Three-dimensional printing with high density nanoparticles

Patent metadata

Field	Value
Publication number	US-12377604-B2
Application number	US-201917417075-A
Country	US
Kind code	B2
Filing date	Aug 12, 2019
Priority date	Aug 12, 2019
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

A multi-fluid kit for three-dimensional printing can include a fusing agent and a nanoparticle-containing agent. The fusing agent can include water and a radiation absorber, where the radiation absorber absorbs radiation energy and converts the radiation energy to heat. The nanoparticle-containing agent can include a liquid vehicle, high density nanoparticles, and a nanoparticle suspension compound selected from the group consisting of terpineol, ethyl cellulose, and a combination thereof.

First claim

What is claimed is:

1. A multi-fluid kit for three-dimensional printing, comprising:
a fusing agent comprising water and a radiation absorber, wherein the radiation absorber absorbs radiation energy and converts the radiation energy to heat; and
a nanoparticle-containing agent consisting of:
an organic solvent selected from the group consisting of i) n-butanol and ii) a combination of ethanol and cyclohexanone;
barium titanate nanoparticles; and
a nanoparticle suspension compound selected from the group consisting of terpineol, ethyl cellulose, and a combination thereof.

2. The multi-fluid kit of claim 1 , wherein the barium titanate nanoparticles have a density from about 4 g/cm 3 to about 12 g/cm 3 .

3. The multi-fluid kit of claim 1 , wherein the barium titanate nanoparticles are unfunctionalized.

4. The multi-fluid kit of claim 1 , wherein the barium titanate nanoparticles are present in an amount from about 1 wt % to about 20 wt % with respect to a total weight of the nanoparticle-containing agent.

5. The multi-fluid kit of claim 1 , wherein the nanoparticle suspension compound is present in an amount from about 2 wt % to about 20 wt % with respect to a total weight of the nanoparticle-containing agent.

6. The multi-fluid kit of claim 1 , wherein the nanoparticle-containing agent is free of a radiation absorber.

7. A three-dimensional printing kit, comprising:
a powder bed material comprising polymer particles;
a fusing agent to selectively apply to the powder bed material, the fusing agent comprising water and a radiation absorber, wherein the radiation absorber absorbs radiation energy and converts the radiation energy to heat; and
a nanoparticle-containing agent to selectively apply to the powder bed material, the nanoparticle-containing agent consisting of:
an organic solvent selected from the group consisting of i) n-butanol and ii) a combination of ethanol and cyclohexanone;
barium titanate nanoparticles; and
a nanoparticle suspension compound selected from the group consisting of terpineol, ethyl cellulose, and a combination thereof.

8. The three-dimensional printing kit of claim 7 , wherein the polymer particles are selected from the group consisting of polyamide 6 particles, polyamide 9 particles, polyamide 11 particles, polyamide 12 particles, polyamide 66 particles, polyamide 612 particles, thermoplastic polyamide particles, polyamide copolymer particles, polyethylene particles, thermoplastic polyurethane particles, polypropylene particles, polyester particles, polycarbonate particles, polyether ketone particles, polyacrylate particles, polystyrene particles, polyvinylidene fluoride particles, polyvinylidene fluoride copolymer particles, poly(vinylidene fluoride-trifluoroethylene) particles, poly(vinylidene fluoroide-trifluoroethylene-chlorotrifluoroethylene) particles, wax particles, and a combination thereof.

9. The three-dimensional printing kit of claim 7 , wherein the barium titanate nanoparticles have a density from about 4 g/cm 3 to about 12 g/cm 3 .

10. The three-dimensional printing kit of claim 7 , wherein the barium titanate nanoparticles are present in an amount from about 1 wt % to about 20 wt % with respect to the total weight of the nanoparticle-containing agent, and wherein the nanoparticle-containing agent includes the nanoparticle suspension compound in an amount from about 2 wt % to about 20 wt % with respect to a total weight of the nanoparticle-containing agent.

Assignees

• Peridot Print Llc

Inventors

• Ionescu Robert
• Stasiak James William
• Hinch Garry

Classifications

• B29C64/112

  using individual droplets, e.g. from jetting heads · CPC title

• B29C64/336

  of two or more materials · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• C01G23/006

  Alkaline earth titanates · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title