Single layer film and hydrophilic material comprising the same
US-9034464-B2 · May 19, 2015 · US
US12378436B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12378436-B2 |
| Application number | US-202117910089-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 12, 2021 |
| Priority date | Mar 13, 2020 |
| Publication date | Aug 5, 2025 |
| Grant date | Aug 5, 2025 |
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Provided is a means for imparting hydrophilicity to a surface of a sanitary facility by means other than hydrophilic particles. A sanitary facility having a hydrophilized organic surface, wherein the hydrophilized organic surface has at least an organic cationic group, and a zeta potential at pH=7 of the hydrophilized organic surface is more than −40 mV.
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The invention claimed is: 1. A sanitary facility having a hydrophilized organic surface, the hydrophilized organic surface having at least an organic cationic group, and a zeta potential more than −40 mV at pH=7. 2. The sanitary facility according to claim 1 , wherein the hydrophilized organic surface has a static contact angle of water of 40° or less. 3. The sanitary facility according to claim 1 , wherein the hydrophilized organic surface has a static contact angle of water of 40° or less after being brought into contact with an aqueous solution containing a cationic surfactant and then washed with water. 4. The sanitary facility according to claim 1 , wherein the organic cationic group of the hydrophilized organic surface is a group bonded to a carbon atom constituting the hydrophilized organic surface. 5. The sanitary facility according to claim 1 , wherein the hydrophilized organic surface has an organic cationic group and an organic anionic group, and each of the organic cationic group and the organic anionic group is a group bonded to a carbon atom constituting the hydrophilized organic surface. 6. The sanitary facility according to claim 1 , wherein the organic cationic group is a quaternary ammonium cationic group. 7. The sanitary facility according to claim 5 , wherein the organic cationic group is a quaternary ammonium cationic group, and the organic anionic group is at least one of a sulfonic acid group and an alkali metal salt of a sulfonic acid group. 8. The sanitary facility according to claim 1 , wherein a zeta potential Ei (mV) at pH=7 of the hydrophilized organic surface, and a zeta potential Ec (mV) at pH=7 after being brought into contact with an aqueous solution containing a cationic surfactant and then washed with water satisfy a relationship represented by a following formula: |Ec−Ei| <50 9. A hydrophilizing treatment agent set for manufacturing the sanitary facility according to claim 1 , the hydrophilizing treatment agent set comprising: a first treatment agent comprising a silane coupling agent having a radical reactive group; and a second treatment agent comprising: an anionic compound having a radical reactive group and an organic anionic group, and a cationic compound having a radical reactive group and an organic cationic group. 10. The hydrophilizing treatment agent set according to claim 9 , wherein the organic anionic group is at least one of a sulfonic acid group and an alkali metal salt of a sulfonic acid group, and the organic cationic group is a quaternary ammonium cationic group. 11. The hydrophilizing treatment agent set according to claim 9 , wherein the radical reactive group of the silane coupling agent, the radical reactive group of the anionic compound, and the radical reactive group of the cationic compound are each independently at least one selected from among an acrylamide group, an acryloyl group, a methacryloyl group, an allyl group, a vinyl group, a styryl group, and a mercapto group. 12. A method for manufacturing the sanitary facility according to claim 1 , the method comprising: a first treatment agent application step of applying a first treatment agent comprising a silane coupling agent having a radical reactive group to a surface of an article to be coated, and a second treatment agent application step of applying a second treatment agent comprising an anionic compound having a radical reactive group and an organic anionic group and a cationic compound having a radical reactive group and an organic cationic group to the surface to which the first treatment agent has been applied. 13. The method for manufacturing according to claim 12 , wherein the organic anionic group is at least one of a sulfonic acid group and an alkali metal salt of a sulfonic acid group, and the organic cationic group is a quaternary ammonium cationic group. 14. The method for manufacturing according to claim 12 , further comprising a radical reaction acceleration step of applying heat or an active energy ray after the second treatment agent application step.
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