Vertically-aligned graphene-carbon fiber hybrid electrodes and methods for making same
US-11686011-B2 · Jun 27, 2023 · US
US12354796B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12354796-B2 |
| Application number | US-202217842145-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 16, 2022 |
| Priority date | Aug 16, 2021 |
| Publication date | Jul 8, 2025 |
| Grant date | Jul 8, 2025 |
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A dual-function supercapacitor carbon fiber composite stores electrical energy and functions, for example, as the body shell of electric vehicles (EVs). This is achieved with a vertically aligned graphene on carbon fiber electrode, upon which metal oxides were deposited to obtain ultra-high energy density anode and cathode. A high-strength multilayer carbon composite assembly is fabricated using an alternate layer patterning configuration of epoxy and polyacrylamide gel electrolyte. The energized composite delivers a high areal energy density of 0.31 mWh cm −2 at 0.3 mm thickness and showed a high tensile strength of 518 MPa, bending strength of 477 MPa, and impact strength 2666 J/m. To show application in EVs, a toy car body fabricated with energized composite operates using the energy stored inside the frame. Moreover, when integrated with a solar cell, this composite powered an IoT (internet of things) device, showing feasibility in communication satellites.
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What is claimed is: 1. A method of making an energy storing carbon fiber reinforced polymer composite, the method comprising: depositing cathode material patches at spaced locations on a first cross-weaved carbon fiber mat to form a first cathode, the deposited cathode material patches collectively having a first configuration; depositing anode material patches at spaced locations on a second cross-weaved carbon fiber mat to form a first anode, the deposited anode material patches collectively having a second configuration that matches the first configuration; and stacking the first and second cross-weaved carbon fiber mats so that the cathode material patches substantially align with the anode material patches with a first separator cross-weaved glass fiber mat positioned between the first and second cross-weaved carbon fiber mats, wherein the first separator cross-weaved glass fiber mat includes electrolyte coating patches on both sides, the electrolyte coating patches having a third configuration that matches the first and second configurations; and wherein the spaces between the cathode material patches, the anode material patches, and the electrolyte coating patches include a filler material. 2. The method of claim 1 further comprising: depositing cathode material patches at spaced locations on a third cross-weaved carbon fiber mat to form a second cathode, the deposited cathode material patches collectively having a fourth configuration; depositing anode material patches at spaced locations on a fourth cross-weaved carbon fiber mat to form a second anode, the deposited anode material patches collectively having a fifth configuration that matches the fourth configuration; stacking the third and fourth cross-weaved carbon fiber mats so that the cathode material patches substantially align with the anode material patches with a second separator cross-weaved glass fiber mat positioned between the third and fourth cross-weaved carbon fiber mats; stacking the stacked third and fourth cross-weaved carbon fiber mats and second separator cross-weaved glass fiber mat and the stacked first and second cross-weaved carbon fiber mats and first separator cross-weaved glass fiber mat with a first insulator cross-weaved glass fiber mat positioned between the second and third cross-weaved carbon fiber mats; and electrically connecting the first and fourth cross-weaved carbon fiber mats in series, wherein the second separator cross-weaved glass fiber mat includes electrolyte coating patches on both sides, the electrolyte coating patches having a sixth configuration that matches the fourth and fifth configurations; and wherein the spaces between the cathode material patches, the anode material patches, and the electrolyte coating patches include a filler material. 3. The method of claim 2 , wherein the filler material comprises an epoxy resin. 4. The method of claim 3 , wherein the electrolyte coating patches comprise a PAM gel electrolyte. 5. The method of claim 2 , wherein the electrolyte coating patches comprise a PAM gel electrolyte. 6. The method of claim 1 , wherein the filler material comprises an epoxy resin. 7. The method of claim 6 , wherein the electrolyte coating patches comprise a PAM gel electrolyte. 8. An energy storing carbon fiber reinforced polymer composite comprising: a first cathode including cathode material patches at spaced locations on a first cross-weaved carbon fiber mat, the deposited cathode material patches collectively having a first configuration; a first anode including anode material patches at spaced locations on a second cross-weaved carbon fiber mat, the deposited anode material patches collectively having a second configuration that matches the first configuration; and a first separator cross-weaved glass fiber mat positioned between the first and second cross-weaved carbon fiber mats, wherein the first and second cross-weaved carbon fiber mats are stacked so that the cathode material patches substantially align with the anode material patches; wherein the first separator cross-weaved glass fiber mat includes electrolyte coating patches on both sides, the electrolyte coating patches having a third configuration that matches the first and second configurations; and wherein the spaces between the cathode material patches, the anode material patches, and the electrolyte coating patches include a filler material. 9. The composite of claim 8 further comprising: a second cathode including cathode material patches at spaced locations on a third cross-weaved carbon fiber mat, the deposited cathode material patches collectively having a fourth configuration; a second anode including anode material patches at spaced locations on a fourth cross-weaved carbon fiber mat, the deposited anode material patches collectively having a fifth configuration that matches the fourth configuration; and a second separator cross-weaved glass fiber mat positioned between the third and fourth cross-weaved carbon fiber mats, wherein the third and fourth cross-weaved carbon fiber mats are stacked so that the cathode material patches substantially align with the anode material patches; wherein the stacked third and fourth cross-weaved carbon fiber mats and second separator cross-weaved glass fiber mat and the stacked first and second cross-weaved carbon fiber mats and first separator cross-weaved glass fiber mat are stacked with a first insulator cross-weaved glass fiber mat positioned between the second and third cross-weaved carbon fiber mats; wherein the first and fourth cross-weaved carbon fiber mats are electrically connected in series; wherein the second separator cross-weaved glass fiber mat includes electrolyte coating patches on both sides, the electrolyte coating patches having a sixth configuration that matches the fourth and fifth configurations; and wherein the spaces between the cathode material patches, the anode material patches, and the electrolyte coating patches include a filler material. 10. The composite of claim 9 , wherein the filler material comprises an epoxy resin. 11. The composite of claim 10 , wherein the electrolyte coating patches comprise a PAM gel electrolyte. 12. The composite of claim 9 , wherein the electrolyte coating patches comprise a PAM gel electrolyte. 13. The composite of claim 8 , wherein the filler material comprises an epoxy resin. 14. The composite of claim 13 , wherein the electrolyte coating patches comprise a PAM gel electrolyte. 15. An energy storing device panel for a device comprising the carbon fiber reinforced polymer composite of claim 8 . 16. The energy storing device panel of claim 15 , wherein the device is an electric vehicle.
characterised by their structure · CPC title
Superstructures (B62D25/161 takes precedence) · CPC title
using propulsion power supplied by capacitors · CPC title
Electric vehicles · CPC title
arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives · CPC title
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