Compositions and methods for plaster-based thermal grout

Patent metadata

Field	Value
Publication number	US-12351518-B2
Application number	US-202318540358-A
Country	US
Kind code	B2
Filing date	Dec 14, 2023
Priority date	Dec 14, 2023
Publication date	Jul 8, 2025
Grant date	Jul 8, 2025

Abstract

A grout composition includes a grout binder comprising calcium sulfate, the grout binder constituting from about 25.0 weight percent to about 99.0 weight percent of the grout composition, and at least one thermal conductivity additive comprising graphite. A grout formed from the grout composition has a thermal conductivity greater than about 1.0 W/m·K. Related grout slurries formed from the grout composition, grouts, and methods of grouting a wellbore are also disclosed.

First claim

What is claimed is:

1. A grout composition, comprising:
a grout binder comprising calcium sulfate, the grout binder constituting from about 25.0 weight percent to about 99.0 weight percent of the grout composition;
at least one thermal conductivity additive comprising graphite; and
at least one retarder comprising borax and ethylenediamine tetra(methylene phosphonic acid), wherein a ratio of borax to ethylenediamine tetra(methylene phosphonic acid) in the at least one retarder is within a range of from about 5.0:1.0 to about 10.0:1.0.

2. The grout composition of claim 1 , wherein the calcium sulfate comprises calcium sulfate hemihydrate.

3. The grout composition of claim 1 , wherein the calcium sulfate constitutes at least about 60.0 weight percent of the grout composition.

4. The grout composition of claim 1 , wherein a weight percent of the graphite in the grout composition is within a range of from about 0.1 weight percent to about 75.0 weight percent.

5. The grout composition of claim 1 , wherein the graphite constitutes greater than about 30.0 weight percent of the grout composition.

6. The grout composition of claim 1 , wherein the grout binder further comprises at least one of bentonite or sand.

7. The grout composition of claim 1 , wherein the grout composition is formulated and configured to, when mixed with water to form a grout, forms a grout exhibiting a modulus of elasticity within a range of from about 2.0 GPa to about 8.0 GPa.

8. The grout composition of claim 1 , wherein a ratio of the calcium sulfate to the graphite is within a range of from about 1.5:1.0 to about 2.5:1.0.

9. A grout slurry composition, comprising:
water;
at least one grout binder comprising at least about 50 weight percent calcium sulfate;
at least one thermal conductivity additive comprising graphite, wherein the grout slurry composition has a density within a range of from about 1,050 kg/m 3 to about 1,450 kg/m 3 and a viscosity within a range of from about 10 cP to about 1,000 cP at about 25° C.; and
at least one retarder comprising borax and ethylenediamine tetra(methylene phosphonic acid), wherein the at least one retarder is within a range of from about 0.01 weight percent to about 4.0 weight percent based on the grout slurry composition not including the water.

10. The grout slurry of claim 9 , wherein a density of the grout slurry is within a range of from about 1,375 kg/m 3 to about 1,440 kg/m 3 .

11. The grout slurry of claim 9 , wherein a thermal conductivity of a grout formed from the grout slurry is within a range of from about 1.73 W/m·K (about 1.0 BTU/hr·ft·° F.) to about 5.19 W/m·K (about 3.0 BTU/hr·ft·° F.).

12. The grout slurry of claim 9 , wherein a weight percent of the graphite not including the water is within a range of from about 10.0 weight percent to about 20.0 weight percent.

13. The grout slurry of claim 9 , wherein the calcium sulfate comprises calcium sulfate hemihydrate.

14. A method of grouting a shallow geothermal wellbore, the method comprising:
pumping a grout slurry in a wellbore extending through an earth formation between surfaces of the earth formation defining the wellbore and a thermal transfer pipe, the grout slurry having a density within a range of from about 1,050 kg/m 3 to about 1,450 kg/m 3 and comprising:
water;
at least about 25.0 weight percent calcium sulfate hemihydrate based on the grout slurry composition not including the water; and
at least about 10.0 weight percent graphite based on the grout slurry composition not including the water;
at least one retarder comprising borax and ethylenediamine tetra(methylene phosphonic acid), wherein a ratio of borax to ethylenediamine tetra(methylene phosphonic acid) in the at least one retarder is within a range of from about 5.0:1.0 to about 10.0:1.0; and

setting the grout slurry to form a grout having a thermal conductivity within a range of from about 1.0 W/m·K to about 10.0 W/m·K.

15. The method of claim 14 , wherein pumping a grout slurry in a wellbore comprises pumping a grout slurry comprising at least about 70.0 weight percent based on the grout slurry composition not including the water calcium sulfate hemihydrate in the wellbore.

Assignees

• Schlumberger Technology Corp

Inventors

• Torres Hortencia
• Droger Nicolas
• Meade Mark
• Parton Christopher
• Kuravskiy Dmitry

Classifications

• C04B2111/70

  Grouts, e.g. injection mixtures for cables for prestressed concrete · CPC title

• C04B28/145

  Calcium sulfate hemi-hydrate with a specific crystal form · CPC title

• C04B2201/20

  for the density · CPC title

• C04B2201/32

  for the thermal conductivity, e.g. K-factors · CPC title

• C04B2201/10

  for the viscosity · CPC title