Electrically conductive materials for heating and deicing airfoils

Patent metadata

Field	Value
Publication number	US-12371172-B2
Application number	US-202318393006-A
Country	US
Kind code	B2
Filing date	Dec 21, 2023
Priority date	Aug 30, 2016
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

Composite airfoils of the present disclosure comprise a root section including a first surface. The airfoils comprise an intermediate section having a first surface and coupled with the root section at a first end. The airfoils comprise a tip section having a first surface and coupled at a first end with a second end of the intermediate section. The airfoils comprise a conductive material layer adjacent at least one of the first surface of the root section, the first surface of the intermediate section, and the first surface of the tip section. The conductive material comprises a first polymer, a second polymer, and a sulfonic acid.

First claim

What is claimed is:

1. An aircraft component, comprising:
a conductive material disposed on a substrate, the conductive material comprising:
a carbon allotrope material; and
a mixture of a polymer and a sulfonic acid disposed on the carbon allotrope material;

wherein the conductive material has a thickness of about 1 μm to about 8 μm and a resistance of about 1e+4Ω/□ about 1e+8Ω/□.

2. The component of claim 1 , wherein the polymer is selected from the group consisting of a polyaniline, a poly(ethylenedioxythiophene), a poly(styrenesulfonate), and combination(s) thereof.

3. The component of claim 1 , wherein the sulfonic acid is selected from the group consisting of a naphthyl sulfonic acid, an anthraceneyl sulfonic acid, a pyrenyl sulfonic acid, and combination(s) thereof.

4. The component of claim 1 , wherein the carbon allotrope material is selected from the group consisting of a multi-walled carbon nanotube, a single-walled carbon nanotube, a graphene, a polycarbonate, a fullerene, or combination(s) thereof.

5. The component of claim 1 , wherein the mixture of the polymer and the sulfonic acid comprises a mixture of a polyaniline (PANI) and a dinonylnaphthalenesulfonic acid (DNNSA).

6. The component of claim 5 , wherein the PANI comprises about 10 to about 10,000 aniline units.

7. The component of claim 6 , wherein the mixture of the polymer and the sulfonic acid comprises a polyaniline dinonylnaphthalenesulfonic acid salt (PANI: DNNSA).

8. The component of claim 7 , wherein the molar ratio of sulfonic acid to aniline comprises about 1:1 to about 1:5.

9. The component of claim 7 , wherein the PANI: DNNSA comprises a weight average molecular weight (Mw) of about 31,250 g/mol to about 5,690 g/mol, as determined by size exclusion chromatography (SEC).

10. The component of claim 1 , wherein the mixture of the polymer and the sulfonic acid comprises about 20 wt % to about 80 wt % of the conductive material.

11. The component of claim 5 , wherein the PANI comprises about 0.1 wt % to about 25 wt % of the conductive material.

12. The component of claim 8 , wherein the PANI comprises about 0.1 wt % to about 25 wt % of the conductive material.

13. An aircraft component, comprising:
a conductive material disposed on a substrate, the conductive material comprising:
a carbon allotrope material; and
a mixture of a first polymer and a sulfonic acid disposed on the carbon allotrope material, the polymer being selected from the group consisting of a polyaniline, a poly(ethylenedioxythiophene), a poly(styrenesulfonate), and combination(s) thereof;

wherein the conductive material has a thickness of about 1 μm to about 8 μm and a resistance of about 1e+4Ω/□ to about 1e+8Ω/□.

14. The component of claim 13 , wherein the sulfonic acid is selected from the group consisting of a naphthyl sulfonic acid, an anthraceneyl sulfonic acid, a pyrenyl sulfonic acid, and combination(s) thereof.

15. The component of claim 13 , wherein the carbon allotrope material is selected from the group consisting of a multi-walled carbon nanotube, a single-walled carbon nanotube, a graphene, a polycarbonate, a fullerene, or combination(s) thereof.

16. The component of claim 13 , wherein the mixture of the first polymer and the sulfonic acid comprises a mixture of a polyaniline (PANI) and a dinonylnaphthalenesulfonic acid (DNNSA).

17. The component of claim 13 , wherein the carbon allotrope material is a metal coated carbon allotrope material.

18. The component of claim 13 , wherein the conductive material further comprises a second polymer.

19. The component of claim 18 , wherein the second polymer is selected from the group consisting of a polyurethane, a polyvinyl butyral, a polyacrylate, an epoxy, a glycidyl-Si—Zr-containing solgel, a polyester, a phenoxy resin, a polysulfide, and combination(s) thereof.

20. An aircraft component, comprising:
a conductive material disposed on a substrate, the conductive material comprising:
a carbon allotrope material; and
a mixture of a first polymer and a sulfonic acid disposed in the carbon allotrope material, the polymer being selected from the group consisting of a polyaniline, a poly(ethylenedioxythiophene), a poly(styrenesulfonate), and combination(s) thereof;

wherein the conductive material has a thickness of about 1 μm to about 8 μm and a resistance of about 1e+4Ω/□ about 1e+8Ω/□.

Assignees

• Boeing Co

Inventors

• Kinlen Patrick J
• Young Kenneth W

Classifications

• B64C27/46

  Blades · CPC title

• H05B2214/04

  Heating means manufactured by using nanotechnology · CPC title

• H05B2203/037

  Heaters with zones of different power density · CPC title

• H05B2214/02

  Heaters specially designed for de-icing or protection against icing · CPC title

• H05B3/145

  Carbon only, e.g. carbon black, graphite · CPC title