Organic solvent purification method and purification system

Patent metadata

Field	Value
Publication number	US-12357984-B2
Application number	US-202017763088-A
Country	US
Kind code	B2
Filing date	Sep 15, 2020
Priority date	Sep 30, 2019
Publication date	Jul 15, 2025
Grant date	Jul 15, 2025

Abstract

A purification method for separating and purifying an organic solvent from a liquid mixture of an organic solvent and water, the organic solvent having a boiling point of more than 100° C. at 1 atm, includes the steps of: passing the liquid mixture through a first ion exchange device; supplying the liquid mixture discharged from the first ion exchange device to a pervaporation device to selectively separate water component; supplying the organic solvent recovered from the concentration side of the pervaporation device to an evaporator to obtain a purified organic solvent; and passing, through the second ion exchange device, a portion of liquid containing the organic solvent and flowing at a first position subsequent to the first ion exchange device. The liquid discharged from the second ion exchange device is returned to a second position which is at a preceding stage of the pervaporation device.

First claim

The invention claimed is:

1. A purification method for separating and purifying an organic solvent from a liquid mixture of the organic solvent and water, the organic solvent having a boiling point of more than 100° C. at 1 atm, the purification method comprising:
a first ion exchange step of passing the liquid mixture into a first ion exchange resin;
a dehydration step of selectively separating water component from the liquid mixture by supplying the liquid mixture discharged from the first ion exchange step to a pervaporation device having a pervaporation membrane;
an evaporation step of supplying the organic solvent recovered from a concentration side of the pervaporation membrane to an evaporator to vaporize, and obtaining the organic solvent which has been purified; and
a second ion exchange step of treating a portion of liquid which contains the organic solvent that flows into a branch point at a first position, and
wherein liquid discharged from the second ion exchange step is returned to a second position,
wherein the first position is:
located between the concentration side of the pervaporation membrane and an inlet of the evaporator,
located between an outlet of the first ion exchange step and an inlet of the pervaporation device, and prior to the second position, and/or
at a position at which the organic solvent discharged from the evaporation step flows, and

wherein the second position is located between the outlet of the first ion exchange step and an inlet of the dehydration step.

2. The purification method according to claim 1 , wherein in the second ion exchange step, liquid supplied to the second ion exchange step is circulated between an ion exchange unit filled with the second ion exchange resin and a tank.

3. The purification method according to claim 1 , wherein, in the second ion exchange step, liquid supplied to the second ion exchange step is stirred together with the second ion exchange resin in a tank into which the second ion exchange resin is charged.

4. The purification method according to claim 1 , wherein, in the second ion exchange step, liquid supplied to the second ion exchange step is passed through an ion exchange unit filled with the second ion exchange resin, and the liquid discharged from the ion exchange unit is returned to the second position.

5. The purification method according to claim 1 , comprising a step of measuring conductivity of liquid supplied to the second ion exchange step.

6. A purification system for separating and purifying an organic solvent from a liquid mixture of the organic solvent and water, the organic solvent having a boiling point of more than 100° C. at 1 atm, the purification system comprising:
a first ion exchange device to which the liquid mixture is supplied;
a pervaporation device having a pervaporation membrane in which the liquid mixture passed through the first ion exchange device is supplied to selectively separate water component from the liquid mixture;
an evaporator vaporizing the organic solvent recovered from a concentration side of the pervaporation membrane and generating the organic solvent which has been purified; and
a second ion exchange device fluidly connected to a branch point at a first position,
wherein liquid discharged from the second ion exchange device is returned to a second position,
wherein the first position is:
located between the concentration side of the pervaporation membrane and an inlet of the evaporator,
located between an outlet of the first ion exchange device and an inlet of the pervaporation device, and is prior to the second position, and/or
at a position at which the organic solvent discharged from the evaporator flows, and

wherein the second position is located between the outlet of the first ion exchange device and the inlet of the pervaporation device.

7. The purification system of claim 6 , wherein the second ion exchange device comprises: a tank; and an ion exchange unit filled with ion exchange resin, and wherein liquid supplied to the second ion exchange device circulates between the tank and the ion exchange unit.

8. The purification system according to claim 6 , wherein the second ion exchange device comprises: a tank into which an ion exchange resin is charged; and a stirring device which stirs inside of the tank, and wherein liquid supplied to the second ion exchange device is stirred together with the ion exchange resin in the tank.

9. The purification system according to claim 6 , wherein the second ion exchange device comprises an ion exchange unit which is filled with ion exchange resin and through which liquid supplied to the second ion exchange device is passed, and wherein liquid discharged from the ion exchange unit is returned to the second position.

10. The purification method according to claim 1 , comprising means for measuring conductivity of liquid supplied to the second ion exchange device, the means is provided at an inlet of the second ion exchange device.

11. The purification method according to claim 2 , comprising a step of measuring conductivity of the liquid supplied to the second ion exchange step.

12. The purification method according to claim 3 , comprising a step of measuring conductivity of the liquid supplied to the second ion exchange step.

13. The purification method according to claim 4 , comprising a step of measuring conductivity of the liquid supplied to the second ion exchange step.

14. The purification system according to claim 7 , comprising means for measuring conductivity of liquid supplied to the second ion exchange device, the means is provided at an inlet of the second ion exchange device.

15. The purification system according to claim 8 , comprising means for measuring conductivity of liquid supplied to the second ion exchange device, the means is provided at an inlet of the second ion exchange device.

16. The purification system according to claim 9 , comprising means for measuring conductivity of liquid supplied to the second ion exchange device, the means is provided at an inlet of the second ion exchange device.

Assignees

• Organo Corp

Inventors

• Terashi Ryosuke
• Yamada Kyosuke

Classifications

• B01D61/365

  Osmotic distillation or osmotic evaporation · CPC title

• C07D207/267 Primary

  with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atom · CPC title

• C07B63/00

  Purification; Separation (separation of optically-active compounds C07B57/00); Stabilisation; Use of additives · CPC title

• B01J47/14

  Controlling or regulating · CPC title

• B01J47/10

  with moving ion-exchange material; with ion-exchange material in suspension or in fluidised-bed form · CPC title