Water-repellent woven or knitted article, production method for same, and garment

Patent metadata

Field	Value
Publication number	US-12359368-B2
Application number	US-202017421493-A
Country	US
Kind code	B2
Filing date	Jan 22, 2020
Priority date	Jan 30, 2019
Publication date	Jul 15, 2025
Grant date	Jul 15, 2025

Abstract

The present invention provides a water-repellent woven or knitted article that overcomes the problems of the related art and exhibits water-repellent properties and is excellent in abrasion resistance and durability. The water-repellent woven or knitted article of the present invention is a woven or knitted article subjected to a water repellent treatment using a water repellent having a perfluorooctanoic acid (PFOA) concentration of 5 ng/g or less, wherein the woven or knitted article includes, as constituent fibers, fibers having a transverse cross-sectional shape, each fiber has a plurality of grooves at an outer circumference of the transverse cross section, each groove has a wide part, and a size of the grooves in the fibers satisfies the following Formulae (Formula 1) and (Formula 2):

w 2/ w 1≥1.3  (Formula 1)

0.15≤ h/d ≤0.25  (Formula 2)
where w 1 represents a groove entrance width, w 2 represents a groove wide part width, h represents a groove depth, and d represents a diameter of the fiber, a droplet contact angle between the woven or knitted article and water is 135° or more after 20 times of washing in accordance with a method of JIS L 0217 103 and a water repellency is grade 4 or more in accordance with a spray method of JIS L 1092.

First claim

The invention claimed is:

1. A water-repellent woven or knitted article that is a woven or knitted article subjected to a water repellent treatment using a water repellent having a perfluorooctanoic acid concentration of 5 ng/g or less, wherein the woven or knitted article includes, as constituent fibers, fibers having a transverse cross-sectional shape, each fiber has a plurality of grooves at an outer circumference of the transverse cross section, each groove has a wide part, and a size of the grooves in the fibers satisfies the following Formulae (Formula 1) and (Formula 2):
w 2 /w 1 ≥1.3  (Formula 1)

0.15≤h/d≤0.25  (Formula 2)

where w 1 represents a groove entrance width, w 2 represents a groove wide part width, h represents a groove depth, and d represents a diameter of specific cross section fiber,
a droplet contact angle between the woven or knitted article and water is 135° or more after 20 times of washing in accordance with a method of JIS L 0217 103 and a water repellency is grade 4 or more in accordance with a spray method of JIS L 1092.

2. A water-repellent woven or knitted article that is a woven or knitted article with a water repellent attached, wherein the water repellent contains only a fluorine-based water repellent composed of a fluorine compound having a perfluoroalkyl group having 6 or less carbon atoms or a non-fluorine-based water repellent, and the woven or knitted article includes, as constituent fibers, fibers having a transverse sectional shape, each fiber has a plurality of grooves at an outer circumference of the transverse cross section, each groove has a wide part, and a size of the grooves in the fibers satisfies the following Formulae (Formula 1) and (Formula 2):
w 2 /w 1 ≥1.3  (Formula 1)

0.15≤h/d≤0.25  (Formula 2)

where w 1 represents a groove entrance width, w 2 represents a groove wide part width, h represents a groove depth, and d represents a diameter of specific cross section fiber,
a droplet contact angle between the woven or knitted article and water is 135° or more after 20 times of washing in accordance with a method of JIS L 0217 103 and a water repellency is grade 4 or more in accordance with a spray method of JIS L 1092.

3. The water-repellent woven or knitted article according to claim 1 , wherein a degree of discoloration after a friction test under wet conditions is grade 4 or more.

4. The water-repellent woven or knitted article according to claim 1 , wherein the water repellent is a water repellent mainly composed of a silicone-based or paraffin-based compound.

5. A garment comprising at least a part of the water-repellent woven or knitted article according to claim 1 .

6. A method for producing the water-repellent woven or knitted article according to claim 1 , comprising subjecting a woven or knitted article to a water repellent treatment using a water repellent having a perfluorooctanoic acid concentration of 5 ng/g or less, wherein the woven or knitted article includes, as constituent fibers, fibers having a transverse sectional shape, each fiber has a plurality of grooves at an outer circumference of the transverse cross section, each groove has a wide part, and a size of the grooves in the fibers satisfies the following Formulae (Formula 1) and (Formula 2):
w2/w1≥1.3  (Formula 1)

0.15≤h/d≤0.25  (Formula 2)

where w 1 represents a groove entrance width, w 2 represents a groove wide part width, h represents a groove depth, and d represents a diameter of specific cross section fiber.

7. The method for producing the water-repellent woven or knitted article according to claim 6 , wherein a non-fluorine-based water repellent is used as the water repellent.

8. The method for producing the water-repellent woven or knitted article according to claim 6 , wherein a water repellent mainly composed of a silicone-based or paraffin-based compound is used as the water repellent.

Assignees

• Toray Industries

Inventors

• Toyabe Keigo
• Fujita Kazuya

Classifications

• D06M2200/12

  Hydrophobic properties · CPC title

• D06M15/643

  containing silicon in the main chain · CPC title

• A41D31/10 Primary

  Impermeable to liquids, e.g. waterproof; Liquid-repellent · CPC title

• D03D15/37

  with specific cross-section or surface shape · CPC title

• D03D15/283

  synthetic polymer-based, e.g. polyamide or polyester fibres (cellulose-based artificial fibres D03D15/225) · CPC title