Installation and method for converting uranium hexafluoride to uranium dioxide

Patent metadata

Field	Value
Publication number	US-12384693-B2
Application number	US-201817282951-A
Country	US
Kind code	B2
Filing date	Oct 9, 2018
Priority date	Oct 9, 2018
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

An installation for the conversion of uranium hexafluoride (UF 6 ) to uranium dioxide (UO 2 ) comprises a hydrolysis reactor ( 4 ) for the conversion of UF 6 into uranium oxyfluoride powder (UO 2 F 2 ), a pyrohydrolysis furnace ( 6 ) for converting the UO 2 F 2 powder supplied by the reactor ( 4 ) into UO 2 powder, a supply device ( 8 ) comprising reagent injection ducts ( 10 ) for the injection of UF 6 , water vapor or H 2 , and a control system ( 16 ) designed to control the supply device ( 8 ) so as to supply at least one of the reagent injection ducts ( 10 ) with a neutral gas during a shutdown or start-up phase of the conversion installation.

First claim

What is claimed is:

1. A conversion installation for converting uranium hexafluoride (UF 6 ) into uranium dioxide (UO 2 ), the conversion installation comprising:
a hydrolysis reactor configured for converting of UF 6 into uranium oxyfluoride powder (UO 2 F 2 ) by reaction between gaseous UF 6 and dry water vapor injected into the hydrolysis reactor;
a pyrohydrolysis furnace configured for converting the UO 2 F 2 powder supplied by the hydrolysis reactor into UO 2 powder by reacting the UO 2 F 2 powder with dry water vapor and dihydrogen (H 2 ) gas injected into the pyrohydrolysis furnace;
a supply device comprising reagent injection ducts configured for injecting UF 6 , water vapor or H 2 , each reagent injection duct being configured to supply the hydrolysis reactor or the pyrohydrolysis furnace; and
a control system configured to control the supply device so as to supply at least one of the reagent injection ducts with a neutral gas during a stopping or starting phase of the conversion installation,
wherein the control system is configured to control the supply device to inject an inert gas in the pyrohydrolysis furnace during the stopping or starting phase of the conversion installation.

2. The conversion installation according to claim 1 , wherein the control system is configured to control the supply device so as to supply each reagent injection duct with the inert gas during the stopping or starting phase of the conversion installation.

3. The conversion installation according to claim 1 , wherein the supply device comprises, in addition to the reagent injection ducts, at least one neutral gas injection duct to inject neutral gas into the hydrolysis reactor during a production phase for converting UF 6 into UO 2 under a neutral gas atmosphere.

4. The conversion installation according to claim 1 , wherein the supply device comprises a neutral gas injection duct for supplying the hydrolysis reactor with neutral gas, forming a neutral gas jet separating a UF 6 jet and a water vapor jet from reagent injection ducts opening into the hydrolysis reactor.

5. The conversion installation according to claim 1 , wherein the control system is configured to supply each of the reagent injection ducts with a neutral gas, by supplying the reagent injection ducts sequentially from upstream to downstream or from downstream to upstream of the conversion installation, taking into account a direction of movement of the uranium in the conversion installation.

6. The conversion installation according to claim 1 , wherein the control system is configured to, in the stopping phase of the conversion installation, successively:
stop the supply of UF 6 to the hydrolysis reactor and replace the supply of UF 6 with a supply of neutral gas; then
stop the supply of dry water vapor to the hydrolysis reactor and replace dry water vapor with a supply of neutral gas; then
optionally, after removing all the UO 2 F 2 powder from the hydrolysis reactor, stop a transfer device configured to transfer the UO 2 F 2 powder from the hydrolysis reactor to the pyrohydrolysis furnace; then
stop the supply of H 2 to the pyrohydrolysis furnace and replace the supply of H 2 with a supply of neutral gas; then
stop the supply of dry water vapor to the pyrohydrolysis furnace and replace the supply of dry water vapor with a supply of neutral gas; then
optionally, after removing all the UO 2 powder from the pyrohydrolysis furnace and cooling a drum of the pyrohydrolysis furnace, stop the drum from rotating.

