Method for Producing Positive Electrode Active Material for Lithium Secondary Battery and Positive Electrode Active Material for Lithium Secondary Battery Produced Thereby
US-2023074059-A1 · Mar 9, 2023 · US
US12347867B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12347867-B2 |
| Application number | US-202217945642-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 15, 2022 |
| Priority date | Sep 22, 2021 |
| Publication date | Jul 1, 2025 |
| Grant date | Jul 1, 2025 |
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Disclosed is a method in which both the suppression of granulation of an active material and the acceleration of production steps are achieved when producing an electrode mixture containing a coated active material. The method comprises dropletizing a slurry containing an active material and a coating liquid to obtain slurry droplets, gas-flow drying the slurry droplets in a heating gas to obtain a first and a second precursor, and firing the first and the second precursor to obtain a first and second particle, wherein the first precursor contains the active material and a component from the coating liquid, the second precursor is free of the active material and contains a component from the coating liquid, the first particle has the active material and a coating layer, and the second particle is free of the active material and contains a component same as that constituting the coating layer.
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The invention claimed is: 1. A method for producing an electrode mixture, comprising: dropletizing a slurry containing an active material and a coating liquid to obtain slurry droplets; gas-flow drying the slurry droplets in a heating gas to obtain a first precursor and a second precursor; and firing the first precursor and the second precursor to obtain a first particle and a second particle, wherein the first precursor contains the active material and a component from the coating liquid, the second precursor is free of the active material and contains a component from the coating liquid, the first particle has the active material and a coating layer covering at least a portion of a surface of the active material, and the second particle is free of the active material and contains a component same as that constituting the coating layer. 2. The method according to claim 1 , wherein the heating gas has a temperature of 250° C. or higher. 3. The method according to claim 1 , wherein the slurry droplets are obtained by spraying the slurry. 4. The method according to claim 1 , wherein the coating liquid contains at least a lithium source and a niobium source. 5. The method according to claim 4 , wherein the coating liquid contains a niobium peroxo complex as the niobium source. 6. The method according to claim 1 , comprising mixing at least the first particle, the second particle, and a solid electrolyte.
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