Thermoplastic resin composition and molded article manufactured therefrom

Patent metadata

Field	Value
Publication number	US-12378396-B2
Application number	US-202118037160-A
Country	US
Kind code	B2
Filing date	Nov 18, 2021
Priority date	Dec 29, 2020
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

A thermoplastic resin composition of the present invention comprises: about 100 parts by weight of a rubber-modified aromatic vinyl-based copolymer resin containing a diene-based rubber-modified vinyl-based graft copolymer, an acrylic rubber-modified vinyl-based graft copolymer, a large-particle diameter rubber copolymer having an average particle diameter of about 5 to about 10 p m, and an aromatic vinyl-based copolymer resin; about 5 to about 25 parts by weight of a polyetheresteramide block copolymer; about 0.05 to about 1.5 parts by weight of a silver (Ag)-based compound; and about 1 to about 15 parts by weight of zinc oxide, wherein the gloss degree of a 3.2-mm thick sample is about 40 to about 70%, as measured at an angle of 600 according to ASTM D523. The thermoplastic resin composition is excellent in low gloss, antiviral properties, weather resistance, impact resistance, and so on.

First claim

The invention claimed is:

1. A thermoplastic resin composition comprising:
about 100 parts by weight of an rubber-modified aromatic vinyl copolymer resin comprising a diene-based rubber-modified vinyl graft copolymer, an acrylic rubber-modified vinyl graft copolymer, a large-diameter rubber copolymer having an average particle diameter of about 5 to about 10 μm, and an aromatic vinyl copolymer resin;
about 5 to about 25 parts by weight of a polyether-ester-amide block copolymer;
about 0.05 to about 1.5 parts by weight of a silver (Ag) compound; and
about 1 to about 15 parts by weight of zinc oxide,
the thermoplastic resin composition having a surface gloss of about 40 to about 70%, as measured on a 3.2 mm thick specimen at angle of 60° in accordance with ASTM D523.

2. The thermoplastic resin composition according to claim 1 , wherein the rubber-modified aromatic vinyl copolymer resin comprises about 5 to about 15 wt % of the diene-based rubber-modified vinyl graft copolymer, about 5 to about 20 wt % of the acrylic rubber-modified vinyl graft copolymer, about 1 to about 5 wt % of the large-diameter rubber copolymer, and about 55 to about 85 wt % of the aromatic vinyl copolymer resin.

3. The thermoplastic resin composition according to claim 1 , wherein the polyether-ester-amide block copolymer is a block copolymer of a reaction mixture comprising an aminocarboxylic acid, lactam, or diamine-dicarboxylic acid salt having 6 or more carbon atoms; a polyalkylene glycol; and dicarboxylic acid having 4 to 20 carbon atoms.

4. The thermoplastic resin composition according to claim 1 , wherein the silver compound comprises at least one of metallic silver, silver oxide, silver halide, and a silver ion-containing carrier.

5. The thermoplastic resin composition according to claim 1 , wherein a weight ratio of the polyether-ester-amide block copolymer to the sum of the silver compound and the zinc oxide (polyether-ester-amide block copolymer: silver compound+zinc oxide) ranges from about 1:0.1 to about 1:2.

6. The thermoplastic resin composition according to claim 1 , wherein a weight ratio of the silver compound to the zinc oxide (silver compound: zinc oxide) ranges from about 1:2 to about 1:100.

7. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a virus killing time of about 15 hours or less, as measured on a specimen having a size of 5 cm×5 cm over time at 25° C. and 50% RH in accordance with ISO 21702, in which the specimen is inoculated with porcine epidemic diarrhea virus or influenza A virus fluid.

8. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a color variation (AE) of about 2.5 or less, as calculated according to Equation 1 based on initial color values (L 0 *, a 0 *, b 0 *) measured on an injection-molded specimen having a size of 50 mm×90 mm×2.5 mm using a colorimeter and color values (L 1 *, a 1 *, b 1 *) of the specimen measured in the same manner as above after testing for 300 hours in accordance with ASTM D4459:
Color variation(Δ E )=√{square root over ((Δ L *) 2 +(Δ a *) 2 +(Δ b *) 2 )}  [Equation 1]

where ΔL* is a difference (L 1 *−L 0 *) between L* values before and after testing, Δa* is a difference (a 1 *−a 0 *) between a* values before and after testing, and Δb* is a difference (b 1 *−b 0 *) between b* values before and after testing.

9. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a notched Izod impact strength of about 12 to about 30 kgf·cm/cm, as measured on a ¼″ thick specimen in accordance with ASTM D256.

10. A molded article formed from the thermoplastic resin composition according to claim 1 .

11. The molded article according to claim 10 , wherein the molded article comprises a corrosion surface having a surface roughness of about 1 to about 50 μm on one surface thereof, as measured by a surface roughness meter.

Assignees

• Lotte Chemical Corp

Inventors

• Kim Gi Sun
• Chu Dong Hui
• Kwon Young Chul

Classifications

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2203/30

  used for thermoforming · CPC title

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title

• C08K2003/2296

  of zinc · CPC title