Deposition of flocculated tailings

Patent metadata

Field	Value
Publication number	US-12378146-B2
Application number	US-202218045743-A
Country	US
Kind code	B2
Filing date	Oct 11, 2022
Priority date	Oct 11, 2022
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

A process for dewatering tailings having a solids content in the range of about 10 wt % to about 70 wt % is provided comprising fully flocculating the tailings by adding an effective amount of a polymeric flocculant to the tailings and mixing the polymeric flocculant and tailings in a mixing device to form fully flocculated tailings having a minimized capillary suction time (CST) and discharging the fully flocculated tailings into a deposition area at a discharge velocity of substantially zero to minimize further mixing.

First claim

The invention claimed is:

1. A process for dewatering tailings, comprising:
providing a tailings feed having a solids content in the range of about 10 wt % to about 70 wt %;
adding an effective amount of a polymeric flocculant to the tailings feed and mixing the polymeric flocculant and tailings feed mixture in a mixing device sufficient to flocculate the tailings and minimize the capillary suction time (CST) of the flocculated tailings to form fully flocculated tailings;
transporting the fully flocculated tailings to a deposition area;
discharging the fully flocculated tailings into the deposition area at a discharge velocity of substantially zero to minimize further mixing;
naturally forming a sloped beached material deposit in the deposition area whereby water is released from the sloped beached material to form a released water pool that pools away from the sloped beached material deposit; and
continuously removing water from the released water pool to ensure that the sloped beached material at a discharge point is at a higher elevation than the released water pool to minimize any buoyant forces on the beached material deposit.

2. The process as claimed in claim 1 , whereby the tailings feed is first treated with an effective amount of a coagulant prior to the addition of the polymeric flocculant.

3. The process as claimed in claim 2 , wherein the coagulant is selected from the group consisting of gypsum, alum and lime and is added at an average dosage of about 900 to about 1500 grams per tonne.

4. The process as claimed in claim 2 , wherein the coagulant is flue-gas desulfurization (FGD) solids added at an average dosage of about 1000 to about 4000 grams per tonne.

5. The process as claimed in claim 1 , wherein the fully flocculated tailings has a CST of ≤75 seconds.

6. The process as claimed in claim 5 , wherein the fully flocculated tailings has a CST of <50 seconds.

7. The process as claimed in claim 5 , wherein the fully flocculated tailings has a CST of <25 seconds.

8. The process as claimed in claim 5 , wherein when the tailings feed has a solids content in the range of about 25 wt % to about 30 wt % solids, the CST of the fully flocculated tailings is about <25 seconds to about <50 seconds.

9. The process as claimed in claim 5 , wherein when the tailings feed has a solids content in the range of about 30 wt % to about 35 wt % solids, the CST of the fully flocculated tailings is about ≤50 seconds to about ≤75 seconds.

10. The process as claimed in claim 1 , wherein the fully flocculated tailings are discharged either sub-aerially or sub-aqueously.

11. The process as claimed in claim 10 , wherein the fully flocculated tailings are deposited sub-aerially at or near the surface of the sloped beached material deposit.

12. The process as claimed in claim 1 , wherein the fully flocculated tailings are transported to the deposition area by means of a horizontal pipe, said horizontal pipe having a discharge end comprising a 90 degree elbow, whereby the vertical portion of the 90 degree elbow, measured from the bottom of the elbow, is less than about two horizontal pipe inner diameters in length.

13. The process as claimed in claim 12 , wherein the horizontal pipe has an inner diameter of 20 to 24 inches.

14. The process as claimed in claim 1 , wherein the tailings feed is oil sand tailings.

15. The process as claimed in claim 14 , wherein the oil sand tailings are fluid fine tailings (FFT) or mature fine tailings (MFT).

16. The process as claimed in claim 15 , wherein the FFT or MFT are diluted to about 20 wt % to about 30 wt % solids content.

17. The process as claimed in claim 1 , wherein the tailings feed has a solids content in the range of about 15 wt % to about 45 wt %.

18. The process as claimed in claim 1 , wherein the polymeric flocculant is a water soluble polymer having a molecular weight between 1,000 kD and 50,000 kD, and an intrinsic viscosity of at least about 3 dl/g (measured in 1M NaCl at 25° C.).

19. The process as claimed in claim 1 , wherein the polymeric flocculant is a cationic, non-ionic, amphoteric, or anionic polymeric flocculant.

20. The process as claimed in claim 1 , wherein the polymeric flocculant has a charge density of 25-35% anionicity.

21. The process as claimed in claim 1 , wherein the dosage of polymeric flocculant added ranges from 10 grams to 10,000 grams per tonne of tailings feed.

22. The process as claimed in claim 21 , wherein dosage of polymeric flocculant ranges from about 400 to about 1,500 grams per tonne of tailings.

23. The process as claimed in claim 1 , wherein the polymeric flocculant is a polyacrylamide-sodium polyacrylate co-polymer with about 25-35% anionicity and a molecular weight of 1,000 kD to 50,000 kD.

24. The process as claimed in claim 1 , wherein the mixing device is a dynamic mixer.

Assignees

• Syncrude Canada Ltd

Inventors

• Bara Barry
• Mikula Randy

Classifications

• C10G1/04

  by extraction · CPC title

• F17D1/088

  for solids or suspensions of solids in liquids, e.g. slurries (F17D1/086 takes precedence) · CPC title

• C02F1/56

  Macromolecular compounds · CPC title

• C02F1/52

  by flocculation or precipitation of suspended impurities {(C02F1/463 takes precedence)} · CPC title

• F17D3/16

  for eliminating particles in suspension (from liquids by sedimentation B01D21/00; separation by filtration or otherwise B01D24/00 - B01D51/00; centrifugal apparatus B04) · CPC title