Process for the manufacture of paper and paperboard
US-2015345081-A1 · Dec 3, 2015 · US
US12378729B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12378729-B2 |
| Application number | US-202017609936-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 7, 2020 |
| Priority date | May 10, 2019 |
| Publication date | Aug 5, 2025 |
| Grant date | Aug 5, 2025 |
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The present invention provides a formulation for a fibrous non-woven facing material, wherein the formulation comprises a binder, a filler, and an extender. The extender has an median particle size, d 50 , which is equal to or less than 3.5 μm, and a non-spherical morphology. The filler has an median particle size, d 50 , which is equal to or less than 3.0 μm and wherein the filler has a d 10 equal to or less than 1.0 μm and a d 90 equal to or less than 6.0 μm. The formulation comprises less than 13 wt % titanium dioxide on a dry solids basis. Also provided is a fibrous non-woven facing material comprising the formulation, a process for preparing the fibrous non-woven facing material and a fibrous non-woven facing material obtained by said process.
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The invention claimed is: 1. A formulation for a fibrous non-woven facing material, wherein the formulation comprises: (i) a binder; (ii) a filler; and (iii) an extender; wherein a median particle size, d 50 , of the extender is equal to or less than 3.5 μm, and wherein the extender has a non-spherical morphology; wherein a median particle size, d 50 , of the filler is equal to or less than 3.0 μm and wherein the filler has a d 10 equal to or less than 1.0 μm and a d 90 equal to or less than 6.0 μm; wherein a weight ratio based on dry solids of the binder to a sum of the extender and the filler is from 0.05:1 to 7:2; wherein a weight ratio based on dry solids of the extender to the filler is from 0.05:1 to 18:1; wherein the formulation comprises less than 13 wt % titanium dioxide on a dry solids basis; wherein the formulation has a total solids content of from 30 to 85%; and wherein the formulation is free of a pigment having a refractive index of 2.5 or more. 2. The formulation according to claim 1 , wherein the extender has a non-spherical morphology consisting essentially of plate-shaped particles, rod-shaped particles, cubic or cuboid-shaped particles, pseudo-cubic shaped particles or cigar-shaped particles. 3. The formulation according to claim 1 , wherein the extender comprises kaolin, calcium carbonate, Huntite, magnesium carbonate, calcium-magnesium carbonate, or a mixture thereof. 4. The formulation according to claim 1 , wherein the filler comprises calcium carbonate or aluminium trihydrate. 5. The formulation according to claim 1 , wherein the filler has a refractive index of less than 2.5. 6. The formulation according to claim 1 , wherein the extender has a refractive index of less than 2.5. 7. The formulation according to claim 1 , wherein the median particle size, d 50 , of the extender is equal to or less than 3.5 μm and greater than 0.6 μm. 8. The formulation according to claim 1 , wherein the average particle size, d 90 , of the extender is between 4 and 20 μm. 9. The formulation according to claim 1 , wherein the median particle size, d 50 , of the filler is equal to or less than 0.8 μm. 10. The formulation according to claim 1 , wherein the filler has a d 50 equal to or less than 1.5 μm, a d 10 equal to or less than 0.5 μm and a d 90 equal to or less than 5 μm and wherein the filler comprises calcium carbonate, kaolin, magnesium carbonate, or a mixture thereof. 11. The formulation according to claim 1 , wherein the filler has a d 50 equal to or less than 2.5 μm, a d 10 equal to or less than 0.9 μm and a d 90 equal to or less than 6.0 μm, and wherein the filler comprises aluminium trihydrate. 12. The formulation according to claim 1 , wherein the formulation comprises less than 10 wt % of titanium dioxide, on a dry solids basis. 13. The formulation according to claim 1 , wherein the formulation is substantially free of titanium dioxide. 14. The formulation according to claim 1 , wherein the binder comprises from 5 wt % to 35 wt % of the dry solids of the formulation. 15. The formulation according to claim 1 , wherein the extender comprises from 5 wt % to 90 wt % of the dry solids of the formulation. 16. The formulation according to claim 1 , wherein the filler comprises from 5 wt % to 90 wt % of the dry solids of the formulation. 17. The formulation according to claim 1 , wherein a weight ratio based on dry solids of the binder to the extender is from 0.05:1 to 7:1.
Flexible structures being applied by the user, e.g. wallpaper (printed wallpapers B41M3/18; paperhanging B44C7/00; pregummed wallpaper C09J7/21) · CPC title
Colorants {; Pigments or opacifying agents} · CPC title
siliceous, e.g. clays · CPC title
Oxides, hydroxides or carbonates · CPC title
Macromolecular organic compounds · CPC title
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