Method for producing effect pigments

Patent metadata

Field	Value
Publication number	US-12371579-B2
Application number	US-202017631963-A
Country	US
Kind code	B2
Filing date	Jul 27, 2020
Priority date	Aug 2, 2019
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

A method for manufacturing platelet-shaped effect pigments includes the steps of a) providing a carrier substrate; b) applying aqueous washing ink droplets to the carrier substrate in first regions forming a first motif; c) applying a reflective coating to the carrier substrate such that a reflective coating is deposited on the carrier substrate in the form of a regular contiguous grid in second regions forming a second motif outside the first regions forming the first motif, wherein the first regions form the first motif and have the washing ink droplets form regular islands within the regular contiguous grid, and a reflective coating is deposited above the washing ink droplets in the first regions forming the first motif; and d) removing the washing ink droplets in the first regions together with the reflective coating present thereon and isolating the removed reflective coating in the form of platelet-shaped effect pigments.

First claim

The invention claimed is:

1. A method for manufacturing platelet-shaped effect pigments, comprising the following steps of:
a) providing a carrier substrate;
b) applying by printing technology in a controlled manner aqueous washing ink droplets to the carrier substrate in first regions forming a first motif;
c) applying a reflective coating to the carrier substrate, so that
in second regions forming a second motif outside the first regions forming a first motif, reflective coating is deposited on the carrier substrate in the form of a regular, contiguous grid,
wherein the first regions forming a first motif and having the washing ink droplets form regular islands within the regular, contiguous grid;
in the first regions forming a first motif, reflective coating is deposited above the washing ink droplets;
d) removing the washing ink droplets in the first regions together with the reflective coating present thereon and isolating the removed reflective coating in the form of platelet-shaped effect pigments,
wherein the remaining carrier substrate has a reflective coating in the form of a regular, contiguous grid only in the second regions forming a second motif.

2. The method according to claim 1 , wherein step b), applying by printing technology in a controlled manner aqueous washing ink droplets to the carrier substrate in first regions forming a first motif, takes place by means of a printing cylinder having a cell grid or a printing plate having a cell grid,
wherein the geometry of the platelet-shaped effect pigments produced in the method is determined by a suitable choice of the parameters of cell arrangement, areal cell geometry, cell depth and web width.

3. The method according to claim 2 , wherein the printing cylinder or the printing plate has a plurality of different cell grid regions,
wherein the cell grid regions differ from one another in at least one of the parameters of cell arrangement, areal cell geometry, cell depth and web width, so that the platelet-shaped effect pigments produced in the method have a plurality of platelet-shaped effect pigments with different geometries corresponding to the plurality of different cell grid regions.

4. The method according to claim 1 , wherein the aqueous washing ink droplets in step b) are based on an aqueous washing ink having a binding agent,
wherein the binding agent is a polymer chosen from the group composed of hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycol and casein.

5. The method according to claim 1 , wherein between the steps b) and c) a drying of the aqueous washing ink droplets applied to the carrier substrate is carried out.

6. The method according to claim 1 , wherein in step a) a foil is provided as the carrier substrate.

7. The method according to claim 1 , wherein the reflective coating applied in step c), and thus each of the platelet-shaped effect pigments isolated in step d), is a metallization chosen from the group composed of aluminum, stainless steel, nichrome, gold, silver, platinum and copper.

8. The method according to claim 1 , wherein the reflective coating applied in step c), and thus each of the platelet-shaped effect pigments isolated in step d), has a multilayer arrangement with the following layer sequence:
semi-transparent absorber layer/dielectric spacer layer/reflective layer; or
semi-transparent absorber layer/dielectric spacer layer/reflective layer/dielectric spacer layer/semitransparent absorber layer.

9. The method according to claim 8 , wherein the reflective coating applied in step c), and thus each of the platelet-shaped effect pigments isolated in step d), has the multilayer arrangement with the layer sequence semitransparent absorber layer/dielectric spacer layer/reflective layer, of Cr/SiO2/Al.

10. The method according to claim 8 , wherein the reflective coating applied in step c), and thus each of the platelet-shaped effect pigments isolated in step d), has the multilayer arrangement with the layer sequence semitransparent absorber layer/dielectric spacer layer/reflective layer/dielectric spacer layer/semitransparent absorber layer, namely a of Cr/SiO2/Al/SiO2/Cr or of Al/SiO2/Al/SiO2/Al,
wherein the central Al layer of the Al/SiO2/Al/SiO2/Al multilayer arrangement has a greater layer thickness than each of the two terminal Al layers.

Assignees

• Giesecke & Devrient Currency Technology Gmbh

Inventors

• Hoffmuller Winfried
• Sobol Michael
• Von Clausbruch Axel
• Rudisch Tobias

Classifications

• C09D11/14

  based on carbohydrates · CPC title

• C09D11/106

  containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09D5/004

  Reflecting paints; Signal paints · CPC title

• C09C1/64

  Aluminium · CPC title

• C09C1/627 Primary

  Copper · CPC title