Anodeless lithium metal battery and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-12334548-B2
Application number	US-202217749372-A
Country	US
Kind code	B2
Filing date	May 20, 2022
Priority date	Jan 5, 2018
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

An anodeless lithium metal battery includes: a cathode including a cathode current collector and a cathode active material layer on the cathode current collector; an anode current collector on the cathode; and a composite electrolyte between the cathode and the anode current collector, wherein the composite electrolyte includes a first liquid electrolyte and at least one of lithium metal or a lithium metal alloy.

First claim

What is claimed is:

1. A charged lithium metal battery comprising:
a cathode comprising a cathode current collector and a cathode active material layer on the cathode current collector;
an anode current collector, wherein the anode current collector is a mesh current collector;
a composite electrolyte between the cathode and the anode current collector; and
a solid electrolyte disposed between the composite electrolyte and the cathode;
wherein the composite electrolyte comprises a first electrolyte comprising a lithium salt and a first solvent and
an interconnected network structure disposed on a surface of the anode current collector, the interconnected structure comprising a plurality of connected metal particles, each metal particle comprising a core of at least one of lithium or lithium metal alloy and lithium from the lithium salt is electrodeposited on a surface of the core of the metal particles, wherein the electrodeposited lithium connects the metal particles to form a layer.

2. The charged lithium metal battery of claim 1 , wherein the electrodeposited lithium connecting the metal particles form the interconnected network structure layer, the layer having a thickness of about 0.1% to about 10% of a thickness of the cathode.

3. The charged lithium metal battery of claim 1 , wherein an amount of the metal particles in the composite electrolyte is 1 part by weight to 50 parts by weight, with respect to 100 parts by weight of a total weight of the composite electrolyte.

4. The charged lithium metal battery of claim 1 , wherein the first solvent comprises at least one selected from the group consisting of an ether compound and a sulfone compound.

5. The charged lithium metal battery of claim 4 , wherein the first solvent comprises the ether compound, and the ether compound is at least one selected from the group consisting of a glyme compound, a dioxolane compound, and a fluorinated ether compound.

6. The charged lithium metal battery of claim 5 , wherein
the glyme compound is at least one selected from the group consisting of ethylene glycol dimethylether, ethylene glycol diethylether, propylene glycol dimethylether, propylene glycol diethylether, butylene glycol dimethylether, butylene glycol diethylether, diethylene glycol dimethylether, triethylene glycol dimethylether, tetraethylene glycol dimethylether, diethylene glycol diethylether, triethylene glycol diethylether, tetraethylene glycol diethylether, dipropylene glycol dimethylether, tripropylene glycol dimethylether, tetrapropylene glycol dimethylether, dipropylene glycol diethylether, tripropylene glycol diethylether, tetrapropylene glycol diethylether, dibutylene glycol dimethylether, tributylene glycol dimethylether, tetrabutylene glycol dimethylether, dibutylene glycol diethylether, tributylene glycol diethylether, and tetrabutylene glycol diethylether,
the dioxolane compound is at least one selected from the group consisting of 1,3-dioxolane, 4,5-dimethyl-1,3-dioxolane, 4,5-diethyl-1,3-dioxolane, 4-methyl-1,3-dioxolane, 4-ethyl-1,3-dioxolane, 2-methyl-1,3-dioxolane, 2-vinyl-1,3-dioxolane, 2,2-dimethyl-1,3-dioxolane, and 2-ethyl-2-methyl-1,3-dioxolane, and
the fluorinated ether compound is at least one selected from the group consisting of 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropyl ether, and 2,2,3,3,4,4,5,5-octafluoropentyl 1,1,2,2-tetrafluoroethyl ether.

7. The charged lithium metal battery of claim 1 , wherein the cathode active material layer further comprises a second electrolyte comprising a lithium salt and a second solvent, and the second solvent comprises at least one selected from the group consisting of an ether compound, a sulfone compound, and a carbonate compound,
wherein the first electrolyte has a composition that is the same or different than a composition of the second electrolyte.

8. The charged lithium metal battery of claim 4 , wherein the first solvent comprises the at least one sulfone compound selected from the group consisting of dimethyl sulfone, diethyl sulfone, and ethylmethyl sulfone.

9. The charged lithium metal battery of claim 1 , wherein composite electrolyte has a kinematic viscosity at 25° C. of 1 centipoise to 30 centipoise or less.

