Method for producing a catalyst system for gas reactions

Patent metadata

Field	Value
Publication number	US-12343795-B2
Application number	US-202017754971-A
Country	US
Kind code	B2
Filing date	Aug 31, 2020
Priority date	Oct 21, 2019
Publication date	Jul 1, 2025
Grant date	Jul 1, 2025

Abstract

A method for producing a catalyst system for gas reactions comprising at least one planar structure of noble metal having gas-permeable openings, comprising the steps of:
(1) providing at least one noble metal powder consisting of at least substantially spherical noble metal particles, and
(2) repeatedly applying the noble metal powder or powders provided in step (1) in layers to a substrate in a build chamber, respectively followed by an at least partial melting of the respective noble metal powder applied as a layer with high-energy radiation, and allowing the melted noble metal powder to solidify within the scope of additive manufacturing.

First claim

The invention claimed is:

1. A method for producing a catalyst system for gas reactions comprising at least one planar structure of noble metal having gas-permeable openings, comprising the steps of:
(1) providing at least one noble metal powder consisting of metal particles, wherein at least 80% of the noble metal particles, relative to their number, satisfy the condition 0.8≤d min /d max ≤1.0, wherein d min is the minimum diameter and d max is the maximum diameter of an individual noble metal particle, and
(2) repeatedly applying the noble metal powder or powders provided in step (1) in layers to a substrate in a build chamber, respectively followed by an at least partial melting of the respective noble metal powder applied as a layer with radiation in the form of a laser or electron beam, and allowing the melted noble metal powder to solidify as part of an additive manufacturing process,
wherein the at least one planar structure of noble metal comprising gas-permeable openings has an individual weight per unit area in the range of 25 to 2500 g/m 2 ,
wherein the noble metal particles of the noble metal powder or powders have a particle size distribution with a d 10 value of ≥5 μm and a d 90 value of ≤80 μm,
wherein the noble metal of the noble metal particles of the noble metal powder or powders is selected from the group consisting of noble metal alloys of
platinum with 1-15 wt. % rhodium,
platinum with 2-15 wt. % rhodium and 0.1-20 wt. % palladium,
platinum with 2-15 wt. % rhodium, 0.1-20 wt. % palladium, and 0.1-2 wt. % ruthenium,
platinum with 2-15 wt. % rhodium, 0.1-20 wt. % palladium, and 0.1-5 wt. % iridium,
palladium with 1-20 wt. % platinum and 1-10 wt. % rhodium,
palladium with 1-25 wt. % tungsten, and
palladium with 1-15 wt. % nickel, and
wherein the at least one planar structure of noble metal is a planar object selected from the group consisting of grids, perforated plates, screens, and nets.

2. The method of claim 1 , wherein the noble metal particles are produced by an atomization process.

3. The method of claim 1 , wherein the d 50 value of the particle size distribution is in the range from 20 to 30 μm.

4. The method of claim 1 , wherein the d 10 value is ≥10 μm and the d 90 value is ≤45 μm.

5. The method according to Claim of claim 4 , wherein the d 10 value is in the range of ≥10 μm to ≤20 μm, and the d 90 value is in the range of ≥30 μm to ≤45 μm.

6. The method of claim 1 , wherein the catalyst system comprises or consists of one planar structure of noble metal, a plurality of identical planar structures of noble metal, or a plurality of different planar structures of noble metal, and wherein the one planar structure of noble metal, the plurality of identical planar structures of noble metal, or the plurality of different planar structures of noble metal constitute a complete catalyst system for gas reactions or a catalyst subsystem in the sense of a part of a complete catalyst system for gas reactions.

7. The method of claim 1 , wherein the at least one planar structure of noble metal has a surface area in the range of 0.25 to 35 square meters.

8. The method of claim 1 , wherein the net or nets at least one planar structure of noble metal is a net with a structure akin to a woven fabric, a weft knitted fabric, or a warp knitted fabric.

9. The method of claim 8 , wherein the structure of the net is as if it were based on round wire and/or on wire with a cross-sectional shape other than round.

