Bijels and methods of making the same

Patent metadata

Field	Value
Publication number	US-12351712-B2
Application number	US-202117534500-A
Country	US
Kind code	B2
Filing date	Nov 24, 2021
Priority date	Jun 1, 2015
Publication date	Jul 8, 2025
Grant date	Jul 8, 2025

Abstract

A method of making a bijel includes dispersing surface-active nanoparticles in a ternary liquid mixture. The ternary liquid mixture includes a hydrophilic liquid, a hydrophobic liquid, and a solvent. The ternary liquid mixture is contacted with water. A bijel includes a stable mixture of two immiscible liquids separated by an interfacial layer of colloidal particles. The bijel has temperature-independent stability, and the domain sizes are below one micrometer.

First claim

What is claimed:

1. A bicontinuous interfacially jammed emulsion that is a bijel having temperature-independent stability, the bijel made according to:
dispersing surface-active nanoparticles into a monophasic ternary liquid mixture to give rise to a loaded mixture, a surface-active nanoparticle having a water-soluble ionic surfactant associated thereon,
wherein the monophasic ternary liquid mixture comprises a hydrophilic liquid, a hydrophobic liquid, and a solvent,
wherein the hydrophilic liquid comprises (i) a liquid that comprises at least one of water, ethylene glycol, and ethane diol, (ii) a polymerizable monomer, or (iii) a combination of the liquid and the polymerizable monomer,
wherein the hydrophobic liquid comprises (i) a liquid that comprises at least one of diethyl phthalate, dimethylphthalate, 1,6-hexanediol diacrylate, 1,6-diacetoxyhexane, trimethylolpropane triacrylate, dipentaerythritol pentaacrylate, triacetin, toluene, chloroform, laurylacrylate, butylacrylate, decanol, styrene, and oleic acid, (ii) a polymerizable monomer, or (iii) a combination of the liquid and the polymerizable monomer,
wherein the solvent comprises at least one of ethanol, acetic acid, methanol, propanol, tetrahydrofuran, dimethyl sulfoxide (DMSO), or acetone, and
wherein the surface-active nanoparticles are equally wettable by both the hydrophilic liquid and the hydrophobic liquid; and
contacting the loaded mixture with water so as to initiate phase separation through spinodal decomposition and induce mass transfer of the solvent and give rise to the bijel.

2. A fiber scaffold for tissue engineering, comprising the bijel of claim 1 .

3. A cosmetic composition, comprising the bijel of claim 1 .

4. A food composition, comprising the bijel of claim 1 .

5. A filter comprising the bijel of claim 1 .

6. A fog harvesting mesh comprising the bijel of claim 1 .

7. A cross-flow reactor comprising the bijel of claim 1 .

8. A bicontinuous interfacially jammed emulsion that is a bijel, comprising:
a stable mixture of two immiscible liquids separated by an interfacial layer of colloidal surface-active nanoparticles equally wettable by the two immiscible liquids, a surface-active nanoparticle of the interfacial layer of colloidal surface-active nanoparticles having a water-soluble ionic surfactant associated thereon,
wherein one of the two immiscible liquids is a hydrophilic liquid and the other of the two immiscible liquids is a hydrophobic liquid,
wherein the hydrophilic liquid comprises (i) a liquid that comprises at least one of water, ethylene glycol, and ethane diol, (ii) a polymerizable monomer, or (iii) a combination of the liquid and the polymerizable monomer,
wherein the hydrophobic liquid comprises (i) a liquid that comprises at least one of diethyl phthalate (DEP), dimethylphthalate, 1,6-hexanediol diacrylate, 1,6-diacetoxyhexane, trimethylolpropane triacrylate, dipentaerythritol pentaacrylate, triacetin, toluene, chloroform, laurylacrylate, butylacrylate, decanol, styrene, and oleic acid, (ii) a polymerizable monomer, or (iii) a combination of the liquid and the polymerizable monomer,
wherein the bijel has temperature-independent stability, and
wherein the bijel has domain sizes of below one micrometer.

9. The bijel of claim 8 , wherein the bijel is a bijel fiber or a bijel membrane.

10. The bijel of claim 8 , wherein the hydrophobic liquid comprises hydrophobic polymerizable monomers, the hydrophobic polymerizable monomers comprising at least one of 1,6-hexanediol diacrylate, butylacrylate, laurylacrylate, styrene, trimethylolpropane triacrylate, or dipentaerythritol pentaacrylate.

11. The bijel of claim 8 , wherein at least one of the hydrophilic liquid and the hydrophobic liquid comprises the polymerizable monomer.

12. The bijel of claim 8 , wherein the domain sizes are between 1 micrometer and 300 nm.

13. The bijel of claim 8 , wherein the domain sizes are between 1 micrometer and 500 nm.

14. The bijel of claim 8 , wherein the hydrophobic liquid comprises diethyl phthalate, dimethylphthalate, 1,6-hexanediol diacrylate, 1,6-diacetoxyhexane, trimethylolpropane triacrylate, dipentaerythritol pentaacrylate, laurylacrylate, butylacrylate, oleic acid, chloroform, styrene, triacetin, decanol, or toluene.

15. The bijel of claim 8 , wherein the hydrophilic liquid is water.

16. The bijel of claim 8 , wherein the bijel further comprises a solvent selected from at least one of ethanol, acetic acid, methanol, propanol, tetrahydrofuran, dimethyl sulfoxide (DMSO) or acetone.

17. The bijel of claim 16 , wherein the solvent comprises ethanol, methanol, or propanol.

18. The bijel of claim 8 , wherein the bijel is in the form of a fiber.

19. The bijel of claim 8 , wherein the bijel is in the form of a membrane.

Assignees

• Univ Pennsylvania

Inventors

• Haase Martin F
• Lee Daeyeon
• Stebe Kathleen J

Classifications

• C08L2205/16

  Fibres; Fibrils · CPC title

• C08L2203/16

  used for films · CPC title

• C08L2203/12

  used for fibers · CPC title

• C08L2203/02

  for biomedical use · CPC title

• C08L2201/54

  Aqueous solutions or dispersions · CPC title