Tungsten oxide powder and electrochromic device using the same

US12372843B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-12372843-B2
Application numberUS-202318335335-A
CountryUS
Kind codeB2
Filing dateJun 15, 2023
Priority dateMar 17, 2021
Publication dateJul 29, 2025
Grant dateJul 29, 2025

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  1. Title

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  2. Abstract

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  5. First independent claim

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Abstract

Official abstract text for this publication.

According to one embodiment, provided is a tungsten oxide powder including primary particles having an average particle size of 100 nm or less. Each of the primary particles include a crystal phase and an amorphous phase coexisting in each primary particle.

First claim

Opening claim text (preview).

What is claimed is: 1. A tungsten oxide powder comprising secondary particles, the secondary particles comprising primary particles having an average particle size of 100 nm or less, each of the primary particles comprising a crystal phase and an amorphous phase coexisting in each primary particle, wherein in each of the primary particles, the amorphous phase is present at a range of 80% to 100% of a peripheral length of the crystal phase, and the primary particles in the secondary particles are bonded via the amorphous phases thereof. 2. The tungsten oxide powder according to claim 1 , wherein in each of the primary particles, the amorphous phase is present at 100% of a peripheral length of the crystal phase. 3. The tungsten oxide powder according to claim 1 , wherein a ratio B 1 /A 1 of an area B 1 of the amorphous phase to an area A 1 of the crystal phase in each of the primary particles is within a range of 0.2 to 0.8. 4. The tungsten oxide powder according to claim 1 , wherein the average particle size is within a range of 5 nm to 20 nm. 5. The tungsten oxide powder according to claim 1 , comprising a tungsten oxide powder containing 0.01 mol % to 50 mol % of any one or more selected from the group consisting of potassium, sodium, lithium, and magnesium. 6. The tungsten oxide powder according to claim 1 , wherein a maximum width of the amorphous phase in each of the primary particles is 0.1 nm to 5 nm. 7. The tungsten oxide powder according to claim 6 , wherein a ratio B 1 /A 1 of an area B 1 of the amorphous phase to an area A 1 of the crystal phase in each of the primary particles is within a range of 0.2 to 0.8. 8. The tungsten oxide powder according to claim 7 , wherein the average particle size is within a range of 5 nm to 20 nm. 9. The tungsten oxide powder according to claim 8 , wherein a ratio B 2 /A 2 of an area B 2 of the amorphous phase to an area A 2 of the crystal phase in the secondary particles is within a range of 0.2 to 0.8. 10. The tungsten oxide powder according to claim 8 , for use in an electrochromic device. 11. The tungsten oxide powder according to claim 1 , for use in an electrochromic device. 12. An electrochromic device comprising an electrochromic layer, the electrochromic layer comprising the tungsten oxide powder according to claim 1 . 13. The electrochromic device according to claim 12 , wherein the electrochromic layer has a volume resistance value of 1×10 5 Ω·cm or less.

Assignees

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Classifications

  • C09K9/00Primary

    Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy · CPC title

  • Optical properties, e.g. expressed in CIELAB-values · CPC title

  • Electric properties · CPC title

  • Nanometer sized, i.e. from 1-100 nanometer · CPC title

  • Agglomerated particles · CPC title

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Frequently asked questions

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What does patent US12372843B2 cover?
According to one embodiment, provided is a tungsten oxide powder including primary particles having an average particle size of 100 nm or less. Each of the primary particles include a crystal phase and an amorphous phase coexisting in each primary particle.
Who is the assignee on this patent?
Toshiba Kk, Toshiba Materials Co Ltd
What technology area does this patent fall under?
Primary CPC classification C09K9/00. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Jul 29 2025 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 6 related publications on this page (citations in our corpus or others sharing the same primary CPC).