7. The conversion installation according to claim 1 , wherein the supply device comprises neutral gas injection ducts for supplying the hydrolysis reactor with neutral gas,
wherein the control system is configured to, during the starting phase of the conversion installation, successively:
inject neutral gas into the hydrolysis reactor and the pyrohydrolysis furnace via the reagent injection ducts and the neutral gas injection ducts during a heating step of the conversion installation; then
replace the neutral gas supply via the reagent injection ducts of the pyrohydrolysis furnace and the hydrolysis reactor with a reactive gas supply, by supplying the reagent injection ducts with reactive gases sequentially from downstream to upstream of the conversion installation, taking into account a direction of uranium movement in the conversion installation.

8. A method for converting uranium hexafluoride (UF 6 ) into uranium dioxide (UO 2 ) in the conversion installation recited in claim 1 , the method comprising the steps of:
converting UF 6 into UO 2 by supplying the hydrolysis reactor and the pyrohydrolysis furnace with reactive gases via reagent injection ducts during a conversion phase, each reagent injection duct opening into the hydrolysis reactor or into the pyrohydrolysis furnace; and
supplying at least one of the reagent injection ducts with a neutral gas during the stopping or starting phase of the conversion installation.

9. The conversion method according to claim 8 , wherein during the stopping or starting phase of the conversion installation, each reagent injection duct is supplied with neutral gas.

10. The conversion method according to claim 8 , wherein during a production phase, the neutral gas is injected into the hydrolysis reactor via at least one neutral gas injection duct to achieve conversion under a neutral gas atmosphere.

11. The conversion method according to claim 8 , wherein the stopping phase of the conversion installation comprises a purging step during which the reagent injection ducts are supplied with neutral gas sequentially from upstream to downstream of the conversion installation, taking into account a direction of uranium movement.

12. The conversion method according to claim 8 , further comprising, in the stopping phase of the conversion installation, the successive steps of:
stopping the supply of UF 6 to the hydrolysis reactor and replace the supply of UF 6 with a supply of neutral gas; then
stopping the supply of dry water vapor to the hydrolysis reactor and replace the supply of dry water vapor with a supply of neutral gas; then
optionally, after removing all the UO 2 F 2 powder from the hydrolysis reactor, stopping a transfer device configured to transfer the UO 2 F 2 powder from the hydrolysis reactor to the pyrohydrolysis furnace; then
stopping the supply of H 2 to the pyrohydrolysis furnace and replacing the supply of H 2 with a supply of neutral gas; then
stopping the supply of dry water vapor to the pyrohydrolysis furnace and replace the supply of dry water vapor with a supply of neutral gas; then
optionally, after removing all the UO 2 powder from the pyrohydrolysis furnace and cooling a drum of the pyrohydrolysis furnace, stopping the drum from rotating.

13. The conversion method according to claim 8 , comprising, in a start-up phase of the conversion installation, the successive steps of:
injecting neutral gas into the hydrolysis reactor and the pyrohydrolysis furnace via the reagent injection ducts and neutral gas injection ducts during a heating step of the conversion installation; then
replacing the neutral gas supply via the reagent injection ducts of the pyrohydrolysis furnace and the hydrolysis reactor with a reactive gas supply, by supplying the reagent injection ducts with reactive gases sequentially from downstream to upstream of the conversion installation taking into account a direction of uranium movement.

Assignees

• Framatome Sa

Inventors

• Mesona Bruno
• Hebrard Stéphane

Classifications

• G21C19/46

  Aqueous processes {, e.g. by using organic extraction means, including the regeneration of these means} · CPC title

• G21C3/623

  Oxide fuels · CPC title

• B01J2219/00245

  Avoiding undesirable reactions or side-effects · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J19/14

  Production of inert gas mixtures; Use of inert gases in general · CPC title