Star-shaped ceramic body for use as catalyst

Patent metadata

Field	Value
Publication number	US-12371382-B2
Application number	US-202117797737-A
Country	US
Kind code	B2
Filing date	Feb 4, 2021
Priority date	Feb 7, 2020
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

Star-shaped ceramic body, wherein the cross-section of the body has six lobes, the ratio of the maximum radius r2 in the star to radius r1 of a circle connecting the intersections of the lobes being in the range from 1.0 to 3.61, preferably from 2.17 to 3.61, the ratio of the area F1 inside this circle to the summed area F2 of the lobes outside this circle being in the range of from 0.54 to 0.90, the ratio of the distance x2 between the two intersections I of one lobe with neighboring lobes and the radius r1 of the circle being in the range of from 0.67 to 1.11. The ceramic body is used as catalyst-support.

First claim

The invention claimed is:

1. Star-shaped ceramic body, wherein the cross-section of the body has six lobes, the ratio of the maximum radius r2 in the star to radius r1 of a circle connecting the intersections of the lobes being in the range from 2.17 to 3.61, the ratio of the area F1 inside this circle to the summed area F2 of the lobes outside this circle being in the range of from 0.54 to 0.90, the ratio of the distance x2 between the two intersections I of one lobe with neighboring lobes and the radius r1 of the circle being in the range of from 0.67 to 1.11.

2. The body according to claim 1 , wherein each lobe has straight outer walls with a rounded top, wherein the ratio of the length x1 from the intersection I of one lobe and neighboring lobes to the end of the straight outer wall to the distance x2 between two intersections I of one lobe and neighboring lobes is from 0.87 to 1.45.

3. The body according to claim 1 , wherein each lobe has straight outer walls with a rounded top, wherein the angle a between the straight outer wall and the straight line x2 between two intersections I of one lobe and neighboring lobes is from 70 to 140 degrees.

4. The body according to claim 1 , wherein each lobe has straight outer walls with a rounded top, wherein the ratio of the length x2 between two intersections I of one lobe and neighboring lobes to the length x3 between the ends of the straight outer walls is from 0.9 to 1.8.

5. The body according to claim 1 , wherein each lobe has straight outer walls with a rounded top and the ratio of the lobe area of the trapeze F3 confined by the straight outer walls of a lobe and the outer lobe area F4 outside this trapeze is from 2.5 to 14.35.

6. The body according to claim 1 , wherein the cross-section area is from 0.19 to 13.9 mm 2 .

7. The body according to claim 1 , wherein the maximum radius r2 is from 0.4 to 6 mm.

8. The body according to claim 1 , wherein the circle radius r1 is from 0.25 to 3.4 mm.

9. The body according to claim 1 , wherein the ceramic body is an alumina body.

10. The body according to claim 9 , having a pore volume in pores of diameter of over 1000 nm, as determined by mercury porosimetry, of at least 0.05 ml/g.

11. The body according to claim 9 , wherein the total pore volume, as determined by mercury porosimetry, is between 0.05 and 2.0 ml/g, and/or wherein the BET surface area is at least 10 m 2 /g, and/or wherein the attrition in accordance with ASTM D4058-87 is less than 5 wt %.

12. The body according to claim 1 , wherein the ceramic body is a silica body.

13. The body according to claim 1 , wherein the cross-section of the body has six axes of mirror symmetry.

14. The body according to claim 1 , having a length L of from 2 to 10 mm and/or having a length L to maximum diameter 2 r2 ratio of from 1 to 3.

15. A process for preparing a body according to claim 1 by forming a ceramic or ceramic precursor paste, optionally cutting the extrudate, drying and optionally calcining the formed paste.

16. A catalyst, comprising at least one catalytically active material supported on a body according to claim 1 .

17. The catalyst according to claim 16 , wherein the catalytically active material is selected from the group consisting of metals, metal oxides, metal sulfides and combinations thereof.

18. The use of a body according to claim 1 in a chemical reaction, preferably in oxidation reactions.

Assignees

• Basf Se

Inventors

• TERORDE Robert
• Bouwman Harry
• Dijkstra Willem
• Lipp Stefan
• Schwab Matthias Georg

Classifications

• B01J35/37

  Crush or impact strength · CPC title

• B01J35/38

  Abrasion or attrition resistance · CPC title

• B01J35/63

  Pore volume · CPC title

• B01J35/50

  characterised by their shape or configuration · CPC title

• C04B2235/94

  Products characterised by their shape · CPC title