Method for preparing TS-1 molecular sieve with hierarchical pores

Patent metadata

Field	Value
Publication number	US-12384686-B2
Application number	US-201817294349-A
Country	US
Kind code	B2
Filing date	Nov 15, 2018
Priority date	Nov 15, 2018
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

The present application discloses a method for preparing a hierarchical porous TS-1 molecular sieve comprising using a silicon-titanium ester polymer as both titanium source and silicon source. In the method, silicon and titanium are uniformly connected to a same polymer, and the hydrolysis rates thereof are equivalent during hydrolysis, which can prevent TiO2 precipitation and reduce the generation of non-framework titanium. Further, the silicon-titanium ester polymer is not only used as both silicon source and titanium source, but also can be used as a mesoporous template in the synthesis process. The obtained TS-1 molecular sieve has mesoporous structure with narrow pore size distribution.

First claim

What is claimed is:

1. A method for preparing a hierarchical porous TS-1 molecular sieve comprising using a silicon-titanium ester polymer as both titanium source and silicon source;
the method for preparing the silicon-titanium ester polymer comprises mixing silicate, titanate, and polyhydric alcohol, and then performing a reaction under stirring conditions and in an inactive atmosphere, wherein the reaction temperature ranges from 80 to 180° C. and the reaction time ranges from 2 to 10 hours;
wherein a molar ratio of the silicate, titanate and polyhydric alcohol satisfies:
titanate:silicate=0.001−0.2;
(titanate+silicate):polyhydric alcohol=(0.5−5)x; 4;
wherein, x is the number of moles of hydroxyl groups contained in each mole of the polyhydric alcohol; and
the number of moles of each component is calculated by the number of moles of the substance itself;
wherein the polyhydric alcohol comprises at least one of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-propanediol, 1,3propanediol, 1,4-butylene glycol, 1,6-hexanediol, polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 600, polyethylene glycol 800, 1,4-cyclohexanediol, 1,4-cyclohexane dimethanol, terephthalyl alcohol, glycerin, trimethylolpropane, pentaerythritol, xylitol and sorbitol;
wherein the reaction further comprises performing vacuum distillation, wherein conditions of the vacuum distillation comprise that a vacuum degree ranges from 0.01 to 5 kPa, a vacuum distillation temperature ranges from 170 to 230° C., and a vacuum distillation time ranges from 0.5 to 5 hours.

2. The method according to claim 1 comprising performing crystallization of a mixture containing the silicon-titanium ester polymer, a template and water to obtain the hierarchical porous TS-1 molecular sieve, wherein the crystallization is hydrothermal crystallization.

3. The method according to claim 2 , wherein a molar ratio of the silicon-titanium ester polymer, template and water satisfies: template:silicon-titanium ester polymer=0.05˜10, water:silicon-titanium ester polymer=5−500;
wherein, the number of moles of the template is based on the number of moles of N atoms in the template;
the number of moles of the silicon-titanium ester polymer is based on the sum of silicon content and titanium content in the silicon-titanium ester polymer;
the silicon content in the silicon-titanium ester polymer is calculated by the number of moles of SiO 2 and the titanium content in the silicon-titanium ester polymer is calculated by the number of moles of TiO 2 ; and
the number of moles of the water is based on the number of moles of H 2 O.

4. The method according to claim 3 , wherein the molar ratio of the silicon-titanium ester polymer, template and water satisfies: template:silicon-titanium ester polymer=0.1˜5; water:silicon-titanium ester polymer=30−300;
wherein, the number of moles of the template is based on the number of moles of N atoms in the template;
the number of moles of the silicon-titanium ester polymer is based on the sum of silicon content and titanium content in the silicon-titanium ester polymer;
the silicon content in the silicon-titanium ester polymer is calculated by the number of moles of SiO 2 , and the titanium content in the silicon-titanium ester polymer is calculated by the number of moles of TiO 2 ; and
the number of moles of the water is based on the number of moles of H 2 O.

