Synergistic green sorption media for cyanobacterial toxin remediation

Patent metadata

Field	Value
Publication number	US-12365604-B2
Application number	US-202418776678-A
Country	US
Kind code	B2
Filing date	Jul 18, 2024
Priority date	Jul 19, 2023
Publication date	Jul 22, 2025
Grant date	Jul 22, 2025

Abstract

Described herein relates to a low-cost, synergistic, and/or green sorption media and methods thereof capable of removing MC-LR in-situ over different landscapes. The synergistic composition may include a mixture of a plurality of sand particles, a plurality of biochar particles, a plurality of clay particles, a plurality of zero-valent iron (hereinafter “ZVI”) iron molecules, and/or a plurality of perlite particles. In certain embodiments, the plurality of clay particles, plurality of ZVI molecules, and/or plurality of perlite particles may have an approximately equal volume percentage, with the volume percentage being less than or equal to a volume percentage of the plurality of biochar particles. Furthermore, the synergistic composition may be homogenously mixed and/or included in a media chamber of a filtration system.

First claim

What is claimed is:

1. A composition for treating water having at least one cyanobacterial toxin, the composition comprising:
a plurality of sand particles comprising about 80 vol %;
a plurality of biochar particles comprising about 5 vol %;
a plurality of perlite particles;
a plurality of zero-valent iron (hereinafter “ZVI”) particles;
wherein the volume percentage of the plurality of ZVI particles is less than or equal to a volume percentage of the biochar particles;
wherein the plurality of biochar particles and the plurality of ZVI particles are chemically bonded, thereby forming a ZVI-biochar honeycomb structure; and
wherein the ZVI-biochar honeycomb structure comprises a plurality of adsorption sites, such that at least one of the plurality of adsorption sites for the at least one cyanobacterial toxin is endothermic, exothermic, or both.

2. The composition of claim 1 , further comprising a plurality of clay particles comprising about 5 vol %.

3. The composition of claim 2 , wherein the volume percentage of the plurality of perlite particles, the plurality of ZVI molecules, or both is about 5 vol %.

4. The composition of claim 3 , wherein the plurality of biochar particles are at most about 25 vol %.

5. The composition of claim 4 , wherein the ZVI-biochar honeycomb structure interacts with at least one of the plurality of clay particles, thereby forming at least one ZVI-biochar-clay structure.

6. The composition of claim 5 , wherein the at least one ZVI-biochar-clay structure of the synergistic composition comprises a point of zero charge (hereinafter “PZC”) of about 9.6 to about 10.6.

7. The composition of claim 6 , wherein the at least one ZVI-biochar-clay structure of the synergistic composition comprises a saturated hydraulic conductivity of 0.6(10 −4 )m*sec −1 to about 2.8(10 −4 )m*sec −1 .

8. The composition of claim 7 , wherein the at least one ZVI-biochar-clay structure of the synergistic composition is porous.

9. The composition of claim 8 , wherein the at least one ZVI-biochar-clay structure of the synergistic composition is homogeneous.

10. The composition of claim 9 , wherein the ZVI-biochar-clay structure further comprises a Brunauer-Emmett-Teller (hereinafter “BET”) surface area of about 1.35 m 2 /g to about 3.08 m 2 /g.

11. The composition of claim 10 , wherein the ZVI-biochar-clay structure further comprises a density of about 2.59 g*cm 3 to about 2.67 g*cm 3 .

12. The composition of claim 11 , wherein the ZVI-biochar-clay structure further comprises the adsorption capacity of about 1.19 μg/g.

13. A filtration system for treating water containing cyanobacterial toxins, the filtration system comprising:
a media chamber including a homogeneously mixed composition, the homogenously mixed composition comprising:
a plurality of sand particles comprising about 80 vol %;
a plurality of biochar particles comprising about 5 vol %;
a plurality of perlite particles;
a plurality of zero-valent iron (hereinafter “ZVI”) particles;
wherein the volume percentage of the plurality of ZVI particles is less than or equal to a volume percentage of the biochar particles;
wherein the plurality of biochar particles and the plurality of ZVI particles are chemically bonded, thereby forming a ZVI-biochar honeycomb structure; and
wherein the ZVI-biochar honeycomb structure comprises a plurality of adsorption sites, such that at least one of the plurality of adsorption sites for the at least one cyanobacterial toxin is endothermic, exothermic, or both.

14. The filtration system of claim 13 , further comprising a plurality of clay particles comprising about 5 vol %.

15. The filtration system of claim 14 , wherein the volume percentage of the plurality of perlite particles, the plurality of ZVI molecules, or both is about 5 vol %.

16. The filtration system of claim 15 , wherein the plurality of biochar particles are at most about 25 vol %.

17. A method of optimizing cyanobacterial toxin removal from a water supply, the method comprising:
incorporating a homogenously mixed synergistic composition into the water supply, the homogenously mixed composition comprising:
a plurality of sand particles comprising about 80 vol %;
a plurality of biochar particles comprising about 5 vol %;
a plurality of perlite particles;
a plurality of zero-valent iron (hereinafter “ZVI”) particles;
wherein the volume percentage of the plurality of ZVI particles is less than or equal to a volume percentage of the biochar particles;
wherein the plurality of biochar particles and the plurality of ZVI particles are chemically bonded, thereby forming a ZVI-biochar honeycomb structure; and
wherein the ZVI-biochar honeycomb structure comprises a plurality of adsorption sites, such that at least one of the plurality of adsorption sites for the at least one cyanobacterial toxin is endothermic, exothermic, or both; and

wherein the incorporation of the homogenously mixed synergistic composition into the water supply thereof optimizes the cyanobacterial toxin removal within the water supply.

18. The method of claim 17 , wherein the homogenously mixed synergistic composition further comprises a plurality of clay particles comprising about 5 vol %.

19. The method of claim 18 , wherein the volume percentage of the plurality of perlite particles, the plurality of ZVI molecules, or both is about 5 vol %.

20. The method of claim 19 , wherein the plurality of biochar particles are at most about 25 vol %.

Assignees

• Univ Central Florida Res Found Inc

Inventors

• Chang Ni-Bin

Classifications

• B01D39/2027

  Metallic material · CPC title

• B01D39/2068

  Other inorganic materials, e.g. ceramics · CPC title

• B01D39/2055

  Carbonaceous material (solid sorbent compositions comprising free carbon B01J20/20) · CPC title

• B01J20/28059

  being less than 100 m2/g · CPC title

• C02F1/283

  using coal, charred products, or inorganic mixtures containing them · CPC title