Glass fiber reinforced polycarbonate composite material, preparation method and application thereof

Patent metadata

Field	Value
Publication number	US-12359061-B2
Application number	US-202017638192-A
Country	US
Kind code	B2
Filing date	Jul 24, 2020
Priority date	Aug 30, 2019
Publication date	Jul 15, 2025
Grant date	Jul 15, 2025

Abstract

A glass fiber reinforced polycarbonate composite material, a preparation method and an application thereof; the material includes the following components:component A: 40 parts to 90 parts of a polycarbonate;component B: 1.5 parts to 50 parts of a polysiloxane block copolymer;component C: 5 parts to 60 parts of a glass fiber;component D: 0.1 parts to 30 parts of a phosphorus-containing compound; andcomponent E: 0.01 parts to 30 parts of a polyolefin compound.

First claim

What is claimed is:

1. A glass fiber reinforced polycarbonate composite material, comprising the following components in parts by weight:
component A: 40 parts to 90 parts of a polycarbonate;
component B: 1.5 parts to 50 parts of a polysiloxane block copolymer;
component C: 5 parts to 60 parts of a glass fiber;
component D: 10 parts to 30 parts of a phosphorus-containing compound, wherein the phosphorus-containing compound is hypophosphorous acid; and
component E: 0.01 parts to 30 parts of a polyolefin compound.

2. The glass fiber reinforced polycarbonate composite material according to claim 1 , wherein in the glass fiber reinforced polycarbonate composite material, a percentage of a siloxane content accounting for a total weight percentage of the composite material is 0.6 wt % to 17 wt %.

3. The glass fiber reinforced polycarbonate composite material according to claim 1 , wherein the polycarbonate is selected from one or more of an aromatic polycarbonate, an aliphatic polycarbonate, an aromatic-aliphatic polycarbonate, and a branched polycarbonate; the aromatic polycarbonate is an aromatic polycarbonate having a viscosity-average molecular weight of 13,000 to 40,000.

4. The glass fiber reinforced polycarbonate composite material according to claim 1 , wherein the polysiloxane block copolymer comprises a polydimethylsiloxane block and a polycarbonate block of bisphenol A, having a siloxane content of 0.6 wt % to 36 wt % based on a weight of the component B.

5. The glass fiber reinforced polycarbonate composite material according to claim 1 , wherein the polyolefin compound is selected from a saturated linear polyolefin; the saturated linear polyolefin is selected from polyethylene.

6. The glass fiber reinforced polycarbonate composite material according to claim 1 , wherein based on the weight of the glass fiber reinforced polycarbonate composite material, the glass fiber reinforced polycarbonate composite material further comprises a component F: 0 to 10 parts of an additional auxiliary agent; the additional auxiliary agent is selected from one or more of a stabilizer, a flame retardant, an anti-drip agent, a lubricant, a release agent, a plasticizer, a filler, an antistatic agent, an antibacterial agent and a colorant.

7. A preparation method of the glass fiber reinforced polycarbonate composite material according to claim 1 , comprising the following steps:
1) Weighing the polycarbonate, the polysiloxane block copolymer, the phosphorus-containing compound, the polyolefin compound, and the additional auxiliary agent according to a ratio, stirring and blending for 1 to 3 min in a high-speed mixer to obtain a premix; and
2) placing the obtained premix to a major feeding port of a twin-screw extruder, and adding glass fiber to a side feeding port for melt extrusion, then performing pelleting and drying to obtain the glass fiber reinforced polycarbonate composite material.

8. The preparation method of the glass fiber reinforced polycarbonate composite material according to claim 7 , wherein the twin-screw extruder has a length-diameter ratio of 46:1 to 50:1; and temperatures of the twin-screw extruder from a feeding section to a head section are successively: 120° C. to 160° C. in a zone I, 200° C. to 230° C. in a zone II, 200° C. to 230° C. in a zone III, 200° C. to 220° C. in a zone IV, 200° C. to 220° C. in a zone V, 200° C. to 220° C. in a zone VI, 200° C. to 220° C. in a zone VII, 200° C. to 220° C. in a zone VIII, 200° C. to 220° C. in a zone IX, 200° C. to 220° C. in a zone X, 200° C. to 220° C. in a zone XI, and 220° C.-to 240° C. in the head section; and a main engine revolution speed is 350 rpm to 500 rpm.

9. The glass fiber reinforced polycarbonate composite material according to claim 1 , comprising the following components in parts by weight:
component A: 40 parts to 90 parts of the polycarbonate;
component B: 3.5 parts to 45 parts of the polysiloxane block copolymer;
component C: 5 parts to 60 parts of the glass fiber;
component D: 10 parts to 12 parts of the phosphorus-containing compound; and
component E: 6 parts to 10 parts of the polyolefin compound.

10. The glass fiber reinforced polycarbonate composite material according to claim 9 , wherein in the glass fiber reinforced polycarbonate composite material, a percentage of a siloxane content accounting for a total weight percentage of the composite material is 0.6 wt % to 17 wt %.

11. The glass fiber reinforced polycarbonate composite material according to claim 9 , wherein the polycarbonate is selected from one or more of an aromatic polycarbonate, an aliphatic polycarbonate, an aromatic-aliphatic polycarbonate, and a branched polycarbonate; the aromatic polycarbonate is an aromatic polycarbonate having a viscosity-average molecular weight of 13,000 to 40,000.

12. The glass fiber reinforced polycarbonate composite material according to claim 9 , wherein the polysiloxane block copolymer comprises a polydimethylsiloxane block and a polycarbonate block of bisphenol A, having a siloxane content of 0.6 wt % to 36 wt % based on a weight of the component B.

13. The glass fiber reinforced polycarbonate composite material according to claim 9 , wherein the polyolefin compound is selected from a saturated linear polyolefin; the saturated linear polyolefin is selected from polyethylene.

14. The glass fiber reinforced polycarbonate composite material according to claim 9 , wherein based on the weight of the glass fiber reinforced polycarbonate composite material, the glass fiber reinforced polycarbonate composite material further comprises a component F: 0 to 10 parts of an additional auxiliary agent; the additional auxiliary agent is selected from one or more of a stabilizer, a flame retardant, an anti-drip agent, a lubricant, a release agent, a plasticizer, a filler, an antistatic agent, an antibacterial agent and a colorant.

Assignees

• Kingfa Science & Technology Co

Inventors

• Cen yin
• Ai Junwei
• Chen Yongwen
• Li Mingkun
• Liu Xianwen
• Zhao Tipeng
• Tong Wei

Classifications

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08J2469/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08J5/043 Primary

  with glass fibres · CPC title

• C08K7/14

  Glass · CPC title

• C08G77/448

  containing polycarbonate sequences · CPC title