Foamable polyolefin composition providing increased flexibility

Patent metadata

Field	Value
Publication number	US-12359036-B2
Application number	US-202017434430-A
Country	US
Kind code	B2
Filing date	Mar 5, 2020
Priority date	Mar 6, 2019
Publication date	Jul 15, 2025
Grant date	Jul 15, 2025

Abstract

The invention relates to a foamable polymer composition comprising a polyolefin polymer which polyolefin polymer does not bear silane moieties and comprises 20 to 99.99 wt. % linear low density polyethylene, and a blowing agent in an amount of 0.01 to 3 wt. % based on the total foamable polymer composition, wherein the blowing agent consists of citric acid and/or derivatives of citric acid or mixtures thereof. Further the invention relates to a foamable polymer composition comprising a polyolefin polymer, and a blowing agent in an amount of 0.01 to 3 wt. % based on the total foamable polymer composition, wherein the blowing agent consists of expandable polymeric microspheres, and the composition does not comprise fluororesin. Further the invention relates to a foamed polymer composition obtained by foaming this foamable polymer composition. Further the invention relates to the use of the foamable composition or the foamed polymer composition for a layer of a cable and a cable comprising at least one layer which comprises the foamable polymer composition or the foamed polymer composition.

First claim

The invention claimed is:

1. A cable comprising:
a cable core; and
at least one layer surrounding the cable core which comprises a foamed composition obtained by foaming a foamable polymer composition comprising:
(A) a polyolefin polymer, wherein the polyolefin polymer (A) does not bear silane moieties and comprises 20 to 99.99 wt. % linear low density polyethylene based on the total weight of the foamable composition wherein the linear low density polyethylene has a density of 880 to 930 kg/m 3 measured according to ISO 1183-1 on samples prepared according to ISO 1872-2, and
(B) a blowing agent in an amount of 0.01 to 3 wt. % based on the total foamable polymer composition, wherein the blowing agent consists of expandable polymeric microspheres,
and the composition does not comprise fluororesin-,
and wherein the foamable composition does not comprise polyolefin polymers bearing silane groups.

2. The cable according to claim 1 , wherein the polyolefin polymer (A) has an MFR 2 of 0.1 to 10 g/10 min measured according to ISO 1133 at 190° C. and a load of 2.16 kg.

3. The cable according to claim 1 , wherein the polyolefin polymer (A) further comprises 0.1 to 80 wt. % low density polyethylene based on the total weight of the foamable polymer composition.

4. The cable according to claim 1 , wherein the composition does not comprise an azo compound and/or physical blowing agents.

5. The cable according to claim 1 , wherein the foamable polymer composition comprises an antioxidant and/or an acid scavenger.

6. A method for the production of a layer of a cable, comprising extruding a foamable composition on a cable core, and foaming the foamable composition, wherein the foamable composition comprises
(A) a polyolefin polymer, wherein the polyolefin polymer (A) does not bear silane moieties and comprises 20 to 99.99 wt. % linear low density polyethylene based on the total weight of the foamable composition wherein the linear low density polyethylene has a density of 880 to 930 kg/m 3 measured according to ISO 1183-1 on samples prepared according to ISO 1872-2, and
(B) a blowing agent in an amount of 0.01 to 3 wt. % based on the total foamable polymer composition, wherein the blowing agent consists of expandable polymeric microspheres, and the composition does not comprise fluororesin,
and wherein the foamable composition does not comprise polyolefin polymers bearing silane groups.

7. The cable according to claim 5 , wherein the antioxidant is a phenolic antioxidant, a phosphorous containing antioxidant, or mixtures thereof.

8. The cable according to claim 5 , wherein the acid scavenger is a calcium stearate, a zinc stearate, or mixtures thereof.

Assignees

• Borealis Ag

Inventors

• Hjartfors Anna
• Wannerskog Asa
• Anker Martin
• Efraimsson Lars
• Nilsson Anette

Classifications

• H01B13/142

  of cellular material · CPC title

• H01B3/441

  from alkenes · CPC title

• C08K2201/019

  the composition being defined by the absence of a certain additive · CPC title

• C08K7/22

  Expanded, porous or hollow particles · CPC title

• C08K5/521

  Esters of phosphoric acids, e.g. of H3PO4 · CPC title