System for producing magnesium chloride aqueous solution and system for producing magnesium

Patent metadata

Field	Value
Publication number	US-12351475-B2
Application number	US-202017790639-A
Country	US
Kind code	B2
Filing date	Dec 14, 2020
Priority date	Jan 8, 2020
Publication date	Jul 8, 2025
Grant date	Jul 8, 2025

Abstract

A system for producing a magnesium chloride aqueous solution includes a crystallization unit configured to generate reaction slurry in which particles of magnesium hydroxide are dispersed by adding a sodium hydroxide aqueous solution to water to be treated, a precipitation unit configured to store reaction slurry, precipitate particles and separate the reaction slurry into recovered slurry and a separated liquid, a removal unit configured to remove divalent cations from the water to be treated or the separated liquid to generate a reaction liquid, an acid-alkali generation unit configured to generate a sodium hydroxide aqueous solution and hydrochloric acid from the reaction liquid, and a reaction unit configured to generate a magnesium chloride aqueous solution by adding hydrochloric acid to the recovered slurry. The acid-alkali generation unit has a main body section configured to generate a sodium hydroxide aqueous solution and hydrochloric acid from the reaction liquid.

First claim

The invention claimed is:

1. A system for producing a magnesium chloride aqueous solution comprising:
a crystallization unit;
a precipitation unit connected to the crystallization unit;
a removal unit connected to the precipitation unit;
an acid-alkali generation unit connected to the removal unit; and
a reaction unit connected to the precipitation unit,
wherein the crystallization unit crystallizes magnesium hydroxide by adding a sodium hydroxide aqueous solution to water to be treated using seawater as a raw material, and generates reaction slurry in which particles of the magnesium hydroxide are dispersed,
the precipitation unit stores the reaction slurry to precipitate the particles, and separates the reaction slurry into a recovered slurry containing the particles at a high concentration and a separated liquid containing the particles at a low concentration,
the removal unit removes divalent cations from the water to be treated or the separated liquid to generate a reaction liquid,
the acid-alkali generation unit generates a sodium hydroxide aqueous solution and hydrochloric acid from the reaction liquid,
the reaction unit adds the hydrochloric acid to the recovered slurry and generates a magnesium chloride aqueous solution, and
the acid-alkali generation unit has:
a main body section configured to generate a sodium hydroxide aqueous solution and hydrochloric acid from the reaction liquid;
a first connection unit configured to connect the main body section and the crystallization unit and supply the sodium hydroxide aqueous solution to the crystallization unit; and
a second connection unit configured to connect the main body section and the reaction unit and supply the hydrochloric acid to the reaction unit.

2. The system for producing a magnesium chloride aqueous solution according to claim 1 , wherein a pre-processing unit connected to the crystallization unit upstream from the crystallization unit is provided, and
the pre-processing unit has a separating unit configured to separate pure water from the water to be treated.

3. The system for producing a magnesium chloride aqueous solution according to claim 2 , further comprising:
a mixing unit provided along a route through which the reaction liquid is supplied from the removal unit to the acid-alkali generation unit and configured to mix at least some of the pure water with the reaction liquid; and
a first supply pipe configured to supply the pure water from the separating unit to the mixing unit.

4. The system for producing a magnesium chloride aqueous solution according to claim 1 , wherein a pre-processing unit connected to the crystallization unit upstream from the crystallization unit is provided,
the pre-processing unit has a decarbonizing unit configured to add hydrochloric acid to the water to be treated and remove at least some carbonic acid contained in the water to be treated, and
the acid-alkali generation unit has a third connection unit configured to connect the main body section and the decarbonizing unit and supply the hydrochloric acid to the decarbonizing unit.

5. A system for producing magnesium comprising:
the system for producing a magnesium chloride aqueous solution according to claim 1 ;
a generation unit configured to separate water from the magnesium chloride aqueous solution to generate magnesium chloride; and
an electrolysis unit configured to perform molten salt electrolysis of the magnesium chloride to obtain metal magnesium.

6. The system for producing magnesium according to claim 5 , further comprising:
a mixing unit provided along a route through which the reaction liquid is supplied from the removal unit to the acid-alkali generation unit and configured to mix at least some water separated by the generation unit with the reaction liquid; and
a second supply pipe configured to supply the water separated by the generation unit from the generation unit to the mixing unit.

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Ito Yoshiaki
• Takeuchi Kazuhisa
• Kiyosawa Masashi

Classifications

• C25C3/04 Primary

  of magnesium · CPC title

• C01F5/32

  Preparation of anhydrous magnesium chloride by chlorinating magnesium compounds · CPC title

• C01F11/46

  Sulfates (dehydration of gypsum {for the production of calcium sulfate cements} C04B11/02) · CPC title

• Y02P10/20

  Recycling · CPC title

• C22B3/10

  Hydrochloric acid {, other halogenated acids or salts thereof} · CPC title