Method for recovering lithium from brine

Patent metadata

Field	Value
Publication number	US-12378638-B2
Application number	US-202017773253-A
Country	US
Kind code	B2
Filing date	May 29, 2020
Priority date	Nov 1, 2019
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

The present invention relates to a method for recovering lithium from brine, and provides a method for recovering lithium from brine, the method comprising: (a) an impurity removal step of adding a carbonate supply source to brine including lithium, magnesium and calcium to precipitate and remove magnesium and calcium impurities; (b) a pH adjusting step of adding an acid to the brine from which the impurities have been removed, to adjust the pH of the brine; (c) a lithium-aluminum compound recovery step of adding an aluminum supply source to the pH-adjusted brine to recover a lithium-aluminum compound; (d) a lithium sulfate and aluminum oxide formation step of adding the lithium-aluminum compound to a sulfur supply source and calcining same to form lithium sulfate and aluminum oxide; and (e) a lithium sulfate solution yield step of selectively dissolving lithium sulfate from among the formed lithium sulfate and aluminum oxide to yield a lithium sulfate solution.

First claim

The invention claimed is:

1. A method for recovering lithium from brine, comprising:
(a) an impurity removal step of adding a carbonate supply source to brine including lithium, magnesium and calcium to precipitate and remove magnesium and calcium impurities;
(b) a pH adjusting step of adding an acid to the brine from which the impurities have been removed, to adjust the pH of the brine;
(c) a lithium-aluminum compound recovery step of adding an aluminum supply source to the pH-adjusted brine to recover a lithium-aluminum compound;
(d) a lithium sulfate and aluminum oxide formation step of adding the lithium-aluminum compound to a sulfur supply source and calcining same to form lithium sulfate and aluminum oxide; and
(e) a lithium sulfate solution yield step of selectively dissolving lithium sulfate from among the formed lithium sulfate and aluminum oxide to yield a lithium sulfate solution.

2. The method for recovering lithium from brine of claim 1 , wherein in the impurity removal step, the carbonate supply source is at least one water-soluble carbonate supply source selected from the group consisting of soda ash (Na 2 CO 3 ), sodium hydrogen carbonate (NaHCO 3 ), potassium carbonate (K 2 CO 3 ), potassium hydrogen carbonate (KHCO 3 ), and carbon-oxygen compounds (CO 2 , CO).

3. The method for recovering lithium from brine of claim 1 , wherein the impurity removal step is a step of adding the carbonate supply source to the brine and stirring for 0.1 to 36 hours to precipitate magnesium and calcium and then removing the magnesium and calcium.

4. The method for recovering lithium from brine of claim 1 , wherein the carbonate supply source is added to the brine so that a molar ratio of carbon:magnesium+calcium is 1:1 to 3:1.

5. The method for recovering lithium from brine of claim 1 , wherein in the pH adjusting step, the acid is at least one strong acid selected from the group consisting of hydrochloric acid, sulfuric acid and nitric acid.

6. The method for recovering lithium from brine of claim 1 , wherein the pH adjusting step is a step of adjusting the pH of the brine to pH 6 to 8 by adding the acid to the brine from which the impurities have been removed.

7. The method for recovering lithium from brine of claim 1 , wherein in the lithium-aluminum compound recovery step, the aluminum supply source includes one selected from the group consisting of sodium aluminate (NaAlO 2 ), aluminum metal (Al), aluminum hydroxide (Al(OH) 3 ), alumina hydrate (AlOOH), aluminum oxide (Al 2 O 3 ), sodium aluminate hydrate (NaAl(OH) 4 ), potassium aluminate (KAlO 2 ), potassium aluminate hydrate (KAl(OH) 4 ), sodium aluminum sulfate (NaAl(SO 4 ) 2 ), potassium aluminum sulfate (KAl(SO 4 ) 2 ), aluminum sulfate (Al 2 (SO 4 ) 3 ), aluminum sulfate ammonium ((NH 4 )Al(SO 4 ) 2 ), aluminum chloride (AlCl 3 ), aluminum nitrate (Al(NO 3 ) 3 )), aluminum perchlorate (Al(ClO 4 ) 3 ), aluminum chlorohydrate (Al 2 (OH) 5 Cl), and combinations thereof.

8. The method for recovering lithium from brine of claim 1 , wherein in the lithium-aluminum compound recovery step, the aluminum supply source is added to the pH-adjusted brine so that a molar ratio of aluminum:lithium is 1:1 to 5:1.

9. The method for recovering lithium from brine of claim 1 , wherein in the lithium-aluminum compound recovery step, the aluminum supply source is added to the pH-adjusted brine and stirred for 0.1 to 36 hours.

10. The method for recovering lithium from brine of claim 1 , wherein in the lithium sulfate and aluminum oxide formation step, the sulfur supply source is at least one solid or liquid sulfur supply source selected from the group consisting of sulfuric acid (H 2 SO 4 ), aluminum sulfate (Al 2 (SO 4 ) 3 ), magnesium sulfate (MgSO 4 ), sulfur (S), ammonium sulfate ((NH 4 ) 2 SO 4 ), hydrazine sulfate (N 2 H 6 SO 4 ), hydroxylammonium sulfate ((NH 3 OH) 2 SO 4 ) and nitrosyl sulfuric acid (NOHSO 4 ).

11. The method for recovering lithium from brine of claim 1 , wherein in the lithium sulfate and aluminum oxide formation step, the lithium-aluminum compound is added to the sulfur supply source so that a molar ratio of sulfur:lithium is 0.2:1 to 2:1.

12. The method for recovering lithium from brine of claim 1 , wherein in the lithium sulfate and aluminum oxide formation step, the lithium-aluminum compound is added to the sulfur supply source and calcined for 0.1 to 6 hours.

13. The method for recovering lithium from brine of claim 1 , wherein in the lithium sulfate and aluminum oxide formation step, the lithium-aluminum compound is added to the sulfur supply source and calcined at 400 to 800° C.

14. The method for recovering lithium from brine of claim 1 , wherein the lithium sulfate solution yield step is a step of adding the prepared lithium sulfate and aluminum oxide to water and selectively dissolving the lithium sulfate to yield a lithium sulfate solution.

15. The method for recovering lithium from brine of claim 14 , wherein in the lithium sulfate solution yield step, the prepared lithium sulfate and aluminum oxide is added to water and reacts for 0.1 to 5 hours.

Assignees

• Korea Inst Geoscience & Mineral Resources

Inventors

• Park In Su
• Hong Hye-Jin
• Suh Chang-Youl
• Park Sukjoon
• Lee Myunggyu

Classifications

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C22B3/22

  by physical processes, e.g. by filtration, by magnetic means {, or by thermal decomposition} (treatment or purification of solutions by liquid-liquid extraction C22B3/26) · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C02F1/5236

  using inorganic agents · CPC title