High performance gear oil and related methods

Patent metadata

Field	Value
Publication number	US-12384983-B2
Application number	US-202418651789-A
Country	US
Kind code	B2
Filing date	May 1, 2024
Priority date	May 1, 2023
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

Gear oil compositions including a first oil basestock and a second basestock. The first basestock includes a Group II bright stock having a kinematic viscosity (ASTM D445, 40° C.) of from 250 mm 2 /s to 600 mm 2 /s, a kinematic viscosity (ASTM D445, 100° C.) of from 20 mm 2 /s to 70 mm 2 /s, a viscosity index (ASTM D2270) of from 80 to 120, and a pour point (ASTM D97) of from −50° C. to −20° C. The second basestock includes a polyalphaolefin (PAO) basestock having a kinematic viscosity (ASTM D445, 40° C.) of from 500 mm 2 /s to 3500 mm 2 /s, a kinematic viscosity (ASTM D445, 100° C.) of from 60 mm 2 /s to 300 mm 2 /s, a viscosity index (ASTM D2270) of from 150 to 250, and a pour point (ASTM D97) of from −50° C. to −20° C.

First claim

What is claimed is:

1. A gear oil composition comprising:
a first oil basestock, the first oil basestock being a Group II bright stock having:
a kinematic viscosity (ASTM D445, 40° C.) of from 450 mm 2 /s to 520 mm 2 /s,
a kinematic viscosity (ASTM D445, 100° C.) of from 20 mm 2 /s to 70 mm 2 /s,
a viscosity index (ASTM D2270) of from 80 to 120, and
a pour point (ASTM D97) of from −50° C. to −20° C.; and

a second oil basestock, the second oil basestock being a polyalphaolefin (PAO) basestock having:
a kinematic viscosity (ASTM D445, 40° C.) of from 500 mm 2 /s to 3500 mm 2 /s,
a kinematic viscosity (ASTM D445, 100° C.) of from 60 mm 2 /s to 300 mm 2 /s,
a viscosity index (ASTM D2270) of from 150 to 250, and
a pour point (ASTM D97) of from −50° C. to −20° C.

2. The gear oil composition of claim 1 , wherein the first oil basestock is present from 15 wt. % to 50 wt. %, by total weight of the gear oil composition.

3. The gear oil composition of claim 1 , wherein the second oil basestock is present from 10 wt. % to 70 wt. %, by total weight of the gear oil composition.

4. The gear oil composition of claim 1 , wherein the second oil basestock is selected from the group consisting of a light conventional PAO, a heavy conventional PAO, a metallocene PAO, and any combination thereof.

5. The gear oil composition of claim 1 , wherein the first oil basestock and the second oil basestock combined are present from 60 wt. % to 99.5 wt. %, by total weight of the gear oil composition.

6. The gear oil composition of claim 1 , further comprising a solubilizing agent and wherein the solubilizing agent is selected from the group consisting of a dibasic acid and an alcohol; an ester of a monocarboxylic acid of 5 to 18 carbon atoms and polyol; a polyoxyalkylene glycol; a polyoxyalkylene glycol ester; a polyoxyalkylene glycol ether and phosphate ester; a naphthalene compound; and any combination thereof.

7. The gear oil composition of claim 1 , further comprising a third oil basestock, the third oil basestock being a Group V basestock having:
a kinematic viscosity (ASTM D445, 40° C.) of from 15 mm 2 /s to 600 mm 2 /s,
a kinematic viscosity (ASTM D445, 100° C.) of from 4 mm 2 /s to 60 mm 2 /s,
a viscosity index (ASTM D2270) of from 80 to 200, and
a pour point (ASTM D97) of from −60° C. to −20° C.

8. The gear oil composition of claim 7 , wherein the first oil basestock, the second oil basestock, and the third oil basestock combined are present from 60 wt. % to 99.5 wt. %, by total weight of the gear oil composition.

9. The gear oil composition of claim 1 , further comprising at least one additive selected from the group consisting of an ashless dispersant, a pour point depressant, an antifoaming agent, an antioxidant, a rust inhibitor, a friction modifier, and any combination thereof.

10. The gear oil composition of claim 1 , further comprising an ashless dispersant present from 0.05 wt. % to 5 wt. %, by total weight of the gear oil composition.

11. The gear oil composition of claim 1 , further comprising a pour point depressant present from 0.05 wt. % to 5 wt. %, by total weight of the gear oil composition.

12. The gear oil composition of claim 1 , further comprising an antifoaming agent present from 0.05 wt. % to 5 wt. %, by total weight of the gear oil composition.

13. The gear oil composition of claim 1 , further comprising (1) an antioxidant present from 0.05 wt. % to 5 wt. %, by total weight of the gear oil composition; (2) a rust inhibitor present from 0.05 wt. % to 5 wt. %, by total weight of the gear oil composition; or both (1) and (2).

14. The gear oil composition of claim 1 , further comprising a friction modifier present from 0.05 wt. % to 5 wt. %, by total weight of the gear oil composition.

15. The gear oil composition of claim 1 , wherein the gear oil has a pour point of less than −20° C. in the absence of a pour point depressant.

16. The gear oil composition of claim 1 , wherein the gear oil has a viscosity index from greater than 150 in the absence of a viscosity index improver.

17. The gear oil composition of claim 1 , wherein the gear oil is pre-blended and is combined with a second pre-blended gear oil comprising the composition of claim 1 , and wherein the combination exhibits a lower viscosity index and lower kinematic viscosity at 40° C. and 100° C. compared to each of the pre-blended compositions alone.

18. The gear oil composition of claim 1 , wherein the first oil basestock has:
a kinematic viscosity (ASTM D445, 100° C.) of from 32.5 mm 2 /s to 35.5 mm 2 /s.

19. A method comprising:
mixing a first oil basestock and a second basestock,
wherein the first basestock is a Group II bright stock having:
a kinematic viscosity (ASTM D445, 40° C.) of from 450 mm 2 /s to 520 mm 2 /s,
a kinematic viscosity (ASTM D445, 100° C.) of from 20 mm 2 /s to 70 mm 2 /s,
a viscosity index (ASTM D2270) of from 80 to 120, and
a pour point (ASTM D97) of from −50° C. to −20° C.; and

wherein the second basestock is a polyalphaolefin (PAO) basestock having:
a kinematic viscosity (ASTM D445, 40° C.) of from 500 mm 2 /s to 3500 mm 2 /s,
a kinematic viscosity (ASTM D445, 100° C.) of from 60 mm 2 /s to 300 mm 2 /s,
a viscosity index (ASTM D2270) of from 150 to 250, and
a pour point (ASTM D97) of from −50° C. to −20° C.

20. The method of claim 19 , further comprising a third oil basestock, the third oil basestock being a Group V basestock having:
a kinematic viscosity (ASTM D445, 40° C.) of from 15 mm 2 /s to 600 mm 2 /s,
a kinematic viscosity (ASTM D445, 100° C.) of from 4 mm 2 /s to 60 mm 2 /s,
a viscosity index (ASTM D2270) of from 80 to 200, and
a pour point (ASTM D97) of from −60° C. to −20° C.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Hawkins Harrison T
• Blumenfeld Michael
• Brown Nilka Y
• Pathare Rugved P

Classifications

• C10N2040/04

  Oil-bath; Gear-boxes; Automatic transmissions; Traction drives · CPC title

• C10N2030/18

  Anti-foaming property · CPC title

• C10N2030/12

  Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title