Method and facility for converting uranium hexafluoride into uranium dioxide

Patent metadata

Field	Value
Publication number	US-12384694-B2
Application number	US-201817283003-A
Country	US
Kind code	B2
Filing date	Oct 9, 2018
Priority date	Oct 9, 2018
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

A conversion process for converting uranium hexafluoride into uranium dioxide includes the steps of hydrolysis of UF 6 to uranium oxyfluoride (UO 2 F 2 ) in a hydrolysis reactor ( 4 ) by reaction between gaseous UF6 and dry water vapour injected into the reactor ( 4 ), pyrohydrolysis of UO 2 F 2 to UO 2 in a pyrohydrolysis furnace ( 6 ) by reacting UO 2 F 2 with dry steam and gaseous hydrogen (H 2 ) injected into the furnace ( 6 ), extracting excess gas in the reactor ( 4 ) via a collecting device ( 50 ) comprising several filters ( 52 ), periodically cleaning the filters ( 52 ) by injecting a neutral gas into the filters ( 52 ) from the outside to the inside of the reactor ( 4 ) to remove powder stuck on the filters ( 52 ), and measuring the relative pressure in the reactor ( 4 ). The conversion method further includes carrying out point cleaning of the filters ( 52 ) when the relative pressure in the reactor ( 4 ) exceeds a predetermined point cleaning threshold.

First claim

What is claimed is:

1. A method for converting uranium hexafluoride (UF 6 ) to uranium dioxide (UO 2 ) in a conversion installation, the method comprising:
hydrolysis of UF 6 to uranium oxyfluoride (UO 2 F 2 ) in a hydrolysis reactor by reaction between gaseous UF 6 and dry water vapor injected into the hydrolysis reactor;
pyrohydrolysis of UO 2 F 2 to UO 2 in a pyrohydrolysis furnace by reaction of UO 2 F 2 with dry water vapor and hydrogen gas (H 2 ) injected into the pyrohydrolysis furnace;
extracting excess gas in the hydrolysis reactor via a capture device comprising several filters;
periodically unclogging of the filters by injecting a neutral gas into the filters from an outside to an inside of the hydrolysis reactor to remove powder stuck on the filters;
measuring the relative pressure in the hydrolysis reactor;
implementing a punctual unclogging of the filters when a relative pressure in the hydrolysis reactor exceeds a predetermined punctual unclogging threshold; and
shutting down the conversion installation if the relative pressure in the hydrolysis reactor exceeds a predetermined safety threshold,
wherein the punctual unclogging threshold is set in a range of 100 mbar below the safety threshold.

2. The method according to claim 1 , further comprising injecting a neutral scavenging gas into the hydrolysis reactor so that the conversion of UF 6 to UO 2 F 2 takes place under a nitrogen atmosphere.

3. The method according to claim 1 , wherein the dry water vapor and the H 2 are injected into the pyrohydrolysis furnace so as to circulate in the pyrohydrolysis furnace against a current of the UO 2 F 2 , to the hydrolysis reactor.

4. The method according to claim 1 , wherein the safety threshold is between 100 and 500 mbar.

5. The method according to claim 1 , further comprising vibrating and/or striking a wall of the hydrolysis reactor.

6. The method according to claim 5 , wherein the vibration is performed by a flow device comprising at least one flow member configured to vibrate and/or strike a wall of the hydrolysis reactor, directly or via an intermediate part.

7. The method according to claim 1 , further comprising impacting a percussion surface of the pyrohydrolysis furnace during the conversion of UO 2 F 2 to UO 2 in order to take off powder of UO 2 F 2 or UO 2 sticking to an internal surface of the pyrohydrolysis furnace.

8. The method according to claim 7 , wherein the pyrohydrolysis furnace comprises a rotary drum receiving the UO 2 F 2 and into which are injected dry water vapor and H 2 , the percussion surface being an outer surface of the drum.

9. The method according to claim 7 , wherein the impacting of the percussion surface is performed using at least one percussion device comprising a striker movable relative to the percussion surface and an intermediate part disposed between the striker and the percussion surface such that the striker strikes the percussion surface via the intermediate part, the intermediate part being movable between a position spaced from the percussion surface and a percussion position in contact with the percussion surface.

10. A conversion installation for converting uranium hexafluoride (UF6) to uranium dioxide (UO2), the conversion installation comprising:
a hydrolysis reactor for the conversion of UF6 to uranium oxyfluoride (UO2F2) by reaction between gaseous UF6 and dry water vapor injected into the reactor;
a pyrohydrolysis furnace for the conversion of UO2F2 to UO2 by reaction of UO2F2 with dry water vapor and hydrogen gas (H2) injected into the furnace;
a capture device for capturing and extracting of excess gas in the reactor, the capture device comprising several filters;
an unclogging device configured for unclogging of the filters by injecting a neutral gas into the filters from the outside to the inside of the reactor to remove a powder stuck on the filters;
a pressure sensor configured for measuring a pressure inside the hydrolysis reactor; and
a control system configured to shut down the conversion installation if the relative pressure in the hydrolysis reactor exceeds a predetermined safety threshold,
the unclogging device configured to:
periodically unclog the filters by injecting a neutral gas into the filters from an outside to an inside of the hydrolysis reactor to remove the powder stuck on the filters; and
implement a punctual unclogging of the filters when a relative pressure in the hydrolysis reactor exceeds a predetermined punctual unclogging threshold,
wherein the punctual unclogging threshold is set in a range of 100 mbar below the safety threshold.

Assignees

• Framatome Sa

Inventors

• Mesona Bruno
• Feugier André
• Yakoubi Alain

Classifications

• Y02W30/50

  Reuse, recycling or recovery technologies · CPC title

• Y02E30/30

  Nuclear fission reactors · CPC title

• G21C19/48

  Non-aqueous processes · CPC title

• C01G43/025 Primary

  Uranium dioxide · CPC title

• F27B7/00

  Rotary-drum furnaces, i.e. horizontal or slightly inclined · CPC title