Propylene polymer composition and shaped article

Patent metadata

Field	Value
Publication number	US-12344731-B2
Application number	US-202017632467-A
Country	US
Kind code	B2
Filing date	Aug 7, 2020
Priority date	Aug 8, 2019
Publication date	Jul 1, 2025
Grant date	Jul 1, 2025

Abstract

A propylene polymer composition includes a propylene homopolymer (A) having an intrinsic viscosity [η] measured in a tetralin solvent at 135° C. in the range of 7 to 12 dl/g, a propylene polymer (B) having an intrinsic viscosity [η] in the range of not less than 0.21 dl/g and less than 0.54 dl/g, and having a proportion of a component eluted at a temperature of not more than −20° C. in TREF in the range of not more than 3.5 mass %, and a propylene polymer (C) having an intrinsic viscosity [η] in the range of not less than 0.54 dl/g and less than 2.6 dl/g, wherein the content of (A) is 0.5 to 47.5 mass %, the content of (B) is 5 to 95 mass % and the content of (C) is 2.5 to 85.5 mass %, based on the total of (A), (B) and (C).

First claim

The invention claimed is:

1. A propylene polymer composition comprising:
a propylene homopolymer (A) having an intrinsic viscosity [η] measured in a tetralin solvent at 135° C. in the range of 7 to 12 dl/g;
a propylene polymer (B) having an intrinsic viscosity [η] measured in a tetralin solvent at 135° C. in the range of not less than 0.21 dl/g and less than 0.54 dl/g, and having a proportion of a component eluted at a temperature of not more than −20° C. in temperature rising elution fractionation (TREF) in the range of not more than 3.5 mass %; and
a propylene polymer (C) having an intrinsic viscosity [η] measured in a tetralin solvent at 135° C. in the range of not less than 0.54 dl/g and less than 2.6 dl/g; wherein
the content of the propylene homopolymer (A) is 0.5 to 47.5 mass %, the content of the propylene polymer (B) is 5 to 95 mass % and the content of the propylene polymer (C) is 2.5 to 85.5 mass %, based on the total of the propylene homopolymer (A), the propylene polymer (B) and the propylene polymer (C),
wherein the propylene polymer (C) is selected from the group consisting of homopolymers of propylene, and copolymers of propylene and a C2-C20 α-olefin (except propylene), and
wherein in the copolymer, the content of propylene-derived structural units is more than 90 mol % and less than 100 mol %, and the content of C2-C20 α-olefin (except propylene)-derived structural units is more than 0 mol % and less than 10 mol % to the total of the number of propylene-derived structural units and the number of C2-C20 α-olefin-derived structural units.

2. The propylene polymer composition according to claim 1 , further comprising an ethylene random copolymer (D) and/or an inorganic filler (E), wherein
the content of the ethylene random copolymer (D) is 0 to 40 mass % and the content of the inorganic filler (E) is 0 to 50 mass %, based on the total of the propylene homopolymer (A), the propylene polymer (B), the propylene polymer (C), the ethylene random copolymer (D) and the inorganic filler (E), provided that the content of at least one of the ethylene random copolymer (D) and the inorganic filler (E) is more than 0 mass %.

3. The propylene polymer composition according to claim 1 , wherein the propylene polymer (B) has a meso pentad fraction (mmmm) determined by 13 C-NMR of 90.0 to 100%.

4. The propylene polymer composition according to claim 1 , wherein the propylene polymer (B) has a melting point (Tm) measured with a differential scanning calorimeter (DSC) of not less than 140° C.

5. The propylene polymer composition according to claim 1 , wherein the propylene polymer (B) has a total proportion of irregular bonds stemming from 2,1-insertion and 1,3-insertion in all propylene units determined by 13 C-NMR in the range of not more than 0.3 mol %.

6. The propylene polymer composition according to claim 1 , wherein the content of propylene-derived structural units in the propylene polymer (B) is not less than 98 mol %.

7. A shaped article comprising the propylene polymer composition described in claim 1 .

Assignees

• Prime Polymer Co Ltd
• Mitsui Chemicals Inc

Inventors

• HIROI Ryoko
• Itakura Keita
• NAITO Shino
• FURUTA Takanori
• Tsurugi Kou

Classifications

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/14

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title

• B29K2023/14

  Copolymers of polypropylene (B29K2023/16 takes precedence) · CPC title