Methods of producing composite vehicle braking components including aluminum alloys

Patent metadata

Field	Value
Publication number	US-12366274-B2
Application number	US-202218090553-A
Country	US
Kind code	B2
Filing date	Dec 29, 2022
Priority date	Dec 29, 2022
Publication date	Jul 22, 2025
Grant date	Jul 22, 2025

Abstract

A method of manufacturing a brake rotor or brake drum having a composite structure includes casting an aluminum alloy to form a core of the brake rotor or brake drum, the core defining a core surface, depositing a high entropy alloy or yttrium stabilized zirconia on the core surface to form a thermal barrier layer on the core surface, and depositing an iron-aluminum-silicon-zirconium alloy on the thermal barrier layer to form a wear-resistant layer on the thermal barrier layer, the wear-resistant layer defining a friction surface of the brake rotor or brake drum.

First claim

What is claimed is:

1. A method of manufacturing a brake rotor or brake drum having a composite structure, the method comprising:
casting an aluminum alloy to form a core of the brake rotor or brake drum, the core defining a core surface;
depositing a high entropy alloy or yttrium stabilized zirconia on the core surface to form a thermal barrier layer on the core surface; and
depositing an iron-aluminum-silicon-zirconium alloy on the thermal barrier layer to form a wear-resistant layer on the thermal barrier layer, the wear-resistant layer defining a friction surface of the brake rotor or brake drum.

2. The method of claim 1 , wherein depositing the high entropy alloy or yttrium stabilized zirconia includes performing atom layer deposition to deposit the high entropy alloy or yttrium stabilized zirconia on the core surface.

3. The method of claim 2 , wherein:
the atom layer deposition includes a first half-cycle and a second half-cycle;
the first half-cycle includes a precursor dosing stage and a purge stage; and
the second half-cycle includes a co-reactant exposure stage and a purge stage.

4. The method of claim 3 , further comprising repeating the first half-cycle and the second half-cycle until a thickness of the thermal barrier layer is greater than or equal to a specified threshold thickness.

5. The method of claim 4 , wherein the specified threshold thickness is within a range of 35 nanometers to 61 nanometers.

6. The method of claim 4 , wherein the specified threshold thickness within a range of 61 nanometers to 138 nanometers.

7. The method of claim 2 , wherein a deposition temperature is less than or equal to 250 degrees Celsius.

8. The method of claim 3 , wherein the precursor dosing stage includes:
applying a tetrakis-(dimethylamido) zirconium (Zr(NMe 2 ) 4 ) precursor for zirconia;
applying a tris-(methylcyclopentadienyl) yttrium precursor for yttrium; and
applying water as an oxidant for each precursor.

9. The method of claim 1 , wherein depositing the high entropy alloy or yttrium stabilized zirconia includes depositing the high entropy alloy to form the thermal barrier layer on the core surface.

10. The method of claim 1 , wherein depositing the high entropy alloy or yttrium stabilized zirconia includes depositing the yttrium stabilized zirconia to form the thermal barrier layer on the core surface.

11. The method of claim 1 , wherein:
depositing the yttrium stabilized zirconia includes depositing the yttrium stabilized zirconia in one or more super cycle; and
each super cycle includes depositing seven cycles of zirconia and depositing one cycle of yttrium.

12. The method of claim 11 , wherein a growth rate of the thermal barrier layer is one nanometer per super cycle of deposition.

13. The method of claim 1 , wherein depositing the iron-aluminum-silicon-zirconium alloy includes depositing the iron-aluminum-silicon-zirconium alloy on the thermal barrier layer using a directed energy deposition process.

14. The method of claim 1 , wherein casting the aluminum alloy includes casting an aluminum-silicon alloy to form the core of the brake rotor or brake drum.

15. The method of claim 1 , wherein:
casting the aluminum alloy includes casting the aluminum alloy to form the core in a shape of a cylindrical body of a brake drum, the cylindrical body defining an inner surface and an outer surface; and
depositing the high entropy alloy or yttrium stabilized zirconia includes depositing the high entropy alloy or yttrium stabilized zirconia on the inner surface of the cylindrical body.

16. The method of claim 1 , wherein:
casting the aluminum alloy includes casting the aluminum alloy to form the core in a shape of an annular disc of a brake rotor, the annular disc defining at least one annular surface; and
depositing the high entropy alloy or yttrium stabilized zirconia includes depositing the high entropy alloy or yttrium stabilized zirconia on the at least one annular surface of the annular disc.

17. A method of manufacturing a composite structure for a vehicle braking component, the method comprising:
casting an aluminum alloy to form a vehicle braking component core, the vehicle braking component core defining a core surface;
depositing a thermally insulating material directly on the core surface of the vehicle braking component core to form a thermal barrier layer; and
depositing an iron-aluminum-silicon-zirconium alloy on the thermal barrier layer to form a wear-resistant layer on the thermal barrier layer, the wear-resistant layer defining a friction surface of the vehicle braking component.

18. The method of claim 17 , wherein depositing the thermally insulating material includes depositing the thermally insulating material using an atom layer deposition process.

19. A vehicle braking component having a composite structure, the vehicle braking component comprising:
a vehicle braking component core including an aluminum alloy, the vehicle braking component core defining a core surface;
a thermally insulating material on the core surface of the vehicle braking component core, the thermally insulating material defining a thermal barrier layer, a thickness of the thermally insulating material being in a range between 50 and 100 nanometers, and the thermally insulating material including a high entropy alloy or yttrium stabilized zirconia deposited on the core surface at least partially by a process other than atomic layer deposition (ALD); and
a wear-resistant layer on the thermal barrier layer, the wear-resistant layer comprising an iron-aluminum-silicon-zirconium alloy, and the wear-resistant layer defining a friction surface of the vehicle braking component.

20. The vehicle braking component of claim 19 , wherein the process other than atomic layer deposition is a physical vapor deposition process.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Liu Zhongyi
• Lee Heewook
• Sachdev Anil K
• Brown Tyson Whittier
• Kukreja Ratandeep Singh

Classifications

• C23C28/3455 Primary

  with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer · CPC title

• F16D2250/0046

  Coating · CPC title

• F16D2250/0007

  Casting · CPC title

• F16D2200/003

  Light metals, e.g. aluminium · CPC title

• F16D65/10

  Drums for externally- or internally-engaging brakes · CPC title