Hydrogen production with membrane reactor

Patent metadata

Field	Value
Publication number	US-12365587-B2
Application number	US-202418648816-A
Country	US
Kind code	B2
Filing date	Apr 29, 2024
Priority date	Jun 18, 2020
Publication date	Jul 22, 2025
Grant date	Jul 22, 2025

Abstract

A system and method for producing hydrogen, including providing hydrocarbon and steam into a vessel to a region external to a tubular membrane in the vessel. The method includes steam reforming the hydrocarbon in the vessel via reforming catalyst to generate hydrogen and carbon dioxide. The method includes diffusing the hydrogen through the tubular membrane into a bore of the tubular membrane, wherein the tubular membrane is hydrogen selective.

First claim

What is claimed is:

1. A method of producing hydrogen, comprising:
providing hydrocarbon and steam into a vessel to a region external to a hydrogen selective tubular membrane in the vessel, the hydrogen selective tubular membrane comprising multiple hydrogen selective tubular membrane units in the vessel, and each hydrogen selective tubular membrane unit is hydrogen selective and comprises a respective bore that is the permeate side of the respective hydrogen selective tubular membrane unit, with each pair of hydrogen selective tubular membrane units sharing a longitudinal axis that is aligned with a central axis of the vessel, with each hydrogen selective tubular membrane unit of a pair of hydrogen selective tubular membrane units comprising a capped end and positioned such that the capped ends of the hydrogen selective tubular membrane units of the pair of hydrogen selective tubular membrane units are adjacent;
steam reforming the hydrocarbon in the vessel via reforming catalyst to generate hydrogen and carbon dioxide;
diffusing the hydrogen through the hydrogen selective tubular membrane into a bore of the hydrogen selective tubular membrane; and
providing heat for the steam reforming with electrical resistive heaters disposed in the vessel, the reforming catalyst disposed on the electrical resistive heaters and on an inside surface of a wall of the vessel.

2. The method of claim 1 , comprising discharging the hydrogen from the bore as permeate to a conduit for collection of the hydrogen.

3. The method of claim 2 , comprising discharging the carbon dioxide as retentate from the vessel.

4. The method of claim 3 , wherein the permeate comprises at least 90 mole-percent hydrogen on a dry basis, and wherein the retentate comprises at least 90 mole-percent carbon dioxide on a dry basis.

5. The method of claim 1 , wherein providing heat comprises heating the hydrocarbon via conduction and convection of heat from the electrical resistive heaters.

6. The method of claim 1 , wherein the electrical resistive heaters comprise electrical cartridge heaters.

7. The method of claim 1 , wherein the region external to the hydrogen selective tubular membrane is a reaction space in the vessel and is a retentate side of the hydrogen selective tubular membrane, the bore of the hydrogen selective tubular membrane is a permeate side of the hydrogen selective tubular membrane, and the reforming catalyst is not in contact with the hydrogen selective tubular membrane.

8. The method of claim 1 , comprising:
providing a sweep gas to the bore of the hydrogen selective tubular membrane;
displacing the hydrogen from the bore with the sweep gas; and
increasing driving force for hydrogen permeation through the hydrogen selective tubular membrane to the bore from the region external to the hydrogen selective tubular membrane via displacing the hydrogen from the bore with the sweep gas.

9. The method of claim 8 , wherein the sweep gas in displacing the hydrogen flows in a countercurrent direction relative to flow of the hydrocarbon and the steam into the vessel.

10. The method of claim 1 , comprising providing heat for the steam reforming via an electrical heater disposed on an outside surface of the wall of the vessel.

11. The method of claim 1 , comprising heating, via a heat source external to the vessel, the wall of the vessel and the reforming catalyst disposed on the inside surface of the wall of the vessel.

12. The method of claim 11 , wherein the heat source comprises an electrical heater disposed on an outside surface of the wall of the vessel.

13. The method of claim 2 , wherein providing heat comprises heating, via the electrical resistive heaters, the reforming catalyst disposed on the electrical resistive heaters.

14. The method of claim 6 , wherein providing heat comprises, heating via the electrical cartridge heaters the reforming catalyst disposed on the electrical cartridge heaters.

15. The method of claim 7 , wherein the hydrocarbon comprises natural gas, methane, liquid petroleum gas (LPG), or a mixture of C1 to C10 hydrocarbons, or any combinations thereof.

16. The method of claim 9 , wherein the sweep gas comprises steam or nitrogen.

17. The method of claim 1 , wherein the vessel comprises a cylindrical pressure vessel.

18. The method of claim 4 , comprising:
providing a sweep gas to the bore of the hydrogen selective tubular membrane;
displacing the hydrogen from the bore with the sweep gas; and
increasing driving force for hydrogen permeation through the hydrogen selective tubular membrane to the bore from the region external to the hydrogen selective tubular membrane via displacing the hydrogen from the bore with the sweep gas.

19. The method of claim 4 , wherein the region external to the hydrogen selective tubular membrane is a reaction space in the vessel and is a retentate side of the hydrogen selective tubular membrane, the bore of the hydrogen selective tubular membrane is a permeate side of the hydrogen selective tubular membrane, the reforming catalyst is not in contact with the hydrogen selective tubular membrane, and the hydrocarbon comprises natural gas, methane, liquid petroleum gas (LPG), or a mixture of C1 to C10 hydrocarbons, or any combinations thereof.

20. The method of claim 2 , comprising heating, via a heat source external to the vessel, the wall of the vessel and the reforming catalyst disposed on the inside surface of the wall of the vessel, the heat source comprising an electrical heater disposed on an outside surface of the wall of the vessel.

Assignees

• Saudi Arabian Oil Co

Inventors

• Paglieri Stephen N
• Harale Aadesh

Classifications

• B01D71/02231

  Palladium · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/085

  by electric heating · CPC title

• C01B2203/041

  In-situ membrane purification during hydrogen production · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title