Air separation unit and method for cryogenic separation of air using a distillation column system including an intermediate pressure kettle column

Patent metadata

Field	Value
Publication number	US-12352496-B2
Application number	US-202217875687-A
Country	US
Kind code	B2
Filing date	Jul 28, 2022
Priority date	Jul 28, 2022
Publication date	Jul 8, 2025
Grant date	Jul 8, 2025

Abstract

An air separation unit and associated method for separating air by cryogenic distillation using a distillation column system including a higher pressure column, a lower pressure column, an intermediate pressure kettle column, and an argon column arrangement is provided. The present air separation unit and associated method employs a once-through kettle column reboiler, a once-through kettle column condenser, and a once-through argon condenser. The once through argon condenser is disposed within the lower pressure column where an argon-rich vapor stream is condensed against the descending liquid in the lower pressure column.

First claim

What is claimed is:

1. An air separation unit for production of product streams from a source of purified, compressed feed air, the air separation unit comprising:
a higher pressure column configured to receive one or more streams of compressed, purified air and a first reflux stream and yield a nitrogen-rich overhead and a kettle liquid;
a lower pressure column configured to receive a diverted liquid air stream and a second reflux stream and yield a low pressure product grade nitrogen overhead, an oxygen liquid at the bottom of the column, and an argon-oxygen contain side stream;
a main condenser-reboiler disposed in the lower pressure column and configured for thermally coupling the higher pressure column and the lower pressure column by liquefying at least a portion of the nitrogen-rich overhead from the higher pressure column against the oxygen liquid at the bottom of the lower pressure column to yield the first reflux stream and the second reflux stream;
an intermediate pressure kettle column configured to receive the kettle liquid from the higher pressure column and yield an oxygen-rich bottoms and a nitrogen rich overhead;
a once-through kettle column reboiler disposed in the intermediate pressure kettle column and configured to boil a portion of the descending liquid in the intermediate pressure kettle column against a first part of the argon-oxygen side stream to yield an ascending vapor stream in the intermediate pressure kettle column and an argon-oxygen liquid stream that is returned to an intermediate location of the lower pressure column;
a once-through kettle column condenser configured to condense all or a portion of the nitrogen rich overhead of the kettle column against a portion of the oxygen-rich bottoms of the intermediate pressure kettle column; and
an argon column arrangement comprising one or more argon columns and a once-through argon condenser;
wherein at least one of the one or more argon columns is configured to receive a second part of the argon-oxygen side stream from the lower pressure column and yield an argon-rich overhead and an oxygen-rich bottoms that is returned to the intermediate location of the lower pressure column;
wherein the once-through argon condenser is disposed within the lower pressure column at a location above the intermediate location of the lower pressure column and the argon-rich overhead is condensed against a portion of the descending liquid in the lower pressure column and/or a diverted portion of the liquid air stream to produce a crude argon stream; and
wherein the oxygen-rich kettle column bottoms of the intermediate pressure kettle column is not directly returned to the lower pressure column or the argon condenser.

2. The air separation unit of claim 1 , wherein the intermediate pressure kettle column is configured to receive the kettle liquid at an intermediate location of the kettle column several separation stages above a bottom section.

3. The air separation unit of claim 1 , wherein the one or more argon columns further comprise:
a first argon column configured to receive the second part of the argon-oxygen side stream from the lower pressure column and yield the argon-rich overhead and the oxygen-rich bottoms that is directed back to the lower pressure column;
a high ratio column configured to receive a portion of the crude argon stream from the once-through argon condenser and rectify the portion of the crude argon stream to yield an argon-rich liquid and an overhead vapor;
wherein the once-through argon condenser is configured to receive the argon-rich overhead from the first argon column and condense the argon-rich overhead to produce the crude argon stream; and
wherein a portion of the argon-rich liquid at the bottom of the high ratio column is taken as a liquid argon product.

4. The air separation unit of claim 3 , wherein the argon column arrangement further comprises:
a high ratio column reboiler disposed at the bottom of the high ratio column and configured for reboiling another portion of the argon-rich liquid at the bottom of the high ratio column to produce an ascending vapor stream in the high ratio column; and
a high ratio column condenser configured to condense the overhead vapor from the high ratio column against another portion of the oxygen-rich bottoms of the intermediate pressure kettle column and return all or a portion of the condensate as a high ratio column reflux stream.

5. The air separation unit of claim 1 , wherein the source of purified, compressed feed air stream is split into one or more streams of purified, compressed air and the air separation unit further comprises:
a main heat exchanger configured for cooling the one or more streams of purified, compressed air to yield at least a liquid air stream that is directed to the higher pressure column and a turbine air stream;
a turbine configured to expand the turbine air stream to produce an exhaust stream; and
a phase separator configured to separate the exhaust stream into a liquid portion that is added to the kettle liquid and a vapor portion that is directed to the higher pressure column.

6. The air separation unit of claim 5 , further comprising a booster compressor configured to further compress a portion of the one or more purified, compressed feed air streams upstream of the turbine and wherein the further compressed portion of the one or more purified, compressed feed air streams is partially cooled in the main heat exchanger to yield the turbine air stream.

7. The air separation unit of claim 5 , wherein a portion of the nitrogen overhead from the intermediate pressure kettle column is warmed in a nitrogen superheater and in the main heat exchanger to produce an intermediate pressure nitrogen product stream.

8. The air separation unit of claim 1 , wherein the source of purified, compressed feed air stream is split into one or more streams of purified, compressed air, and the air separation unit further comprises:
one or more booster compressors configured to further compress portions of the one or more purified, compressed feed air streams;
a main heat exchanger configured to cool the one or more streams of purified, compressed air to yield at least a liquid air stream that is directed to the higher pressure column, a booster air stream, and a turbine air stream; and
a lower column turbine configured to expand the turbine air stream to produce an exhaust stream that is directed to the higher pressure column.

9. The air separation unit of claim 8 , wherein:
the higher pressure column is further configured to yield a dirty shelf nitrogen stream taken from an intermediate location of the higher pressure column that is directed to the lower pressure column as a dirty shelf reflux stream; and
a portion of the condensed nitrogen rich overhead exiting the once-through kettle column condenser is mixed with the dirty shelf reflux stream and directed to the lower pressure column.

10. The air separation unit of claim 8 , wherein a portion of the nitrogen overhead from the higher pressure column is warmed in the main heat exchanger to produce a higher pressure nitrogen product stream.

11. The air separation unit of claim 8 , wherein the diverted liquid air stream is taken from an intermediate location of the higher pressure column.

12. The air separation unit of claim 1 , wherein the source of purified, compressed feed air stream is split into one or more streams of purified, compressed air, and the air separation unit further comprises:
one or more booster compressors configured to further compress portions of the one or more purified, compressed feed air streams;
a main heat exchanger configure to cooling the

Assignees

• Prosser Neil M
• Praxair Technology Inc

Inventors

• Prosser Neil M

Classifications

• F25J3/0423

  Subcooling of liquid process streams · CPC title

• F25J2200/20

  in an elevated pressure multiple column system wherein the lowest pressure column is at a pressure well above the minimum pressure needed to overcome pressure drop to reject the products to atmosphere · CPC title

• F25J3/0486

  of vaporisers for oxygen enriched liquids, e.g. purging of liquids · CPC title

• F25J3/04727

  using an auxiliary pure argon column for nitrogen rejection (F25J3/04739 takes precedence) · CPC title

• F25J2230/40

  the fluid being air · CPC title