Fuel cell system including catalyst ring anode tail gas oxidizer

Patent metadata

Field	Value
Publication number	US-12388100-B2
Application number	US-202217655289-A
Country	US
Kind code	B2
Filing date	Mar 17, 2022
Priority date	Nov 11, 2021
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

A fuel cell system anode tail gas oxidizer (ATO) includes an inner ATO wall, an outer ATO wall, and a first catalyst ring disposed in a chamber formed between the inner ATO wall and the outer ATO wall. The first catalyst ring includes an inner wall, an outer wall, and a matrix disposed between the inner wall and the outer wall and loaded with an oxidation catalyst.

First claim

The invention claimed is:

1. An anode tail gas oxidizer (ATO), comprising:
an inner ATO wall;
an outer ATO wall; and
a first catalyst ring disposed in a chamber formed between the inner ATO wall and the outer ATO wall, the first catalyst ring comprising:
an inner wall that contacts the inner ATO wall;
an outer wall that contacts the outer ATO wall; and
a matrix that extends from the inner wall to the outer wall, the matrix comprising channels that are loaded with an oxidation catalyst and that extend from a top surface to an opposing bottom surface of the first catalyst ring.

2. The ATO of claim 1 , wherein:
the ATO is configured to provide fluid flow through the chamber in an axial direction; and
the channels extend lengthwise in the axial direction.

3. The ATO of claim 1 , wherein the matrix comprises:
concentric cylindrical walls; and
cylindrical corrugated spacers disposed between the walls.

4. The ATO of claim 3 , wherein the cylindrical walls and the spacers are brazed to each other to form the matrix.

5. The ATO of claim 3 , wherein the matrix comprises at least three of the concentric cylindrical walls which are separated by the cylindrical corrugated spacers.

6. The ATO of claim 3 , wherein the channels are at least partially defined by the walls and the spacers.

7. The ATO of claim 6 , wherein the channels have a trapezoidal horizontal cross sectional shape, with the short and long parallel trapezoid sides alternating in an angular direction.

8. The ATO of claim 1 , wherein the channels have a hexagonal horizontal cross sectional shape.

9. The ATO of claim 1 , wherein the matrix comprises at least ten of the channels in a radial direction perpendicular to an axial direction of fluid flow through the first catalyst ring.

10. The ATO of claim 1 , wherein the matrix comprises alumina.

11. An anode tail gas oxidizer (ATO), comprising:
an inner ATO wall;
an outer ATO wall;
a first catalyst ring disposed in a chamber formed between the inner ATO wall and the outer ATO wall, the first catalyst ring comprising:
an inner wall;
an outer wall; and
a matrix disposed between the inner wall and the outer wall and loaded with an oxidation catalyst; and

a second catalyst ring disposed in the chamber below the first catalyst ring, the second catalyst ring comprising:
an inner wall;
an outer wall; and
a matrix disposed between the inner wall and the outer wall and loaded with an oxidation catalyst.

12. The ATO of claim 11 , wherein the first and second catalyst ring directly contact each other or are spaced apart within the chamber.

13. The ATO of claim 11 , further comprising a third catalyst ring disposed in the chamber below the second catalyst ring, the third catalyst ring comprising:
an inner wall;
an outer wall; and
a matrix disposed between the inner wall and the outer wall and loaded with an oxidation catalyst.

14. A fuel cell system comprising:
fuel cell stacks;
a central column; and
the ATO of claim 1 located between the fuel cell stacks and the central column.

15. The fuel cell system of claim 14 , wherein:
the ATO is cylindrical and surrounds the central column; and
the fuel cell stacks surround the ATO.

16. The fuel cell system of claim 15 , wherein the central column comprises:
an anode recuperator configured to heat fuel provided to the fuel cell stacks using anode exhaust output from the fuel cell stacks; and
an anode exhaust cooler configured to heat air provided to the fuel cell stacks using the anode exhaust output from and the anode recuperator.

17. The fuel cell system of claim 16 , further comprising a splitter configured to provide a first portion of the anode exhaust output from the anode recuperator to the ATO, and to provide a second portion of the anode exhaust output from the anode recuperator to the anode exhaust cooler.

18. The fuel cell system of claim 17 , further comprising a vortex generator containing vanes located above the splitter and configured to swirl cathode exhaust output from the fuel cell stacks into the first portion of the anode exhaust flowing from the splitter through the chamber toward the first catalyst ring.

19. The fuel cell system of claim 17 , wherein the ATO surrounds the anode recuperator.

20. The fuel cell system of claim 17 , wherein:
the cathode exhaust oxidizes a majority of the first portion of the anode exhaust in the chamber before the anode exhaust enters the first catalyst ring; and
the first catalyst ring is configured to oxidize a remaining part of the first portion of the anode exhaust.

21. A fuel cell system comprising:
fuel cell stacks;
a central column comprising an anode recuperator configured to heat fuel provided to the fuel cell stacks using anode exhaust output from the fuel cell stacks, and an anode exhaust cooler disposed configured to heat air provided to the fuel cell stacks using the anode exhaust output from and the anode recuperator;
an anode tail gas oxidizer (ATO), located between the fuel cell stacks and the central column;
a splitter configured to provide a first portion of the anode exhaust output from the anode recuperator to the ATO, and to provide a second portion of the anode exhaust output from the anode recuperator to the anode exhaust cooler; and
a vortex generator containing vanes located above the splitter;
wherein:
the ATO comprises:
an inner ATO wall;
an outer ATO wall;
a first catalyst ring disposed in a chamber formed between the inner ATO wall and the outer ATO wall, the first catalyst ring comprising:
an inner wall;
an outer wall; and
a matrix disposed between the inner wall and the outer wall and loaded with an oxidation catalyst; and

the vortex generator is configured to swirl cathode exhaust output from the fuel cell stacks into the first portion of the anode exhaust flowing from the splitter through the chamber toward the first catalyst ring.

Assignees

• Bloom Energy Corp

Inventors

• Petrucha Michael
• Fisher John
• Basu Nilanjana
• Perry Martin
• Ranganathan Srikanth
• Silva Victor

Classifications

• H01M8/04761

  of fuel cell exhausts · CPC title

• H01M8/04097 Primary

  with recycling of the reactants (H01M8/04119, H01M8/04104 take precedence) · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/0827

  at least part of the fuel being a recycle stream · CPC title

• C01B2203/066

  with fuel cells · CPC title