Polymeric material, production method therefor, and polymeric material composition

Patent metadata

Field	Value
Publication number	US-12338327-B2
Application number	US-202017636279-A
Country	US
Kind code	B2
Filing date	Aug 28, 2020
Priority date	Aug 30, 2019
Publication date	Jun 24, 2025
Grant date	Jun 24, 2025

Abstract

The present invention aims to provide a polymeric material having reduced coloration in the visible light region, a high refractive index, and low optical dispersion. The present invention relates to a polymeric material having a sulfoxide structure in a main chain.

First claim

The invention claimed is:

1. An optical material comprising:
a polymer that comprises a sulfoxide structure in a main chain, and a substituted aromatic ring structure in the main chain,
wherein the main chain of the polymer comprises a constituent unit (A) represented by the following formula (1):

wherein A 1 is a substituted divalent aromatic hydrocarbon group that is selected from the group consisting of a phenylene group, a naphthylene group, an anthrylene group, a biphenylene group, and a triphenylene group, and
wherein a substituent of the substituted divalent aromatic hydrocarbon group is selected from the group consisting of a halogen atom, a hydroxy group, an optionally substituted C1-C18 alkyl group, an optionally substituted C1-C18 alkoxy group, an optionally substituted aryl group, an optionally substituted aralkyl group, and an optionally substituted sulfur-containing substituent and wherein the optical material has an Abbe number in the range of 10 or greater and an Abbe number in the range of 60 or less.

2. The optical material according to claim 1 ,
wherein the constituent unit (A) represented by the formula (1) is a constituent unit represented by the following formula (1-1):

wherein each R is the same as or different from each other and is a halogen atom, a hydroxy group, an optionally substituted C1-C18 alkyl group, an optionally substituted C1-C18 alkoxy group, an optionally substituted aryl group, an optionally substituted aralkyl group, or an optionally substituted sulfur-containing substituent; and n represents a number of Rs and is an integer of 1 to 4.

3. The optical material according to claim 1 ,
wherein the optical material has an elemental ratio of oxygen atoms O to sulfur atoms S (O/S) in a range of 0.1 to 1.5.

4. The optical material according to claim 1 ,
wherein the optical material has a glass transition temperature in a range of 80° C. to 250° C.

5. The optical material according to claim 1 ,
wherein the optical material is a thermoplastic polymeric material.

6. An optical material composition comprising:
the optical material according to claim 1 ; and
a metal oxide.

7. The optical material composition of claim 6 , wherein the metal oxide is at least one selected from the group consisting of a titanium oxide, a silicon dioxide, a zirconium oxide, an aluminum oxide, a magnesium oxide, a perovskite-type oxide, a boron nitride, an aluminum hydroxide, and an aluminum titanate.

8. The optical material composition of claim 6 , wherein the metal oxide has an average particle size in a range of 1 nm to 50 nm.

9. A method of producing the optical material according to claim 1 , comprising:
polymerizing a monomer component comprising a sulfur-containing monomer to obtain a sulfur-containing polymer; and
oxidizing the sulfur-containing polymer using an oxidant,
the oxidant comprising at least one selected from the group consisting of a peroxide and a chloric acid.

10. The optical material according to claim 1 , wherein a proportion of the constituent unit (A) represented by the formula (1) based on 100% by mass of all constituents of the polymer is in a range of 1 to 80% by mass.

Assignees

• Nippon Catalytic Chem Ind

Inventors

• Oyaizu Kenichi
• Hirai Motoyasu
• Sun Yushun
• Matsushima Kanta
• Nakamura Jun-Ichi
• Kawase Takeo
• Fujibayashi Teruhisa

Classifications

• C08K2003/2244

  of zirconium · CPC title

• C08K3/22

  of metals · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title

• C08L81/08

  Polysulfonates · CPC title

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title