5. The method according to claim 2 , wherein the template refers to at least one of organic base templates,
the organic base template comprises a first template which is at least one of tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, triethylpropylammonium hydroxide, tetrapropylammonium halide, tetraethylammonium halide, tetrabutylammonium halide and triethylpropylammonium halide.

6. The method according to claim 5 , wherein the organic base template further includes a second template which is at least one of aliphatic amine and alcohol amine compounds.

7. The method according to claim 2 , wherein conditions of the crystallization are as follows: the crystallization is conducted in sealed condition, a crystallization temperature ranges from 100 to 200° C., and a crystallization time under autogenous pressure does not exceed 30 days.

8. The method according to claim 7 , wherein conditions of the crystallization are as follows: the crystallization is conducted in sealed condition, a crystallization temperature ranges from 120 to 180° C., and a crystallization time under autogenous pressure ranges from 1 to 15 days.

9. The method according to claim 6 , wherein the second template comprises at least one of ethylamine, diethylamine, triethylamine, n-butylamine, butanediamine, hexamethylenediamine, octanediamine, monoethanolamine, diethanolamine and triethanolamine.

10. The method according to claim 7 , wherein the mixture undergoes crystallization after aging, and conditions of aging are that an aging temperature is not higher than 120° C. for an aging time in a range from 0 to 100 hours.

11. The method according to claim 1 , wherein the molar ratio of the silicate, titanate and polyhydric alcohol satisfies:
titanate:silicate=0.005˜0.1;
(titanate+silicate):polyhydric alcohol=(0.8˜1.2)x: 4;
wherein, x is the number of moles of hydroxyl groups contained in each mole of the polyhydric alcohol; and
the number of moles of each component is calculated by the number of moles of the substance itself.

12. The method according to claim 1 , wherein the reaction is carried out in an inactive atmosphere, a reaction temperature ranges from 100 to 160° C. and a reaction time ranges from 4 to 8 hours.

13. The method according to claim 1 , wherein the silicate is at least one of compounds having a chemical formula shown in Formula I:

wherein, R 1 , R 2 , R 3 and R 4 are independently selected from C 1 to C 10 alkyl group.

14. The method according to claim 13 , wherein the silicate comprises at least one of tetramethoxysilane, tetratetraethyl orthosilicate, tetrapropyl silicate and tetrabutyl silicate.

15. The method according to claim 1 , wherein the titanate is at least one of compounds having a chemical formula shown in Formula II,

wherein, R 5 , R 6 , R 7 and R 8 are independently selected from C 1 to C 10 alkyl group.

16. The method according to claim 15 , wherein the titanate includes at least one of tetraethyl titanate, tetraisopropyl titanate, tetrabutyl titanate, tetrahexyl titanate, and tetraisooctyl titanate.

17. The method according to claim 1 comprising:
a) mixing silicate, titanate and polyhydric alcohol, and then performing the reaction under stirring conditions and in an nitrogen atmosphere for protection, wherein the reaction temperature ranges from 80 to 180° C., and the reaction time ranges from 2 to 10 hours;
b) after the reaction in step a), performing vacuum distillation to prepare the silicon-titanium ester polymer, during which the vacuum degree ranges from 0.01 to 5 kPa, the vacuum distillation temperature ranges from 170 to 230° C., and the vacuum distillation time ranges from 0.5 to 5 hours;
c) mixing the silicon-titanium ester polymer obtained in step b) with an organic base template and water, and keeping the obtained mixture at a temperature not higher than 120° C. for aging for a time in a range fro

Assignees

• Dalian Inst Chem & Physics Cas

Inventors

• Yuan Danhua
• Xing Jiacheng
• Xu Yunpeng
• Liu Zhongmin

Classifications

• C01P2006/16

  Pore diameter · CPC title

• C01P2002/74

  by peak-intensities or a ratio thereof only · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• B01J29/89

  Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium {(B01J29/005 takes precedence)} · CPC title

• C01B39/48

  using at least one organic template directing agent · CPC title