Non-aqueous crosslinkable composition with improved appearance

Patent metadata

Field	Value
Publication number	US-12365757-B2
Application number	US-201917285018-A
Country	US
Kind code	B2
Filing date	Nov 5, 2019
Priority date	Nov 6, 2018
Publication date	Jul 22, 2025
Grant date	Jul 22, 2025

Abstract

The present invention relates to a polyol component comprising a1) a polyol having a weight averaged molecular weight Mw of from 1,000 to 4,000 Dalton, a number averaged molecular weight Mn of from 600 to 2,500 Dalton, an OH value between 80 and 300 mg KOH/g of resin and a glass transition temperature Tg of from −10 to 90° C., and a2) between 0.1 and 10% by weight of polyurea product as rheological agent, as well as it use in a crosslinkable composition especially suitable for clear coat applications.

First claim

The invention claimed is:

1. A polyol component comprising
at least 35% by weight of a polyol a1) selected from polyester polyols, (meth)acrylic polyols, and mixtures of hybrids thereof, having a weight averaged molecular weight Mw of from 1,000 to lower than 3,500 Dalton, a number averaged molecular weight Mn of from 600 to lower than 2,000 Dalton, a polydispersity Mw/Mn of from 1.1 to 4, an hydroxyl value between 100 and 250 mg KOH/g of polyol a1), an acid value of less than 8 mg KOH/gram of polyol a1), and a glass transition temperature Tg of from −10 to 75° C., and
between 0.1 and 10% by weight of polyurea product a2) as rheological agent,
wherein the polyurea product a2) is the reaction product of an isocyanate component and an amine component, the polyurea product a2) being prepared in the presence of polyol a1) by:
mixing a mixture of the polyol a1) and the isocyanate component with the amine component,
mixing a mixture of the polyol a1) and the amine component with the isocyanate component, mixing a mixture of the polyol a1) and the amine component with a mixture of the polyol a1 and the isocyanate component, and/or
mixing the isocyanate component and the amine component with the polyol a1) simultaneously.

2. The polyol component according to claim 1 wherein polyol a1) has a Mw of 1,000 or more and lower than 3,000 Dalton and a glass transition temperature Tg higher than −5° C. but at most 75° C.

3. The polyol component according to claim 1 wherein polyol a1) is a (meth)acrylic polyol having a weight averaged molecular weight Mw of from 1,500 to lower than 3,500 Dalton and a number averaged molecular weight Mn of from 900 to lower than 2,000 Dalton.

4. The polyol component according to claim 1 wherein polyol a1) is a polyester polyol having a weight averaged molecular weight Mw of from 1,000 to 3,000 Dalton and a number averaged molecular weight Mn of 600 to lower than 1,500 Dalton.

5. The polyol component according to claim 1 wherein polyol a1) is a polyester polyol obtained the polymerization of:
from 5 to 58% by weight of one or more of at least difunctional carboxylic acids, C1-C4 alkyl esters thereof and/or anhydrides thereof,
from 42 to 95% by weight of at least difunctional hydroxy compounds, more specifically,
0 from 0 to 40% by weight of difunctional hydroxy compounds
0 from 0 to 49% by weight of trifunctional hydroxy compounds, and
0 from 0 to 10% by weight of tetrafunctional hydroxy compounds, and
from 0 to 50% by weight of linear or branched monofunctional carboxylic acid and/or hydroxy compound comprising 4 to 20 carbon atoms.

6. The polyol component according to claim 1 wherein the isocyanate component is a polyisocyanate or its isocyanurate, biuret or uretdione derivative and the amine component is at least one mono-amine.

7. The polyol component according to claim 6 wherein the polyisocyanate is selected from the group of hexamethylene-1,6-diisocyanate (HMDI), its isocyanurate trimer or its biuret, trans-cyclohexylene-1,4-diisocyanate, para- and meta-xylylene diisocyanate, and toluene diisocyanate and/or wherein the mono-amine is a primary amine selected from n-aliphatic amines; cyclohexylamine; benzylamine; 3-methoxypropylamine; S-alpha-methylbenzylamine and 2-phenethylamine, as well as mixtures thereof.

8. The polyol component according to claim 1 , wherein the amount of polyol a1) in the polyol component is from 50 to 90% by weight, and wherein the polyol component further comprises less than 40% by weight of a polyol R different from polyol a1) relative to the total weight of polyol a1), polyol R) and polyurea compound a2).

9. A crosslinkable composition comprising
a) at least one polyol component a) according to claim 1 ,
b) optionally at least one polyol b) which can be same or different from polyol a1), said polyol b) having at least 2 free —OH groups
c) a crosslinker reactable with polyols a1) and/or b), and
d) optionally a catalyst for catalysing the reaction between —OH groups of said polyol a1) and/or
b) and said crosslinker c).

10. The crosslinkable composition according to claim 9 wherein the polyol b) is present and has a Mw of from 700 to 10,000 Dalton and a glass transition temperature Tg between −80 and 90° C.

11. The crosslinkable composition according to claim 9 wherein polyol b) is selected from polyester polyols and (meth)acrylic polyols, polyacrylate polyester polyol hybrids and mixtures thereof.

12. The crosslinkable composition according to claim 9 wherein crosslinker c) is selected from amino crosslinker resins, isocyanates or blocked isocyanates or mixtures of amino crosslinker resins with (blocked) isocyanates.

13. The crosslinkable composition according to claim 9 having a solid content is at least 50% by weight, at application viscosity.

14. The crosslinkable composition according to claim 9 comprising
from 0.1 to 10% of weight of polyurea product a2),
from 10 to 89% of weight of polyol a1) plus polyol b),
from 10 to 89% of weight of crosslinker c),
optionally, from 0.001 to 10% of weight of catalyst d)

based on the total amount of polyol a1), polyurea product a2), polyol b), crosslinker c), and, if present, catalyst d).

15. A method of providing a coating comprising the steps of applying a crosslinkable composition according to claim 9 to at least part of a transportation vehicle and curing the applied coating composition at a temperature in the range of 5 to 180° C.

16. The method according to claim 15 comprising the steps of applying a first aqueous colored layer on a metal optionally comprising an electrodeposition layer, followed by flash-off at a temperature lower than 90° C., then application of an aqueous basecoat layer, another flash-off at a temperature lower than 90° C. and there after the application of a clear coat layer comprising the crosslinkable composition, followed by one high bake curing step for all layers simultaneously at a temperature in the range of 80 to 180° C.

Assignees

• Allnex Netherlands Bv

Inventors

• De Wolf Elwin
• Goedegebuure Marinus

Classifications

• C09D175/06

  from polyesters · CPC title

• C08G18/73 Primary

  acyclic · CPC title

• C08G18/2865

  Compounds having only one primary or secondary amino group; Ammonia · CPC title

• B05D7/574

  at least some layers being let to dry at least partially before applying the next layer (B05D7/577 takes precedence) · CPC title

• B05D7/572

  all layers being cured or baked together · CPC title