Lubricating oil composition

Patent metadata

Field	Value
Publication number	US-12384982-B2
Application number	US-202218260064-A
Country	US
Kind code	B2
Filing date	Mar 4, 2022
Priority date	Mar 30, 2021
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

A lubricating oil composition may contain a base oil (A) and a dispersant-type viscosity index improver (B), in which the nitrogen atom content based on the solid content of the dispersant-type viscosity index improver (B) is 0.50 to 1.50% by mass, and the weight-average molecular weight (Mw) thereof is 100,000 or more, and the content in terms of the solid content based on the total amount of the composition of the dispersant-type viscosity index improver (B) is more than 0.05% by mass and less than 5.0% by mass. The lubricating oil composition may exert excellent wear resistance in a state contaminated with soot.

First claim

The invention claimed is:

1. A lubricating oil composition, comprising:
a base oil that is present in a range of from 60% to 99% by mass, based on a total amount of the lubricating oil composition;
a dispersant-type viscosity index improver selected from the group consisting of a dispersant-type nitrogen-containing poly(meth)acrylate and a dispersant-type nitro-containing polyolefin and having a weight-average molecular weight in a range of 120,000 to 240,000;
a non-dispersant-type viscosity index improver which is a non-dispersant-type poly(meth)acrylate having a weight-average molecular weight in a range of 280,000 to 310,000; and
a molybdenum-based friction modifier which is a binuclear molybdenum dithiocarbamate selected from the group consisting of a compound of formula (D-1) and a compound of formula (D-2),

where R 11 to R 14 each independently are a hydrocarbon group having 6 to 22 carbon atoms, X 11 to X 18 each independently are an oxygen atom or a sulfur atom, and at least two of X 11 to X 18 are sulfur atoms,
wherein the dispersant-type viscosity index improver has a nitrogen atom content in a range of 0.77% to 1.05% by mass, based on a solid content of the dispersant-type viscosity index improver, a content of the dispersant-type viscosity index improver in terms of the solid content is in a range of 0.11% to 0.32% by mass, based on the total amount of the lubricating oil composition, a content of the non-dispersant-type viscosity index improver in terms of the solid content is in a range of from 1.4% to 2.1% by mass, based on the total amount of the lubricating oil composition, a content of the molybdenum-based friction modifier in terms of the solid content is in a range of from 0.10% to 0.70% by mass, based on the total amount of the lubricating oil composition, and a solid content mass ratio of the non-dispersant-type viscosity index improver to the dispersant-type viscosity index improver is in a range of from 4.4 to 12.7.

2. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a kinematic viscosity at 100° C. in a range of from 3.0 to 16.0 mm 2 /s.

3. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a viscosity index of 150 or more.

4. The lubricating oil composition of claim 1 , wherein the dispersant-type viscosity index improver has a molecular weight distribution, Mw/Mn, of 3.0 or less.

5. The lubricating oil composition of claim 1 , wherein the molybdenum-based friction modifier is present in a range of from 50 to 2,000 ppm by mass in terms of molybdenum atoms, based on the total amount of the lubricating oil composition.

6. The lubricating oil composition of claim 1 , further comprising:
zinc dithiophosphate.

7. The lubricating oil composition of claim 6 , wherein the zinc dithiophosphate is in a range of from 200 to 5,000 ppm by mass in terms of phosphorus atoms, based on the total amount of the lubricating oil composition.

8. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a dispersant-derived nitrogen atom content of 0.10% by mass or less, based on the total amount of the lubricating oil composition.

9. The lubricating oil composition of claim 8 , wherein the dispersant-derived nitrogen atom content is a total amount of the nitrogen atom derived from a non-boron-modified succinimide and a boron-modified succinimide.

10. The lubricating oil composition of claim 1 , wherein the base oil is present in a range of from 70 to 95% by mass, based on the total amount of the lubricating oil composition.

11. A method for producing the lubricating oil composition of claim 1 , comprising:
mixing the base oil, the dispersant-type viscosity index improver, the non-dispersant-type viscosity index improver, and the molybdenum-based friction modifier.

12. A diesel engine, comprising:
the lubricating oil composition of claim 1 .

13. A method for lubricating an engine, comprising:
contacting the engine with the lubricating oil composition of claim 1 .

14. The lubricating oil composition of claim 1 , wherein the molybdenum-based friction modifier includes the compound of the formula (D-2), where R 11 to R 14 each independently are selected from the group consisting of an isooctyl group and an isotridecyl group, a molar ratio of the isooctyl group to the isotridecyl group in the molybdenum-based friction modifier is 50/50, X 13 and X 14 are sulfur atoms, and X 11 and X 12 are oxygen atoms.

15. The lubricating oil composition of claim 1 , wherein the base oil is present in a range of from 80% to 93% by mass, based on the total amount of the lubricating oil composition.

16. The lubricating oil composition of claim 1 , wherein the base oil is present in a range of from 82.93 to 87.63% by mass, based on the total amount of the lubricating oil composition.

17. The lubricating oil composition of claim 1 , wherein the base oil includes at least one selected from the group consisting of a mineral oil and a synthetic oil.

18. The lubricating oil composition of claim 1 , wherein the base oil includes a Group III mineral oil in American Petroleum Institute base oil category.

19. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a kinematic viscosity at 100° C. in a range of from 7.0 to 10.8 mm 2 /s.

20. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a viscosity index in a range of 192 to 230.

Assignees

• Idemitsu Kosan Co

Inventors

• Fujita Shoichiro
• Sunahara Kenji
• Yamagishi Tsukasa
• Kubota Masaya

Classifications

• C10M2219/068

  Thiocarbamate metal salts · CPC title

• C10M2217/06

  Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2010/12

  Groups 6 or 16 · CPC title

• C10M2209/084

  Acrylate; Methacrylate · CPC title