Cyclic olefin-based copolymer, cyclic olefin-based copolymer composition, molded article, and medical container
US-2020369812-A1 · Nov 26, 2020 · US
US12338306B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12338306-B2 |
| Application number | US-202017789443-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 14, 2020 |
| Priority date | Jan 22, 2020 |
| Publication date | Jun 24, 2025 |
| Grant date | Jun 24, 2025 |
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Provided is an optical component including a cyclic olefin-based copolymer (A), in which the cyclic olefin-based copolymer (A) has a constitutional unit (a) derived from at least one olefin represented by the following general formula (I), a constitutional unit (b) derived from at least one cyclic olefin represented by the following general formula (II), and a constitutional unit (c) derived from at least one cyclic olefin represented by the following general formula (III), and the content of the constitutional unit (a) is equal to or less than 50 mol % in a case where the total content of the constitutional unit (a), the constitutional unit (b), and the constitutional unit (c) is taken as 100 mol %.
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The invention claimed is: 1. An optical component comprising: a cyclic olefin-based copolymer (A), wherein the cyclic olefin-based copolymer (A) has a constitutional unit (a) derived from at least one olefin represented by the following general formula (I), a constitutional unit (b) derived from at least one cyclic olefin represented by the following general formula (II), and a constitutional unit (c) derived from at least one cyclic olefin represented by the following general formula (III), and a content of the constitutional unit (a) is equal to or less than 50 mol % in a case where a total content of the constitutional unit (a), the constitutional unit (b), and the constitutional unit (c) is taken as 100 mol %, and wherein a glass transition point (Tg) of the cyclic olefin-based copolymer (A) measured by DSC is equal to or higher than 140° C., in the general formula (I), R 300 represents a hydrogen atom or a linear or branched hydrocarbon group having 1 to 29 carbon atoms in the general formula (II), R 1 to R 8 are each independently a hydrogen atom, a halogen atom, or a hydrocarbon group having equal to or less than 4 carbon atoms, R 5 to R 8 may be bonded to each other to form a monocyclic ring, the monocyclic ring may have a double bond, and R 5 and R 6 or R 7 and R 8 may form an alkylidene group in the general formula (III), n is 0 or 1, m is 0 or a positive integer, n+m is a positive integer, q is 0 or 1, R 1 to R 18 and R a and R b are each independently a hydrogen atom, a halogen atom, or a hydrocarbon group, R 15 to R 18 may be bonded to each other to form a monocyclic or polycyclic ring, the monocyclic or polycyclic ring may have a double bond, and R 15 and R 16 or R 17 and R 18 may form an alkylidene group. 2. The optical component according to claim 1 , wherein a ratio ((b)/(c)) of a content of the constitutional unit (b) to a content of the constitutional unit (c) in the cyclic olefin-based copolymer (A) is equal to or more than 2. 3. The optical component according to claim 1 , wherein the constitutional unit (b) in the cyclic olefin-based copolymer (A) includes a repeating unit derived from bicyclo[2.2.1]-2-heptene, and the constitutional unit (c) in the cyclic olefin-based copolymer (A) includes a repeating unit derived from tetracyclo[4.4.0.1 2,5 .1 7,10 ]-3-dodecene. 4. The optical component according to claim 1 , wherein the constitutional unit (a) in the cyclic olefin-based copolymer (A) includes a repeating unit derived from ethylene. 5. The optical component according to claim 1 , wherein the optical component is an fθ lens, an image pickup lens, a sensor lens, a prism, or a light guide plate. 6. The optical component according to claim 1 , wherein the optical component is an in-vehicle camera lens or a camera lens for a mobile device.
having condensed rings (coumarone-indene polymers C08F244/00) · CPC title
Lenses · CPC title
Ethene · CPC title
made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title
having one carbon-to-carbon double bond · CPC title
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