Cathode active material comprising lithium peroxide, cathode for a lithium-ion battery, lithium-ion battery, and use of coated lithium peroxide in a lithium-ion battery

Patent metadata

Field	Value
Publication number	US-12374683-B2
Application number	US-202017628977-A
Country	US
Kind code	B2
Filing date	Jul 17, 2020
Priority date	Jul 22, 2019
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

A cathode active material comprises lithium peroxide, wherein the lithium peroxide is provided at least in part with a coating, and wherein the coating comprises a non-metal inorganic compound. Furthermore, a cathode for a lithium-ion battery, and a lithium-ion battery, are specified, which comprise such a cathode active material. In addition, the use of coated lithium peroxide in the production of a lithium-ion battery is described.

First claim

What is claimed is:

1. An active cathode material comprising:
an active material constituent;
lithium peroxide in a form of solid particles; and
a coating covering the lithium peroxide,
wherein the coating comprises a nonmetallic inorganic compound, and
wherein the lithium peroxide is not homogeneously distributed in the active cathode material.

2. The active cathode material according to claim 1 , wherein the coating comprises a solid lithium ion conductor.

3. The active cathode material according to claim 2 , wherein the solid lithium ion conductor comprises a lithium garnet.

4. The active cathode material according to claim 3 , wherein the lithium garnet comprises: Li 7 La 3 Zr 2 O 12 ; Li 5 La 3 M 2 O 12 with M=Ta or Nb; or Li 6 ALa 2 M 2 O 12 with A=Ca, Sr, or Ba and M=Ta or Nb.

5. The active cathode material according to 1 , wherein the coating comprises one or more materials selected from the group consisting of: AlF 3 , Al 2 O 3 , TiO 2 , Nb 2 O 5 , WO 3 , SiO 2 , a silicate, a zirconate, a niobate, and a tantalate.

6. The active cathode material according to claim 1 , wherein the coating has a layer thickness of not more than 100 nm.

7. The active cathode material according to claim 6 , wherein the layer thickness is not more than 50 nm.

8. The active cathode material according to claim 1 , wherein the coating comprises a monolayer on the lithium peroxide.

9. The active cathode material according to claim 1 , wherein the coating is formed by sol-gel synthesis, laser beam evaporation (PLD) and/or atomic layer deposition (ALD).

10. The active cathode material of claim 1 , wherein the active material constituent is selected from the group consisting of LiCoO 2 , a lithium-nickel-cobalt-manganese compound (NCM or NMC), lithium nickel cobalt aluminum oxide (NCA), lithium iron phosphate, lithium manganese oxide spinel (LMS or LMO), and overlithiated layered oxide (OLO).

11. The active cathode material of claim 1 , wherein the lithium peroxide is disposed only in an outer layer or a top layer of the active cathode material.

12. The active cathode material of claim 1 , wherein a proportion of the lithium peroxide based on lithium content of the active cathode material is 1 to 60 mol %.

13. The active cathode material of claim 12 , wherein the proportion of the lithium peroxide based on the lithium content of the active cathode material is 3 to 40 mol %.

14. A cathode for a lithium ion battery comprising a carrier supporting the active cathode material according to claim 1 .

15. The cathode according to claim 14 , wherein the carrier comprises aluminum.

16. The cathode according to claim 14 , further comprising an electrode binder holding the active cathode material together.

17. The cathode according to claim 16 , wherein the electrode binder includes one or more polymers selected from the group consisting of: polyvinylidene fluoride (PVdF), polyvinylidene fluoride-hexafluoropropylene copolymer (PVdF-HFP), polyethylene oxide (PEO), polytetrafluoro-ethylene (PTFE), polyacrylate, styrene-butadiene rubber, polyvinylpyrrolidone (PVP), and carboxymethyl cellulose (CMC).

18. A lithium ion battery comprising:
the cathode according to claim 14 ; and
an anode comprising an anode active material separated from the cathode by a separator permeable to lithium ions.

19. A vehicle or portable device having the lithium ion battery according to claim 18 .

20. A method of forming the lithium ion battery according to claim 18 utilizing coated lithium peroxide.

21. The method according to claim 20 , wherein the coated lithium peroxide is broken down during the formation of the lithium ion battery.

22. An active cathode material comprising:
an active material constituent;
lithium peroxide in a form of solid particles; and
a coating covering the lithium peroxide,
wherein the coating comprises a nonmetallic inorganic compound,
wherein a proportion of the lithium peroxide based on lithium content of the active cathode material is in a range from 3 mol % to 40 mol %.

23. The active cathode material of claim 22 , wherein the active material constituent is selected from the group consisting of LiCoO 2 , a lithium-nickel-cobalt-manganese compound (NCM or NMC), lithium nickel cobalt aluminum oxide (NCA), lithium iron phosphate, lithium manganese oxide spinel (LMS or LMO), and overlithiated layered oxide (OLO).

24. The active cathode material of claim 22 , wherein the coating comprises a solid lithium ion conductor.

25. The active cathode material of claim 22 , wherein the lithium peroxide is homogeneously distributed in the active cathode material.

26. The active cathode material of claim 22 , wherein the lithium peroxide is not homogeneously distributed in the active cathode material.

Assignees

• Bayerische Motoren Werke Ag

Inventors

• Jung Roland
• Ogihara Hideki
• Woehrle Thomas

Classifications

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/623

  fluorinated polymers · CPC title