Electrochemical cells for hydrogen gas production and electricity generation, and related systems and methods

Patent metadata

Field	Value
Publication number	US-12359327-B2
Application number	US-201917309012-A
Country	US
Kind code	B2
Filing date	Oct 28, 2019
Priority date	Oct 29, 2018
Publication date	Jul 15, 2025
Grant date	Jul 15, 2025

Abstract

An electrochemical cell comprises a first electrode, a second electrode, and a proton-conducting membrane between the first electrode and the second electrode. The first electrode comprises a layered perovskite having the general formula: DAB 2 O 5+δ , wherein D consists of two or more lanthanide elements; A consists of one or more of Sr and Ba; B consists of one or more of Co, Fe, Ni, Cu, Zn, Mn, Cr, and Nd; and δ is an oxygen deficit. The second electrode comprises a cermet material including at least one metal and at least one perovskite. Related structures, apparatuses, systems, and methods are also described.

First claim

What is claimed is:

1. An electrochemical cell for hydrogen gas production, comprising:
an anode configured to produce oxygen gas from steam;
a cathode configured to produce hydrogen gas from the steam; and
a proton-conducting membrane between the anode and the cathode,
wherein the anode comprises a layered perovskite having a general formula:
DAB 2 O 5+δ ,
wherein:
D consists of two or more lanthanide (Ln) elements;
A consists of one or more of Sr and Ba;
B consists of one or more of Co, Fe, Ni, Cu, Zn, Mn, Cr, and Nd; and
δ is an oxygen deficit, and

wherein the cathode comprises a cermet material including at least one metal and at least one perovskite.

2. The electrochemical cell of claim 1 , wherein the anode comprises (Pr 1-x Ln x )(Ba y ,Sr 1-y )(Co z ,Tn 1-z ) 2 O 5+δ , wherein Ln is selected from La, Nd, Ce, Pm, Sm, Er, Gd, Dy, Ho, and Yb; Tn is selected from Fe, Ni, Cu, Zn, Mn, Cr, and Nd; 0<x<1; 0≤y≤1; and 0≤z≤1.

3. The electrochemical cell of claim 1 , wherein the anode comprises Pr 0.5 La 0.5 BaCo 2 O 5+δ .

4. The electrochemical cell of claim 1 , wherein the layered perovskite of the anode comprises:
a first BaO layer;
a first CoO 2 layer on the first BaO layer;
a first DO z layer on the first CoO 2 layer, wherein z<1;
a second CoO 2 layer on the first DO z layer; and
a second BaO layer on the second CoO 2 layer.

5. The electrochemical cell of claim 1 , wherein the cathode comprises a nickel/perovskite cermet.

6. The electrochemical cell of claim 1 , wherein the cathode comprises a Ni-BCZYYb.

7. The electrochemical cell of claim 1 , wherein the proton-conducting membrane comprises one or more of a BCZYYb, a BSNYYb, a doped BaCeO 3 , a doped BaZrO 3 , Ba 2 (YSn)O 5.5 , and Ba 3 (CaNb 2 )O 9 .

8. The electrochemical cell of claim 1 , wherein the proton-conducting membrane comprises a BCZYYb.

9. A system for H 2 gas production, comprising:
a source of steam; and
an electrochemical apparatus in fluid communication with the source of steam, and comprising:
a housing structure configured and positioned to receive a steam stream from the source of steam; and
an electrochemical cell within an internal chamber of the housing structure, and comprising:
an anode configured to produce oxygen gas from the steam, the anode comprising a layered perovskite having a general formula:
DAB 2 O 5+δ ,
wherein:
D consists of two or more lanthanide (Ln) elements;
A consists of one or more of Sr and Ba;
B consists of one or more of Co, Fe, Ni, Cu, Zn, Mn, Cr, and Nd; and
δ is an oxygen deficit;

a cathode configured to produce hydrogen gas from the steam, the cathode comprising a cermet material including at least one metal and at least one perovskite; and
a proton-conducting membrane between the anode and cathode.

10. The system of claim 9 , wherein the electrochemical cell is configured to switch between the electrolysis mode for producing the H 2 gas from the steam stream and a fuel cell mode for generating electricity from the produced H 2 gas at the one or more temperatures within the range of from about 400° C. to about 700° C.

11. The system of claim 9 , further comprising at least one heating apparatus operatively associated with the electrochemical apparatus and configured to heat the steam stream to the one or more temperatures within the range of from about 400° C. to about 700° C.

12. The system of claim 9 , wherein the proton-conducting membrane comprises a BCZYYb selected from BaCe 0.4 Zr 0.4 Y 0.1 Yb 0.1 O 3-δ , BaCe 0.5 Zr 0.3 Y 0.1 Yb 0.1 O 3-δ , and BaCe 0.7 Zr 0.1 Y 0.1 Yb 0.1 O 3-δ .

13. The electrochemical cell of claim 1 , wherein D consists of two or more of La, Ce, Pr, Nd, Pm, Sm, Er, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu.

14. The electrochemical cell of claim 1 , wherein:
D consists of Pr and one of La, Ce, Nd, Pm, Sm, Er, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; and
B consists of Co and one of Fe, Ni, Cu, Zn, Mn, Cr, and Nd.

15. The electrochemical cell of claim 1 , wherein:
D consists of Pr and La;
A consists of Ba; and
B consists of Co.

16. The electrochemical cell of claim 1 , wherein the layered perovskite of the anode consists essentially of Pr 0.5 La 0.5 BaCo 2 O 5+δ .

17. The electrochemical cell of claim 1 , wherein the layered perovskite of the anode consists of Pr 0.5 La 0.5 BaCo 2 O 5+δ .

Assignees

• Battelle Energy Alliance Llc

Inventors

• Ding Dong
• Ding Hanping
• Wu Wei
• Jiang Chao

Classifications

• C25B9/015

  Cylindrical cells · CPC title

• C25B9/23 Primary

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• C25B13/00

  Diaphragms; Spacing elements · CPC title

• C25B11/091

  consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds · CPC title

• C25B15/023

  Measuring, analysing or testing during electrolytic production · CPC title