Assembly comprising a SOEC/SOFC-type solid oxide cell stack and a clamping system having a hot plate

Patent metadata

Field	Value
Publication number	US-12334615-B2
Application number	US-202218693596-A
Country	US
Kind code	B2
Filing date	Sep 19, 2022
Priority date	Sep 21, 2021
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

An assembly including a stack of solid oxide cells of the SOEC/SOFC type and a clamping system for the stack. This assembly furthermore includes at least one heating plate, demountable and interchangeable, inserted in a housing of at least one of the top and bottom clamping plates, the housing being formed in the thickness of the at least one of the top and bottom clamping plates, and comprising first and second opposite ends, at least one of which emerges on the lateral face-of the at least one of the top and bottom clamping plates, being located inside, at a distance from its main top and bottom faces substantially parallel to each other.

First claim

What is claimed is:

1. An assembly, including:
a stack of solid-oxide cells of the SOEC/SOFC type operating at high temperature, including:
a plurality of electrochemical cells each formed by a cathode, an anode, and an electrolyte interposed between the cathode and the anode, and a plurality of intermediate interconnectors each arranged between two adjacent electrochemical cells,

a system for clamping the stack of solid-oxide cells of the SOEC/SOFC type, including a top clamping plate and a bottom clamping plate, between which the stack of solid-oxide cells of the SOEC/SOFC type is clamped, each clamping plate including at least two clamping orifices, the clamping system further including:
at least two clamping rods intended to each extend through a clamping orifice of the top clamping plate and through a corresponding clamping orifice of the bottom clamping plate to enable the top and bottom clamping plates to be assembled together,
clamping means at each clamping orifice of the top and bottom clamping plates intended to cooperate with said at least two clamping rods to enable the top and bottom clamping plates to be assembled together,

wherein at least one of the top and bottom clamping plates includes a housing, formed in the thickness of said at least one of the top and bottom clamping plates, comprising first and second opposite ends, at least one of which emerges on the lateral face of said at least one of the top and bottom clamping plates, said housing being located inside said at least one of the top and bottom clamping plates, at a distance from its main top and bottom faces substantially parallel to each other, and
wherein the assembly includes at least one heating plate, demountable and interchangeable, inserted in said housing.

2. The assembly according to claim 1 , wherein said housing and said at least one heating plate have a substantially parallelepipedal shape, in particular a slab shape or a cubic shape.

3. The assembly according to claim 1 , wherein said housing is formed, in the thickness of said at least one of the top and bottom clamping plates, centrally, at equal distances from the main top and bottom faces, and at equal distances from the clamping orifices, between the clamping orifices.

4. The assembly according to claim 1 , wherein the thickness of said housing is between 5 mm and 10 mm, in particular of the order of 8 mm, and wherein the width of the housing is between 20 mm and 86 mm, in particular of the order of 86 mm.

5. The assembly according to claim 1 , wherein said at least one heating plate includes a heating element the maximum power of which is at least 1200 W.

6. The assembly according to claim 1 , wherein said at least one heating plate is produced from ceramic or from metal alloy, in particular from stainless steel or from nickel-based alloy, being in particular treated by an aluminizing coating.

7. The assembly according to claim 1 , wherein a clearance is present between the external surface of said at least one heating plate and the internal surface of said housing, the dimension of which is between 0.2 and 0.5 mm.

8. The assembly according to claim 1 , wherein said at least one of the top and bottom clamping plates includes at least one internal groove formed in the thickness of said at least one of the top and bottom clamping plates, and extending substantially parallel to the top and bottom-faces thereof, and at least one end of which emerges on the lateral face of said at least one of the top and bottom clamping plates, and wherein the assembly includes at least one thermocouple device inserted in said at least one internal groove.

9. The assembly according to claim 8 , wherein said at least one internal groove includes a first safety internal groove and a second regulation internal groove and wherein said at least one thermocouple device includes a first safety thermocouple device inserted in the first internal groove and a second regulation thermocouple device inserted in the second internal groove.

10. The assembly according to claim 1 , it includes-further including a top end plate and a bottom end plate, between which the plurality of electrochemical cells and the plurality of intermediate interconnectors are clamped.

11. The assembly according to claim 1 , wherein said at least one of the top and bottom clamping plates is manufactured by an additive manufacturing technique, being in particular produced from refractory austenitic steel.

12. The assembly according to claim 1 , said wherein at least one of the top and bottom clamping plates has a thickness of between 20 and 30 mm, in particular of the order of 25 mm.

13. A method for manufacturing the assembly according to claim 1 , including the step of producing said housing in said at least one of the top and bottom clamping plates.

14. The according to claim 13 , wherein the step of producing said housing includes production by electroerosion, by hubbing, and/or by additive manufacturing.

Assignees

• Commissariat Energie Atomique

Inventors

• Planque Michel
• Roux Guilhem

Classifications

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/0432

  Temperature; Ambient temperature · CPC title

• H01M8/04067

  Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins · CPC title

• C25B9/05

  Pressure cells · CPC title

• C25B15/023

  Measuring, analysing or testing during electrolytic production · CPC title