Gradient permittivity film

Patent metadata

Field	Value
Publication number	US-12362471-B2
Application number	US-201917045582-A
Country	US
Kind code	B2
Filing date	Apr 5, 2019
Priority date	Apr 6, 2018
Publication date	Jul 15, 2025
Grant date	Jul 15, 2025

Abstract

Gradient permittivity films are described. In particular, gradient permittivity films that include a first continuous matrix of a first component having a first relative permittivity and a second component disposed within the continuous matrix having a second relative permittivity. The first permittivity is greater than the second permittivity for at least one wavelength between 20 GHz and 300 GHz. Such films may be useful in improving the signal to noise ratio for transmitting and receiving units behind a protective cover.

First claim

What is claimed is:

1. A gradient permittivity film having a first major surface and an opposing second major surface, separated by a thickness, comprising:
a first continuous matrix of a first component having a first relative permittivity ε r1 ;
a second component disposed within the continuous matrix having a second relative permittivity ε r2 ;
wherein ε r1 is greater than ε r2 for at least one frequency within a frequency range, the frequency range being between 20 GHz and 300 GHz;
wherein a relative permittivity of a first half including the half of the thickness of the
gradient permittivity film closest to the first major surface is lower by at least 10% than a relative permittivity of a second half including the half of the thickness closest to the second major surface, for the at least one frequency within the frequency range;
wherein the gradient permittivity film has a haze greater than 50% or a transmission of visible light less than 50%; and
wherein both the first major surface and second major surface are primarily the first component.

2. The gradient permittivity film of claim 1 , wherein the second component is disposed within a third component having a third relative permittivity ε r3 , and ε r2 ≤ε r3 for the at least one frequency within the frequency range.

3. The gradient permittivity film of claim 2 , wherein the third component is glass and the second component is air.

4. The gradient permittivity film of claim 3 , wherein the glass is coated with a broadband absorber.

5. The gradient permittivity film of claim 2 , wherein the third component is a polymer and the second component is a gas.

6. The gradient permittivity film of claim 5 , wherein the polymer is coated with a broadband absorber.

7. The gradient permittivity film of claim 2 , wherein the third component is a ceramic and the second component is a gas.

8. The gradient permittivity film of claim 7 , wherein the ceramic is porous.

9. The gradient permittivity film of claim 5 , wherein the ceramic is coated with a broadband absorber.

10. The gradient permittivity film of claim 1 , wherein the first component includes a polymeric material.

11. The gradient permittivity film of claim 1 , wherein the continuous matrix is a nonwoven material.

12. The gradient permittivity film of claim 1 , wherein the second component is a gas.

13. The gradient permittivity film of claim 1 , wherein the second component is air.

14. The gradient permittivity film of claim 1 , further comprising a second continuous matrix of a fourth component having a fourth relative permittivity ε r4 ; wherein the second continuous matrix is disposed on the first continuous matrix.

15. The gradient permittivity film of claim 14 , wherein the first component and the fourth component are the same material.

16. The gradient permittivity film of claim 14 , wherein the second continuous matrix includes a different, by at least 10%, volume percentage of the second component within its matrix than the first continuous matrix.

17. The gradient permittivity film of claim 16 , further comprising a third continuous matrix of a fifth component having a fifth relative permittivity ε r5 , wherein the third continuous matrix is disposed on the first continuous matrix or the second continuous matrix, wherein the third continuous matrix includes a different, by at least 10% volume percentage of the second component within its matrix than either the first continuous matrix or the second continuous matrix.

18. The gradient permittivity film of claim 17 , wherein the fifth component, the fourth component, and the first component are the same material.

19. The gradient permittivity film of claim 1 , wherein the gradient permittivity film is a single layer.

20. The gradient permittivity film of claim 1 disposed on a substrate, wherein the substrate is a solid layer without the second component.

21. The gradient permittivity film of claim 1 , wherein a volume fraction of the second component varies over one or more non-thickness directions of the gradient permittivity film.

22. The gradient permittivity film of claim 21 , wherein the variation in the one or more non-thickness directions is a monotonic variation.

23. The gradient permittivity film of claim 1 , wherein the gradient permittivity film is non-planar.

24. The gradient permittivity film of claim 1 , wherein the first continuous matrix of the first component includes fibers.

25. The gradient permittivity film of claim 1 , wherein the gradient permittivity film of claim 1 includes perforations.

26. The gradient permittivity film of claim 25 , wherein the perforations are round.

27. The gradient permittivity film of claim 25 , wherein the perforations are differently sized.

28. The gradient permittivity film of claim 25 , wherein the perforations vary in size, shape, or density over one or more non-thickness directions.

29. The gradient permittivity film of claim 1 , wherein the frequency range is between 20 GHz and 120 GHz.

30. The gradient permittivity film of claim 1 , wherein the frequency range is between 20 GHz and 100 GHz.

31. The gradient permittivity film of claim 1 , wherein the frequency range is between 20 GHz and 81 GHz.

32. The gradient permittivity film of claim 1 , wherein the frequency range is between 20 GHz and 30 GHz.

33. A gradient permittivity tape, comprising the gradient permittivity film of claim 1 and an adhesive layer.

34. The gradient permittivity tape of claim 33 , further comprising a backing layer disposed on the adhesive layer opposing the gradient permittivity film.

35. An assembly, comprising the gradient permittivity tape of claim 33 attached to a vehicle bumper fascia.

36. The assembly of claim 35 , wherein, at a location of attachment of the gradient permittivity tape to the vehicle bumper fascia, a relative permittivity of the vehicle bumper fascia is within 10% of the first relative permittivity.

37. The assembly of claim 36 , wherein the relative permittivity of the vehicle bumper fascia is within 5% of the first relative permittivity.

38. An assembly, comprising the gradient permittivity tape of claim 33 attached to an automobile radome.

39. The assembly of claim 38 , wherein, at a location of attachment of the gradient permittivity tape and the automobile radome, a relative permittivity of the automobile radome is within 10% of the first relative permittivity.

40. The assembly of claim 39 , wherein the relative permittivity of the automobile radome is within 5% of the first relative permittivity.

Assignees

• 3M Innovative Properties Company

Inventors

• Jesme Ronald D
• Kim Jaewon
• Etzkorn Stephen J
• Ghosh Dipankar
• Salehi Mohsen
• Du Guanglei
• Wheatley John A

Classifications

• C09J2433/006

  in the substrate · CPC title

• C09J11/04

  inorganic · CPC title

• C08K7/28

  Glass · CPC title

• C08K3/40

  Glass · CPC title

• C08J2333/04

  esters · CPC title