System for producing magnesium hydroxide

Patent metadata

Field	Value
Publication number	US-12364933-B2
Application number	US-202017790778-A
Country	US
Kind code	B2
Filing date	Dec 16, 2020
Priority date	Jan 8, 2020
Publication date	Jul 22, 2025
Grant date	Jul 22, 2025

Abstract

Disclosed is a system for producing magnesium hydroxide including: a generation unit; and a recovery unit connected to the generation unit, wherein the generation unit has a reaction tank in which a calcium hydroxide slurry is added to water to be treated containing magnesium ions to crystallize magnesium hydroxide and to obtain a reaction slurry containing particles of magnesium hydroxide, and a sedimentation tank in which the reaction slurry is reserved to sediment the particles and to separate the reaction slurry into a separation slurry containing the particles at a high concentration and a separation liquid containing the particles at a low concentration, and wherein, in the recovery unit, an alkaline aqueous solution is added to the separation liquid to crystallize magnesium hydroxide and to obtain the reaction slurry and then the reaction slurry is reserved to sediment the particles and to recover the sedimented particles.

First claim

The invention claimed is:

1. A system for producing magnesium hydroxide comprising:
a generation unit; and
a recovery unit connected to the generation unit,
wherein the generation unit has
a reaction tank in which a calcium hydroxide slurry is added to water to be treated containing magnesium ions to crystallize magnesium hydroxide and to obtain a reaction slurry containing particles of magnesium hydroxide, and
a sedimentation tank in which the reaction slurry is reserved to sediment the particles and to separate the reaction slurry into a separation slurry containing the particles at a high concentration and a separation liquid containing the particles at a low concentration, and
wherein, in the recovery unit, an alkaline aqueous solution is added to the separation liquid to crystallize magnesium hydroxide and to obtain the reaction slurry and then the reaction slurry is reserved to sediment the particles and to recover the sedimented particles.

2. The system for producing magnesium hydroxide according to claim 1 , wherein the alkaline aqueous solution is a sodium hydroxide aqueous solution.

3. The system for producing magnesium hydroxide according to claim 1 ,
wherein the reaction tank includes a first reaction tank and a second reaction tank,
wherein the sedimentation tank includes a first sedimentation tank and a second sedimentation tank,
wherein, in the first reaction tank, the calcium hydroxide slurry is added to the water to be treated to generate a first reaction slurry containing the particles,
wherein, in the first sedimentation tank, the first reaction slurry is reserved to sediment the particles and to separate the first reaction slurry into a first separation slurry containing the particles at a high concentration and a first separation liquid containing the particles at a low concentration,
wherein, in the second reaction tank, the calcium hydroxide slurry is added to the first separation liquid to generate a second reaction slurry containing the particles,
wherein, in the second sedimentation tank, the second reaction slurry is reserved to sediment the particles and to separate the second reaction slurry into a second separation slurry containing the particles at a high concentration and a second separation liquid containing the particles at a low concentration, and
wherein, in the recovery unit, the alkaline aqueous solution is added to the second separation liquid as the separation liquid.

4. The system for producing magnesium hydroxide according to claim 1 , further comprising a decarboxylation unit in which at least some of carbonic acid is removed from the water to be treated prior to the generation unit.

5. The system for producing magnesium hydroxide according to claim 1 , further comprising a control unit that controls an amount of the alkaline aqueous solution to be added to the separation liquid on the basis of a concentration of the magnesium ions contained in the separation liquid.

6. The system for producing magnesium hydroxide according to claim 2 ,
wherein the reaction tank includes a first reaction tank and a second reaction tank,
wherein the sedimentation tank includes a first sedimentation tank and a second sedimentation tank,
wherein, in the first reaction tank, the calcium hydroxide slurry is added to the water to be treated to generate a first reaction slurry containing the particles,
wherein, in the first sedimentation tank, the first reaction slurry is reserved to sediment the particles and to separate the first reaction slurry into a first separation slurry containing the particles at a high concentration and a first separation liquid containing the particles at a low concentration,
wherein, in the second reaction tank, the calcium hydroxide slurry is added to the first separation liquid to generate a second reaction slurry containing the particles,
wherein, in the second sedimentation tank, the second reaction slurry is reserved to sediment the particles and to separate the second reaction slurry into a second separation slurry containing the particles at a high concentration and a second separation liquid containing the particles at a low concentration, and
wherein, in the recovery unit, the alkaline aqueous solution is added to the second separation liquid as the separation liquid.

7. The system for producing magnesium hydroxide according to claim 2 , further comprising a decarboxylation unit in which at least some of carbonic acid is removed from the water to be treated prior to the generation unit.

8. The system for producing magnesium hydroxide according to claim 3 , further comprising a decarboxylation unit in which at least some of carbonic acid is removed from the water to be treated prior to the generation unit.

9. The system for producing magnesium hydroxide according to claim 2 , further comprising a control unit that controls an amount of the alkaline aqueous solution to be added to the separation liquid on the basis of a concentration of the magnesium ions contained in the separation liquid.

10. The system for producing magnesium hydroxide according to claim 3 , further comprising a control unit that controls an amount of the alkaline aqueous solution to be added to the separation liquid on the basis of a concentration of the magnesium ions contained in the separation liquid.

11. The system for producing magnesium hydroxide according to claim 4 , further comprising a control unit that controls an amount of the alkaline aqueous solution to be added to the separation liquid on the basis of a concentration of the magnesium ions contained in the separation liquid.

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Takeuchi Kazuhisa
• Ito Yoshiaki
• Kamito Ryo
• Kaneda Shinpei
• Kiyosawa Masashi

Classifications

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C02F2001/5218

  Crystallization · CPC title

• C02F1/5236

  using inorganic agents · CPC title

• C02F1/5209

  Regulation methods for flocculation or precipitation · CPC title

• C01F5/22

  from magnesium compounds with alkali hydroxides or alkaline- earth oxides or hydroxides · CPC title