/nm) of the first layer.

15. The light-emitting device according to claim 1 , wherein a GSP (mV/nm) of the second layer is larger than the GSP (mV/nm) of the first layer.

16. The light-emitting device according to claim 1 , wherein the first organic compound and the third organic compound are different organic compounds.

17. A display device comprising:
a first light-emitting device; and
a second light-emitting device,
wherein the first light-emitting device comprises the light-emitting device according to claim 1 ,
wherein the second light-emitting device comprises an Electro-Luminescent (EL) layer between a third electrode and the second electrode,
wherein the EL layer of the second light-emitting device comprises at least a light-emitting layer, a fourth layer, a fifth layer, and a sixth layer,
wherein the fourth layer, the fifth layer, and the sixth layer respectively have the same structure as the first layer, the second layer, and the third layer, and
wherein a peak wavelength of light emitted from a light-emitting material comprised in the light-emitting layer of the first light-emitting device is different from a peak wavelength of light emitted from a light-emitting material comprises in the light-emitting layer of the second light-emitting device by more than or equal to 30 nm.

18. A display device comprising:
a first light-emitting device; and
a second light-emitting device,
wherein the first light-emitting device comprises the light-emitting device according to claim 1 ,
wherein the second light-emitting device comprises an Electro-Luminescent (EL) layer between a third electrode and the second electrode,
wherein the EL layer of the second light-emitting device comprises at least a light-emitting layer, a fourth layer, a fifth layer, and a sixth layer,
wherein the fourth layer, the fifth layer, and the sixth layer respectively have the same thickness as the first layer, the second layer, and the third layer, and
wherein a peak wavelength of light emitted from a light-emitting material comprised in the light-emitting layer of the first light-emitting device is different from a peak wavelength of light emitted from a light-emitting material comprised in the light-emitting layer of the second light-emitting device by more than or equal to 30 nm.

19. A display device comprising:
the light-emitting device according to claim 1 ; and
at least one of a sensor, an operation button, a speaker, and a microphone.

20. A light-emitting apparatus comprising:
the light-emitting device according to claim 1 ; and
at least one of a transistor and a substrate.

21. A lighting device comprising:
the light-emitting device according to claim 1 ; and
a housing.

22. A light-emitting device comprising:
a first electrode;
a second electrode; and
an Electro-Luminescent (EL) layer positioned between the first electrode and the second electrode,
wherein the EL layer comprises at least a light-emitting layer, a first layer, a second layer, and a third layer,
wherein the first layer is positioned between the first electrode and the light-emitting layer,
wherein the third layer is positioned between the first layer and the light-emitting layer,
wherein the second layer is positioned between the first layer and the third layer,
wherein the first layer comprises a first organic compound,
wherein the second layer comprises a second organic compound,
wherein the third layer comprises a third organic compound,
wherein an ordinary refractive index of the second organic compound with respect to light with any of wavelengths greater than or equal to 455 nm and less th

Assignees

• Semiconductor Energy Lab

Inventors

• Watabe Takeyoshi
• Ueda Airi
• Kawano Yuta
• Ohsawa Nobuharu
• Seo Satoshi

Classifications

• H10K50/818

  Reflective anodes, e.g. ITO combined with thick metallic layers · CPC title

• H10K85/00

  Organic materials used in the body or electrodes of devices covered by this subclass · CPC title

• H10K59/879

  comprising refractive means, e.g. lenses · CPC title

• H10K59/876

  comprising a resonant cavity structure, e.g. Bragg reflector pair · CPC title

• H10K59/80518

  Reflective anodes, e.g. ITO combined with thick metallic layers · CPC title