Ferrite particles, electrophotographic developer carrier core material, electrophotographic developer carrier, and electrophotographic developer

Patent metadata

Field	Value
Publication number	US-12386281-B2
Application number	US-202017433591-A
Country	US
Kind code	B2
Filing date	Feb 20, 2020
Priority date	Feb 25, 2019
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

The present invention provides: a ferrite particle containing a crystal phase component containing a perovskite crystal represented by the compositional formula RZrO 3 (where R is an alkaline earth metal element); and an electrophotographic developer carrier core material, an electrophotographic developer carrier, and an electrophotographic developer containing the ferrite particles.

First claim

The invention claimed is:

1. A ferrite particle having a unified polycrystalline body comprising a ferrite component and a perovskite crystal represented by the compositional formula: RZrO 3 , wherein R represents an alkaline earth metal element, wherein the ferrite particle comprises 0.05% by mass or more and 2.50% by mass or less of the perovskite crystal when a phase composition analysis of a crystal phase constituting the ferrite particle is performed by a Rietveld analysis of an X-ray diffraction pattern.

2. The ferrite particle according to claim 1 , wherein R is at least one element selected from the group consisting of Sr, Ca, and Ba.

3. The ferrite particle according to claim 1 , having a ratio log L/log H between a logarithmic value of a resistance value L (log Ω) in a low-temperature and low-humidity environment (10° C., relative humidity 20%) and a logarithmic value of a resistance value H (log Ω) in a high-temperature and high-humidity environment (30° C., relative humidity 80%) being 1.0 or more and 1.15 or less when measured at a distance between electrodes of 2 mm and an applied voltage of 500 V.

4. The ferrite particle according to claim 3 , having the resistance value H of 1.0×10 7 (Ω) or more and 1.0×10 9 (Ω) or less, and a saturation magnetization obtainable by a VSM measurement when a magnetic field of 1K·1000/4π·A/m is applied being 55 emu/g or more and 65 emu/g or less.

5. The ferrite particle according to claim 1 , wherein the ferrite component is a crystal phase component comprising a spinel crystal represented by the compositional formula: (MO)a(Fe 2 O 3 )b, wherein M represents at least one metal element selected from the group consisting of Fe, Mg, Mn, Cu, Zn, and Ni, and a+b=100 (mol %) as a main component.

6. The ferrite particle according to claim 1 , wherein the ferrite component is a crystal phase component comprising a spinel crystal represented by the compositional formula: (MnO)x(MgO)y(Fe 2 O 3 )z, wherein 15≤x≤50, 2≤y≤35, 45≤z≤60, x+y+z=100 (mol %) as a main component.

7. An electrophotographic developer carrier core material, comprising the ferrite particle described in claim 1 .

8. An electrophotographic developer carrier, comprising the ferrite particle described in claim 1 and a resin coating layer provided on a surface of the ferrite particle.

9. An electrophotographic developer, comprising the electrophotographic developer carrier described in claim 8 and a toner.

10. The electrophotographic developer according to claim 9 , used as a replenishment developer.

11. The ferrite particle according to claim 1 , wherein at least a portion of the perovskite crystal is dispersed on boundaries between grains of the unified polycrystalline body of the ferrite particle.

12. The ferrite particle according to claim 5 , wherein at least a portion of the perovskite crystal is dispersed on boundaries between grains of the spinel crystal.

13. The ferrite particle according to claim 6 , wherein at least a portion of the perovskite crystal is dispersed on boundaries between grains of the spinel crystal.

14. The ferrite particle according to claim 1 , wherein the ferrite particle comprises an inner portion and a surface portion and wherein at least a portion of the perovskite crystal is dispersed in the inner portion of the ferrite particle.

15. The ferrite particle according to claim 14 , wherein the perovskite crystal is dispersed in both the inner portion and the surface portion of the ferrite particle.

Assignees

• Powdertech Co Ltd

Inventors

• Ishikawa Makoto
• Uemura Tetsuya

Classifications

• H01F1/36

  in the form of particles {(H01F1/346, H01F1/348 and H01F1/38 take precedence)} · CPC title

• C01G49/0018

  Mixed oxides or hydroxides, (C01G49/0009 takes precedence) · CPC title

• H01F1/344

  Ferrites, e.g. having a cubic spinel structure (X2+O)(Y23+O3), e.g. magnetite Fe3O4 · CPC title

• G03G9/1132

  Macromolecular components of coatings · CPC title

• C01P2006/12

  Surface area · CPC title