Method for preparing polyamide by anion ring-opening polymerization and polyamide prepared thereby

Patent metadata

Field	Value
Publication number	US-12338323-B2
Application number	US-201816762725-A
Country	US
Kind code	B2
Filing date	Nov 5, 2018
Priority date	Nov 8, 2017
Publication date	Jun 24, 2025
Grant date	Jun 24, 2025

Abstract

Provided is a method for preparing a polyamide by an anionic polymerization reaction, wherein lactam, and based on 100 parts by weight of the entire lactam, 0.01 parts by weight to 20 parts by weight of an alkali metal as an initiator, 0.3 parts by weight to 10 parts by weight of a molecular weight controller, and 0.002 parts by weight to 1.0 part by weight of carbon dioxide as an activator may be included.

First claim

The invention claimed is:

1. A method for preparing a polyamide by an anionic polymerization reaction, said method comprising:
subjecting a lactam compound to an anionic ring-opening polymerization to prepare the polyamide, in the presence of, based on 100 parts by weight of a total weight of the lactam compound, 0.01 parts by weight to 20 parts by weight of an alkali metal as an initiator, 0.3 parts by weight to 10 parts by weight of a molecular weight controller, and 0.002 parts by weight to 1.0 part by weight of carbon dioxide as an activator,
wherein the molecular weight controller comprises one or more selected from the group consisting of a urea compound, and a di-urea compound,
wherein the polyamide has a polydispersity index (PDI) of 2.5 or less, and
wherein the anionic polymerization reaction is carried out in the absence of a solvent.

2. The method of claim 1 , wherein the lactam compound comprises one or more selected from the group consisting of caprolactam, laurolactam, pyrrolidone, and piperidinone.

3. The method of claim 2 , wherein the lactam compound comprises two different lactams, and an amount of at least one of the two different lactams is 50 parts by weight or more based on 100 parts by weight of the total weight of the lactam compound.

4. The method of claim 1 , wherein the alkali metal comprises one or more selected from the group consisting of a metal hydride, a metal hydroxide, and a metal alkoxide.

5. The method of claim 1 , wherein the anionic ring-opening polymerization reaction is performed within a range of 0.5 minutes to 120 minutes.

6. The method of claim 1 , wherein the lactam compound in the anionic ring-opening polymerization reaction has a conversion rate of 95% or more to the polyamide.

7. The method of claim 1 , wherein a polymerization temperature in the anionic ring-opening polymerization reaction is in a range of 180° C. to 300° C.

8. The method of claim 1 , wherein the polyamide has a weight average molecular weight (Mw) ranging from 20,000 to 100,000.

9. The method of claim 1 , wherein the polyamide has a linear, branched, hyperbranched, or dendritic structure.

10. The method of claim 1 , wherein the anionic ring-opening polymerization reaction is performed within a range of 0.5 minutes to 30 minutes.

11. The method of claim 1 , wherein the polyamide has a weight average molecular weight (Mw) ranging from 40,000 to 100,000.

12. The method of claim 1 , wherein the polyamide has a weight average molecular weight (Mw) ranging from 73,000 to 100,000.

Assignees

• Hanwha Solutions Corp

Inventors

• Do Seung Hoe
• Lee Jin Seo
• Kwon Kyung Ho
• Kim Do Kyoung
• Lee Hye Yeon
• Yim Kyoung Won

Classifications

• C08K5/20

  Carboxylic acid amides · CPC title

• C08K3/20

  Oxides; Hydroxides {(graphene oxides C08K3/042)} · CPC title

• C08K3/12

  Hydrides · CPC title

• C08J5/00

  Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00) · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title