Systems and methods for improved raffinate injection

Patent metadata

Field	Value
Publication number	US-12378634-B2
Application number	US-202318480377-A
Country	US
Kind code	B2
Filing date	Oct 3, 2023
Priority date	Dec 29, 2014
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

The present disclosure provides a method comprising determining an ore map for a heap to identify a location of a recoverable metal-bearing material in the heap, wherein the metal-bearing material comprises iron and at least one other metal value, delivering a leaching solution from a leaching solution source to a leaching solution regulating system, wherein the leaching solution comprises an effective amount of citric acid and hydrogen peroxide, regulating at least one of a pressure, a mass flow rate, or a volumetric flow rate of the leaching solution to achieve a target operational condition, wherein the target operational condition is selected to optimize a set of operational parameters to maximize recovery of the at least one other metal value, delivering the leaching solution at the target operational condition from the leaching solution regulating system to the subsurface leaching distribution system, and delivering the leaching solution at the target operational condition from the subsurface leaching distribution system to the location of the recoverable metal-bearing material under a surface of the heap to leach and recover the at least one other metal value.

First claim

The invention claimed is:

1. A method for recovering a metal from chalcopyrite, comprising:
delivering a leaching solution from a leaching solution source to a leaching solution regulating system, wherein the leaching solution comprises a combination of an effective amount of citric acid and hydrogen peroxide, wherein the citric acid keeps iron in the leaching solution and allows the hydrogen peroxide to interact with the chalcopyrite;
regulating a pressure, a mass flow rate and a volumetric flow rate of the leaching solution to achieve a target operational condition, wherein the target operational condition is selected to optimize a set of operational parameters to allow options of preventing plugging of a subsurface leaching distribution system, minimizing locking up of the leaching solution in the heap and maximizing recovery of the recoverable metal in the chalcopyrite;
delivering the leaching solution at the target operational condition from the leaching solution regulating system to the subsurface leaching distribution system; and
delivering the leaching solution at the target operational condition from the subsurface leaching distribution system to a location of the recoverable metal in the chalcopyrite under a surface of the heap to leach and recover the recoverable metal from the chalcopyrite.

2. The method of claim 1 , wherein the leaching solution regulating system comprises a plurality of leaching solution regulating modules.

3. The method of claim 2 , wherein each leaching solution regulating module comprises a meter configured to detect the pressure, the mass flow rate and the volumetric flow rate of the leaching solution.

4. The method of claim 2 , wherein each leaching solution regulating module comprises a regulator configured to set the pressure, the mass flow rate and the volumetric flow rate of the leaching solution to the target operational condition.

5. The method of claim 1 , further comprising determining an ore map for a heap to identify a location of the recoverable metal in the chalcopyrite in the heap.

6. The method of claim 1 , wherein the set of operational parameters comprises at least one of minerology, chemistry, permeability or the recoverable metal.

7. The method of claim 1 , further comprising transmitting the pressure, the mass flow rate and the volumetric flow rate of the leaching solution between the leaching solution regulating system and the subsurface leaching distribution system.

8. The method of claim 1 , further comprising determining x,y,z coordinates for the location of the recoverable metal in the chalcopyrite in the heap.

9. The method of claim 1 , wherein the effective amount of citric acid is about 1 g/L to about 10 g/L and wherein the effective amount of hydrogen peroxide is about 0.5% to about 10% by weight.

10. The method of claim 1 , further comprising treating the location of the recoverable metal in the chalcopyrite to render the recoverable metal in the chalcopyrite susceptible to further leaching, wherein the treating comprises delivering a treatment solution to the location of the recoverable metal in the chalcopyrite, and wherein the treatment solution comprises the citric acid.

11. A system, comprising:
recoverable metal in chalcopyrite in a heap;
a leaching solution regulating system configured to detect and regulate a pressure, a mass flow rate and a volumetric flow rate of a leaching solution to a target operational condition, wherein the target operational condition is selected to optimize a set of operational parameters to allow options of preventing plugging of a subsurface leaching distribution system, minimizing locking up of the leaching solution in the heap and maximizing recovery of the recoverable metal in the chalcopyrite, and
wherein the leaching solution comprises a combination of an effective amount of citric acid and hydrogen peroxide, wherein the citric acid keeps iron in the leaching solution and allows the hydrogen peroxide to interact with the chalcopyrite; and
a subsurface leaching solution distribution system fluidly coupled to the leaching solution regulating system, the subsurface leaching solution distribution system comprising a subsurface injector configured to deliver the leaching solution to the recoverable metal in the chalcopyrite under the surface of the heap to leach and recover the recoverable metal in the chalcopyrite.

12. The system of claim 11 , wherein the set of operational parameters comprises at least one of at least one of minerology, chemistry, permeability, and the recoverable metal.

13. The system of claim 11 , wherein the effective amount of citric acid is about 1 g/L to about 10 g/L and wherein the effective amount of hydrogen peroxide is about 0.5% to about 10% by weight.

14. The system of claim 11 , wherein the leaching solution regulating system transmits the pressure, the mass flow rate and the volumetric flow rate of the leaching solution between the leaching solution regulating system and the subsurface leaching distribution system.

15. The system of claim 11 , wherein the heap also includes at least one of copper, nickel, zinc, silver, gold, germanium, lead, arsenic, antimony, chromium, molybdenum, rhenium, tungsten, iron, ruthenium, osmium, cobalt, rhodium, iridium, palladium, platinum, uranium, or rare earth metals.

16. The system of claim 11 , wherein the subsurface injector is further configured to deliver a treatment solution to the at least one location of the recoverable metal in the chalcopyrite to render the at least one location susceptible to further leaching, wherein the treatment solution comprises citric acid.

17. The system of claim 11 , wherein the subsurface injector is inserted into a bore formed in the heap, the bore filled with at least one material configured to provide stability and sealing for the subsurface injector.

18. The system of claim 11 , further comprising a plurality of sensors distributed along a length of the subsurface injector.

19. The system of claim 11 , further comprising an ore map determined by adding flow data, irrigation data and a remaining mineral prediction from a machine learning model to obtain information by section and by data for the heap.

20. The system of claim 19 , wherein the at least one location of the recoverable metal in the chalcopyrite in the heap is in x,y,z coordinates of the heap.

Assignees

• Freeport Minerals Corp

Inventors

• Lyons Sarah
• Robertson Joanna M
• Clayton Casey J
• Sanchez Richard Melecio
• Crossman Raquel
• Issoe Luciano Kiniti
• Ni Tianfang
• Klesov Oleksandr
• Gerdes Luke
• Alam Muneeb
• Zenner Chase
• Dean Jr John Warren

Classifications

• G01F15/006

  characterised by the use of a particular material, e.g. anti-corrosive material (G01F15/14 takes precedence) · CPC title

• G01F1/74

  Devices for measuring flow of a fluid or flow of a fluent solid material in suspension in another fluid · CPC title

• G01F15/066

  involving magnetic transmission devices · CPC title

• G01F15/005

  Valves (valves in general F16K) · CPC title

• G01F15/003

  using electromagnetic, electric or electronic means (G01F15/002, G01F15/02 take precedence) · CPC title