10. The charged lithium metal battery of claim 1 , wherein the first electrolyte has a kinematic viscosity at 25° C. of 1 centipoise to 5 centipoise or less.

11. The charged lithium metal battery of claim 1 , wherein the composite electrolyte further comprises a non-woven fabric supporting the metal particles.

12. The charged lithium metal battery of claim 11 , wherein the non-woven fabric comprises at least one selected from the group consisting of cellulose, polyester, polyetherimide, polyethylene, polypropylene, polyethylene terephthalate, polybutylene terephthalate, polyamide, polyacetal, polycarbonate, polyimide, polyether ketone, polyether sulfone, polyphenylene oxide, polyphenylene sulfide, polyethylene naphthalate, polytetrafluoroethylene, polyvinylidene fluoride, polyvinyl chloride, polyacrylonitrile, nylon, and polypara-phenylene benzobisoxazole.

13. The charged lithium metal battery of claim 1 , wherein a concentration of the lithium salt in the first electrolyte is about 1 molar to about 8 molar.

14. The charged lithium metal battery of claim 13 , wherein the concentration of the lithium salt in the first electrolyte is about 2 molar to about 5 molar.

15. The charged lithium metal battery of claim 13 , wherein the lithium salt comprises at least one selected from the group consisting of LiSCN, LiN(CN) 2 , Li(CF 3 SO 2 ) 3 C, Li(FSO 2 ) 2 N(LiFSI), LiC 4 F 9 SO 3 , LiN(SO 2 CF 2 CF 3 ) 2 , LiPF 3 (C 2 F 5 ) 3 , LiCl, LiF, LiBr, LiI, LiB(C 2 O 4 ) 2 , LiPF 6 , LiPF 5 (CF 3 ), LiPF 5 (C 2 F 5 ), LiPF 5 (C 3 F 7 ), LiPF 4 (CF 3 ) 2 , LiPF 4 (CF 3 )(C 2 F 5 ), LiPF 3 (CF 3 ) 3 , LiPF 3 (CF 2 CF 3 ) 3 , LiPF 4 (C 2 O 4 ) 2 , LiBF 4 , LiBF 3 (C 2 F 5 ), lithium bis(oxalato) borate, lithium oxalyldifluoroborate, lithium difluoro (oxalato) borate, lithium bis(trifluoro methanesulfonyl)imide, LiN(SO 2 CF 3 ) 2 , lithium bis(fluorosulfonyl)imide, LiN(SO 2 F) 2 , LiN(SO 2 C 2 F 5 ) 2 , LiCF 3 SO 3 , LiAsF 6 , LiSbF 6 , and LiClO 4 .

16. The charged lithium metal battery of claim 1 , wherein the solid electrolyte layer is selected from the group consisting of an inorganic solid electrolyte material, an organic solid electrolyte material, and an organic/inorganic composite solid electrolyte material.

17. The charged lithium metal battery of claim 16 , wherein
the inorganic solid electrolyte material is at least one selected from the group consisting of a glassy active metal ionic conductor, an amorphous active metal ionic conductor, a ceramic active metal ionic conductor, and a glass-ceramic active metal ionic conductor,
the organic solid electrolyte material is at least one selected from the group consisting of a polyethylene derivative, a polyethylene oxide derivative, a polypropylene oxide derivative, a phosphoric acid ester polymer, polyester sulfide, polyvinyl alcohol, and polyvinylidene fluoride; and
the organic/inorganic composite electrolyte material comprises the organic solid electrolyte material and the inorganic solid electrolyte material.

18. The charged lithium metal battery of claim 1 , wherein the metal particle comprises the lithium metal.

19. The charged lithium metal battery of claim 1 , wherein the metal particle has a size of about 5 micrometers to about 50 micrometers.

Assignees

• Samsung Electronics Co Ltd
• Samsung Sdi Co Ltd

Inventors

• Chang Wonseok
• Kang Hyorang
• Kim Soyeon
• Kim Jirai
• Sugimoto Toshinori
• Lee Yonggun
• Im Dongmin
• Kitajima Shintaro

Classifications

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title

• H01M2300/0091

  in the form of mixtures · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title

• H01M2300/0082

  Organic polymers · CPC title

• H01M2300/0068

  inorganic · CPC title