Method for applying a coating composition to a substrate

Patent metadata

Field	Value
Publication number	US-12338364-B2
Application number	US-202218860253-A
Country	US
Kind code	B2
Filing date	May 20, 2022
Priority date	May 20, 2022
Publication date	Jun 24, 2025
Grant date	Jun 24, 2025

Abstract

The present invention relates to a method comprising the steps of a) applying a 0.1-mm to 2-mm thick layer of a pigmented coating composition onto a cement, concrete, or asphalt substrate, and b) allowing the coating to composition to dry. The method of the present invention is useful for preparing a traffic paint with improved color retention and durability.

First claim

The invention claimed is:

1. A method comprising the steps of a) applying a 0.1-mm to 2-mm thick layer of a pigmented coating composition onto a cement, concrete, or asphalt substrate, and b) allowing the coating composition to dry;
wherein the pigmented coating composition comprises an aqueous dispersion of 1) first polymer particles having a calculated T g in the range of from −25° C. to 50° C.; 2) second polymer particles having a calculated T g in the range of from 30° C. to 110° C.; 3) extender particles; 4) pigment particles; and 5) a base which is ammonia or a volatile amine or a salt thereof;
with the proviso that the second polymer particles have a T g of at least 20° C. higher than the first polymer particles, wherein, based on the weight of the composition:
the first and second polymer particles together have a solids content in the range of from 10 to 20 weight percent;
the extender particles have a solids content in the range of from 45 to 70 weight percent;
the pigment particles have a solids content in the range of from 3 to 15 weight percent; and
the composition has a total solids content in the range of from 60 to 85 weight percent;
wherein the w/w ratio of the first polymer particles to the second polymer particles is in the range of from 30:70 to 90:10;
wherein the first and second polymer particles consist of acrylic or styrene-acrylic polymer particles.

2. The method of claim 1 wherein the pigment is TiO 2 ; the first polymer particles have T g in the range of from −15° C. to 30° C. and the second polymer particles have a T g in the range of from 50° C. to 110° C.

3. The method of claim 2 wherein the pigmented coating composition further comprises from 0.01 to 2 weight percent, based on the weight of the composition, of a polyamine; wherein the weight-to-weight ratio of first polymer particles to the second polymer particles is in the range of from 50:50 to 90:10.

4. The method of claim 3 wherein the composition has a pigment volume concentration (PVC) is the range of from 60 to 90.

5. The method of claim 4 wherein the base is ammonia, 2-amino-2-methyl-1-propanol, dimethylaminoethanol, or monoisopropanol amine; wherein the polyamine is poly(oxazolidinoethyl methacrylate); and wherein the composition has a pH in the range of from 8.5 to 12.

6. The method of claim 4 wherein the composition has a PVC is in the range of from 65 to 85.

7. The method of claim 6 wherein the composition further comprises a surfactant, a defoamer, a dispersant, and a rheology modifier.

8. The method of claim 1 wherein the composition further comprises one or more additional materials selected from the group consisting of surfactants, defoamers, dispersants, coalescents, rheology modifiers, and solvents.

9. The method of claim 1 wherein the composition comprises a coalescent at a high enough concentration to promote film formation of the first polymer particles at ambient temperature, but low enough so as not to promote film formation of the second polymer particles at ambient temperature.

10. The method of claim 1 which further comprises, before step b), the drop-on addition to the substrate of glass beads, sand, quartz, Al 2 O 3 , or bauxite, or a combination thereof.

11. A method comprising the steps of a) applying a 0.1-mm to 2-mm thick layer of a pigmented coating composition onto a cement, concrete, or asphalt substrate, and b) allowing the coating composition to dry;
wherein the pigmented coating composition comprises an aqueous dispersion of 1) first polymer particles having a calculated T g in the range of from −25° C. to 50° C.; 2) second polymer particles having a calculated T g in the range of from 30° C. to 110° C.; 3) extender particles; 4) pigment particles; and 5) a base which is ammonia or a volatile amine or a salt thereof;
with the proviso that the second polymer particles have a T g of at least 20 C° higher than the first polymer particles, wherein, based on the weight of the composition:
the first and second polymer particles together have a solids content in the range of from 10 to 20 weight percent;
the extender particles have a solids content in the range of from 45 to 70 weight percent;
the pigment particles have a solids content in the range of from 3 to 15 weight percent;
the composition has a total solids content in the range of from 60 to 85 weight percent; and
wherein the w/w ratio of the first polymer particles to the second polymer particles is in the range of from 30:70 to 90:10; and
wherein the first polymer particles are film-forming, and the second polymer particles are not film-forming.

12. The method of claim 11 wherein the first and second polymer particles are acrylic or styrene-acrylic polymer particles; the pigment is TiO 2 ; the first polymer particles have T g in the range of from −15° C. to 30° C. and the second polymer particles have a T g in the range of from 50° C. to 110° C.

13. The method of claim 12 wherein the pigmented coating composition further comprises from 0.01 to 2 weight percent, based on the weight of the composition, of a polyamine; wherein the weight-to-weight ratio of first polymer particles to the second polymer particles is in the range of from 50:50 to 70:30; and wherein the first and second polymer particles are acrylic polymer particles.

14. The method of claim 13 wherein the acrylic polymer particles consist of structural units of methyl methacrylate and one or more monomers selected from the group consisting of methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate, 2-propylheptyl acrylate, methacrylic acid and a salt thereof, acrylic acid and a salt thereof, itaconic acid and a salt thereof, sulfoethyl methacrylate and a salt thereof, sulfopropyl methacrylate and a salt thereof, styrene sulfonic acid and a salt thereof, vinyl sulfonic acid and a salt thereof, 2-acrylamido-2-methyl propanesulfonic acid and a salt thereof; and 2-phosphoethyl methacrylate and a salt thereof.

15. The method of claim 14 wherein the composition has a pigment volume concentration (PVC) is the range of from 65 to 85.

16. The method of claim 11 wherein the composition further comprises a surfactant, a defoamer, a dispersant, and a rheology modifier.

17. The method of claim 16 wherein the composition comprises a coalescent at a high enough concentration to promote film formation of the first polymer particles at ambient temperature.

Assignees

• Rohm & Haas
• Dow Global Technologies Llc

Inventors

• Greyson Eric C
• Gallagher Joy A
• Cooper Richard

Classifications

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• C09D133/064

  containing anhydride, COOH or COOM groups, with M being metal or onium-cation · CPC title

• C09D5/028

  Pigments; Filters · CPC title

• C09D5/004

  Reflecting paints; Signal paints · CPC title

• C09D7/61

  inorganic · CPC title