Carbon dioxide fixation method and carbon dioxide fixation system

Patent metadata

Field	Value
Publication number	US-12364948-B2
Application number	US-202117469711-A
Country	US
Kind code	B2
Filing date	Sep 8, 2021
Priority date	Mar 19, 2021
Publication date	Jul 22, 2025
Grant date	Jul 22, 2025

Abstract

A carbon dioxide fixation method includes: immersing a magnesium alloy in an aqueous solvent; blowing carbon dioxide-containing gas into the aqueous solvent; and electrically energizing and thereby subjecting the aqueous solvent to electrolysis treatment so as to produce precipitates containing magnesium carbonate. The method can be carried out in a system having: a treating bath for storing a magnesium alloy and an aqueous solvent to treat a magnesium alloy in which the magnesium alloy is treated, a gas-introducing unit for blowing carbon dioxide-containing gas into the aqueous solvent, a pair of electrodes for applying voltage to the aqueous solvent so as to conduct electrolysis treatment, and a power control unit connected to the electrodes.

First claim

The invention claimed is:

1. A carbon dioxide fixation method comprising:
immersing a single pair of an anode consisting of a magnesium alloy and a cathode in a single aqueous solvent which is stored in a single treating bath:
performing an acid-addition in which an acid is added to said aqueous solvent to obtain a pH value of 2 or less;
performing a gas-blowing in which carbon dioxide-containing gas is blown into said aqueous solvent having a pH of 2 or less to obtain a pH value of 4 to 6; and
performing an electrolysis treatment in which said aqueous solvent is electrically energized using said single pair of said anode and said cathode and thereby subjected to electrolysis treatment so as to elute magnesium ions from said magnesium alloy and to produce precipitates containing magnesium carbonate,
wherein conditions of said electrolysis treatment are controlled so that a pH value of said aqueous solvent is maintained between 7 and 10 while said electrolysis treatment is conducted, and the blowing of said carbon dioxide-containing gas is stopped before said electrolysis treatment.

2. The method according to claim 1 , further comprising adding electrolytes into said aqueous solvent prior to said electrolysis treatment.

3. The method according to claim 1 , wherein a carbon electrode is used as said cathode in said electrolysis treatment.

4. The method according to claim 1 , wherein the electric power used in said electrolysis treatment is renewable energy produced by photovoltaic power or wind power.

5. The method according to claim 1 , wherein said electrolysis treatment further generates hydrogen, and
still further comprising a hydrogen recovery in which the hydrogen is recovered.

6. The method according to claim 1 , further comprising a precipitate recovery in which said precipitates are recovered.

7. The method according to claim 1 , wherein said magnesium alloy is scrap or waste material.

8. The method according to claim 1 , wherein said carbon dioxide-containing gas is exhaust gas released from a power plant.

9. A method for producing precipitates containing magnesium carbonate, comprising:
immersing a single pair of an anode consisting of a magnesium alloy and a cathode in a single aqueous solvent which is stored in a single treating bath;
adding an acid to said aqueous solvent to obtain a pH value of 2 or less;
blowing carbon dioxide-containing gas into the aqueous solvent to obtain a pH value of from 4 to 6; and
electrically energizing and thereby subjecting the aqueous solvent to electrolysis treatment using said single pair of an anode and a cathode so as to elute magnesium ions from said magnesium alloy and to produce precipitates containing magnesium carbonate,
wherein conditions of said electrolysis treatment are controlled so that a pH value of said aqueous solvent is maintained between 7 and 10 while said treatment is conducted, and the blowing of said carbon dioxide-containing gas is stopped before said electrolysis treatment.

10. A carbon dioxide fixation method comprising:
preparing an aqueous solvent having a pH value of 2 or less which is stored in a single treating bath;
immersing a single pair of an anode consisting of a magnesium alloy and a cathode in said aqueous solvent;
performing a gas-blowing in which carbon dioxide-containing gas is blown into said aqueous solvent to obtain a pH value of from 4 to 6; and
performing an electrolysis treatment in which said aqueous solvent is electrically energized and thereby subjected to electrolysis treatment using said single pair of an anode and a cathode so as to elute magnesium ions from said magnesium alloy and to produce precipitates containing magnesium carbonate,
wherein conditions of said electrolysis treatment are controlled so that a pH value of said aqueous solvent is maintained between 7 and 10 while said treatment is conducted, and the blowing of said carbon dioxide-containing gas is stopped before said electrolysis treatment.

11. A method for producing precipitates containing magnesium carbonate, comprising:
preparing an aqueous solvent having a pH value of 2 or less which is stored in a single treating bath;
immersing a single pair of an anode consisting of a magnesium alloy and a cathode in said aqueous solvent;
blowing carbon dioxide-containing gas into the aqueous solvent to obtain a pH of from 4 to 6; and
electrically energizing and thereby subjecting the aqueous solvent to electrolysis treatment using said single pair of an anode and a cathode so as to elute magnesium ions from said magnesium alloy and to produce precipitates containing magnesium carbonate,
wherein conditions of said electrolysis treatment are controlled so that a pH value of said aqueous solvent is maintained between 7 and 10 while said treatment is conducted and the blowing of said carbon dioxide-containing gas is stopped before said electrolysis treatment.

Assignees

• Toshiba Kk

Inventors

• Sano Kenji
• Saito Hitomi
• Miyamoto Hirohisa
• Imada Toshihiro

Classifications

• C01F5/24

  Magnesium carbonates · CPC title

• B01D2252/103

  Water · CPC title

• C25B15/083

  Separating products · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title

• C25B15/031

  pH · CPC title