10. The method of claim 9 , wherein, independently of the cross-sectional shape, the wire cross-sectional area ranges from 400 to 22500 μm 2 .

11. The method of claim 1 , wherein the selection of digital 3D design data within the context of additive manufacturing influences surface roughness, porosity, and/or solidity of the noble metal material of the noble metal planar structure.

12. A method for producing a catalyst system for gas reactions comprising at least one planar structure of noble metal having gas-permeable openings, comprising the steps of:
(1) providing at least one noble metal powder consisting of metal particles, wherein at least 80% of the noble metal particles, relative to their number, satisfy the condition 0.8 23 d min /d max ≤1.0, wherein d min is the minimum diameter and d max is the maximum diameter of an individual noble metal particle, and
(2) repeatedly applying the noble metal powder or powders provided in step (1) in layers to a substrate in a build chamber, respectively followed by an at least partial melting of the respective noble metal powder applied as a layer with radiation in the form of a laser or electron beam, and allowing the melted noble metal powder to solidify as part of an additive manufacturing process,
wherein the at least one planar structure of noble metal comprising gas-permeable openings has an individual weight per unit area in the range of 25 to 2500 g/m 2 ,
wherein the noble metal particles of the noble metal powder or powders have a particle size distribution with a d 10 value of ≥5 μm, a d 50 value in the range of 20 to 30 μm, and a d 90 value of ≤80 μm,
and wherein the noble metal of the noble metal particles of the noble metal powder or powders is selected from the group consisting of noble metal alloys of
platinum with 1-15 wt. % rhodium,
platinum with 2-15 wt. % rhodium and 0.1-20 wt. % palladium,
platinum with 2-15 wt. % rhodium, 0.1-20 wt. % palladium, and 0.1-2 wt. % ruthenium,
platinum with 2-15 wt. % rhodium, 0.1-20 wt. % palladium, and 0.1-5 wt. % iridium, palladium with 3-15 wt. % platinum,
palladium with 1-20 wt. % platinum and 1-10 wt. % rhodium,
palladium with 1-25 wt. % tungsten, and
palladium with 1-15 wt. % nickel.

13. The method of claim 12 , wherein the noble metal particles are produced by an atomization process.

14. The method of claim 12 , wherein the d 10 value is ≥10 μm and the d 90 value is ≤45 μm.

15. The method of claim 14 , wherein the d 10 value is in the range of ≥10 μm to ≤20 μm, and the d 90 value is in the range of ≥30 μm to ≤45 μm.

16. The method of claim 12 , wherein the catalyst system comprises or consists of one planar structure of noble metal, a plurality of identical planar structures of noble metal, or a plurality of different planar structures of noble metal, and wherein the one planar structure of noble metal, the plurality of identical planar structures of noble metal, or the plurality of different planar structures of noble metal constitute a complete catalyst system for gas reactions or a catalyst subsystem in the sense of a part of a complete catalyst system for gas reactions.

17. The method of claim 12 , wherein the at least one planar structure of noble metal is a planar object selected from the group consisting of grids, perforated plates, screens, and nets.

18. The method of claim 12 , wherein the at least one planar structure of noble metal has a surface area in the range of 0.25 to 35 square meters.

19. The method of claim 12 , wherein the selection of digital 3D design data within the context of additive manufacturing influences surface roughness, porosity, and/or solidity of the noble metal material of the noble metal planar structure.

20. The method of claim 12 , wherein the noble metal particles of the noble metal powder or powders have a d 50 value in the range of 20 to 30 μm.

21. A method for producing a catalyst system for gas reactions comprising at least one planar structure of noble metal having gas-permeable openings, comprisi

Assignees

• Heraeus Deutschland Gmbh & Co Kg

Inventors

• Boll Willi
• Humm Stephan
• Hubert Peter
• Hirschel Pascal

Classifications

• B01J35/612

  less than 10 m2/g · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J35/58

  Fabrics or filaments · CPC title

• B22F10/60

  Treatment of workpieces or articles after build-up · CPC title

• B22F12/41

  characterised by the type, e.g. laser or electron beam · CPC title